Cafetite is a rare titanium

Titanium

Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

 oxide mineral

Oxide mineral

The oxide mineral class includes those minerals in which the oxide anion is bonded to one or more metal ions. The hydroxide bearing minerals are typically included in the oxide class...

 with formula (Ca

Calcium

Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

,Mg

Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

)(Fe

Iron

Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

,Al

Aluminium

Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

)₂Ti

Titanium

Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

₄O

Oxygen

Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

₁₂·4(H

Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

₂O)).

It was first described in 1959 for an occurrence in the Afrikanda Massif, Afrikanda

Afrikanda (rural locality)

Afrikanda is the rural locality in Polyarnye Zori municipality of Murmansk Oblast, Russia. The village is located beyond the Arctic circle, on the Kola Peninsula...

, Kola Peninsula

Kola Peninsula

The Kola Peninsula is a peninsula in the far northwest of Russia. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely to the north of the Arctic Circle and is washed by the Barents Sea in the north and the White Sea in the east and southeast...

, Murmanskaja Oblast', Northern Region, Russia

Russia

Russia or , officially known as both Russia and the Russian Federation , is a country in northern Eurasia. It is a federal semi-presidential republic, comprising 83 federal subjects...

. It is also reported from the Khibiny

Khibiny Massif

The Khibiny Massif, Khibiny Mountains, Khibinsky Mountains or Khibins, Khibinsky tundras, Khibiny is one of the two main mountain ranges of the Kola Peninsula, Russia, within the Arctic Circle, located between Imandra and Umbozero lakes.The massif is of oval shape of about 1,300 sq.km...

 and Kovdor massif

Massif

In geology, a massif is a section of a planet's crust that is demarcated by faults or flexures. In the movement of the crust, a massif tends to retain its internal structure while being displaced as a whole...

s of the Kola Peninsula and from Meagher County, Montana

Meagher County, Montana

-National protected areas:*Gallatin National Forest *Helena National Forest *Lewis and Clark National Forest -Demographics:As of the census of 2000, there were 1,932 people, 803 households, and 529 families residing in the county...

, USA.

It occurs in pegmatite

Pegmatite

A pegmatite is a very crystalline, intrusive igneous rock composed of interlocking crystals usually larger than 2.5 cm in size; such rocks are referred to as pegmatitic....

s in a pyroxenite

Pyroxenite

Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite and diopside, hypersthene, bronzite or enstatite. They are classified into clinopyroxenites, orthopyroxenites, and the websterites which contain both pyroxenes...

 intrusion as crystals in miarolitic cavities. It occurs associated with ilmenite

Ilmenite

Ilmenite is a weakly magnetic titanium-iron oxide mineral which is iron-black or steel-gray. It is a crystalline iron titanium oxide . It crystallizes in the trigonal system, and it has the same crystal structure as corundum and hematite....

, titaniferous magnetite

Magnetite

Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

, titanite

Titanite

Titanite, or sphene , is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present...

, anatase

Anatase

Anatase is one of the three mineral forms of titanium dioxide, the other two being brookite and rutile. It is always found as small, isolated and sharply developed crystals, and like rutile, a more commonly occurring modification of titanium dioxide, it crystallizes in the tetragonal system; but,...

, perovskite

Perovskite

A perovskite structure is any material with the same type of crystal structure as calcium titanium oxide , known as the perovskite structure, or XIIA2+VIB4+X2−3 with the oxygen in the face centers. Perovskites take their name from this compound, which was first discovered in the Ural mountains of...

, baddeleyite

Baddeleyite

Baddeleyite is a rare zirconium oxide mineral , occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. Baddeleyite is a refractory mineral, with a melting point of...

, phlogopite

Phlogopite

Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O102. Iron substitutes for magnesium in variable amounts...

, clinochlore

Chlorite group

The chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the following four elements in the silicate lattice; Mg, Fe, Ni, and Mn....

 and kassite

Kassite

Kassite is a rare mineral with formula CaTi2O42. It crystallizes in the orthorhombic crystal system and forms radiating rosettes and pseudo-hexagonal tabular crystals which are commonly twinned. Crystals are brownish pink to pale yellow and are translucent with an adamantine luster...

.