Antiferroelectricity is a physical property of certain materials. It is closely related to ferroelectricity

Ferroelectricity

Ferroelectricity is a property of certain materials which possess a spontaneous electric polarization that can be reversed by the application of an external electric field. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was...

; the relation between antiferroelectricity and ferroelectricity is analogous to the relation between antiferromagnetism

Antiferromagnetism

In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usuallyrelated to the spins of electrons, align in a regular pattern with neighboring spins pointing in opposite directions. This is, like ferromagnetism and ferrimagnetism, a manifestation of ordered magnetism...

 and ferromagnetism

Ferromagnetism

Ferromagnetism is the basic mechanism by which certain materials form permanent magnets, or are attracted to magnets. In physics, several different types of magnetism are distinguished...

.

An antiferroelectric material consists of an ordered (crystal

Crystal

A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

line) array of electric dipoles (from the ions and electrons in the material), but with adjacent dipoles oriented in opposite (antiparallel) directions (the dipoles of each orientation form interpenetrating sublattices, loosely analogous to a checkerboard

Checkerboard

A checkerboard or chequerboard is a board of chequered pattern on which English draughts is played. It is an 8×8 board and the 64 squares are of alternating dark and light color, often red and black....

 pattern). This can be contrasted with a ferroelectric, in which the dipoles all point in the same direction.

In an antiferroelectric, unlike a ferroelectric, the total, macroscopic spontaneous polarization

Polarization density

In classical electromagnetism, polarization density is the vector field that expresses the density of permanent or induced electric dipole moments in a dielectric material. When a dielectric is placed in an external electric field, its molecules gain electric dipole moment and the dielectric is...

 is zero, since the adjacent dipoles cancel each other out.

Antiferroelectricity is a phase

Phase (matter)

In the physical sciences, a phase is a region of space , throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, and chemical composition...

 of a material, and it can appear or disappear (more generally, strengthen or weaken) depending on temperature, pressure, external electric field, growth method, and other parameters. In particular, at a high enough temperature, antiferroelectricity disappears; this temperature is called the antiferroelectric Curie point

Curie point

In physics and materials science, the Curie temperature , or Curie point, is the temperature at which a ferromagnetic or a ferrimagnetic material becomes paramagnetic on heating; the effect is reversible. A magnet will lose its magnetism if heated above the Curie temperature...

.