Autoprotolysis
Encyclopedia
In autoprotolysis a proton
Proton
The proton is a subatomic particle with the symbol or and a positive electric charge of 1 elementary charge. One or more protons are present in the nucleus of each atom, along with neutrons. The number of protons in each atom is its atomic number....

 is transferred between two identical molecule
Molecule
A molecule is an electrically neutral group of at least two atoms held together by covalent chemical bonds. Molecules are distinguished from ions by their electrical charge...

s, one of which acts as a Brønsted acid, releasing a proton which is accepted by the other molecule acting as a Brønsted base. For example water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 undergoes autoprotolysis in the self-ionization of water
Self-ionization of water
The self-ionization of water is the chemical reaction in which a proton is transferred from one water molecule to another, in pure water or an aqueous solution, to create the two ions, hydronium, H3O+ and hydroxide, OH−...

reaction.
H2O + H2O OH + H3O+


Every solvent containing hydrogen can undergo autoprotolysis.
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