Benitoite is a rare blue barium

Barium

Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...

 titanium

Titanium

Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

 silicate mineral, found in hydrothermally altered serpentinite

Serpentinite

Serpentinite is a rock composed of one or more serpentine group minerals. Minerals in this group are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle...

. Benitoite fluoresces under short wave ultraviolet light, appearing bright blue to bluish white in color. The more rarely seen clear to white benitoite crystals fluoresce red under long-wave UV light.

It was first described in 1907 by George D. Louderback, who named it benitoite for its occurrence near the headwaters of the San Benito River

San Benito River

The San Benito River is a river on the Central Coast of California. From its headwaters near San Benito Mountain in the Diablo Range, it flows northwest between the Diablo Range and the Gabilan Range, traveling for about before its confluence with the Pajaro River, about upstream from the river's...

 in San Benito County, California

California

California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...

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Benitoite occurs in a number of sites, but gemstone quality material has only been found in California. It is California's official state gem.

Associated minerals and locations

Benitoite typically occurs with an unusual set of minerals, along with minerals that make up its host rock. Frequently associated minerals include: natrolite

Natrolite

Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany....

, neptunite

Neptunite

Neptunite is a silicate mineral with the formula KNa2Li2Ti2Si8O24. With increasing manganese it forms a series with mangan-neptunite. Watatsumiite is the variety with vanadium replacing the titanium in the formula....

, joaquinite, serpentine and albite

Albite

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. As such it represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi3O8. It is a tectosilicate. Its color is usually pure white, hence...

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Benitoite is a rare mineral found in very few locations including San Benito County, California, Japan

Japan

Japan is an island nation in East Asia. Located in the Pacific Ocean, it lies to the east of the Sea of Japan, China, North Korea, South Korea and Russia, stretching from the Sea of Okhotsk in the north to the East China Sea and Taiwan in the south...

 and Arkansas

Arkansas

Arkansas is a state located in the southern region of the United States. Its name is an Algonquian name of the Quapaw Indians. Arkansas shares borders with six states , and its eastern border is largely defined by the Mississippi River...

. In the San Benito occurrence, it is found in natrolite

Natrolite

Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany....

 veins

Vein (geology)

In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation...

 within glaucophane

Glaucophane

Glaucophane is a mineral belonging to the amphibole group, chemical formula []Na2]Mg3Al2][2|Si8O22].-Name:It is named from its typical blue color . Glaucophane crystallizes in the monoclinic system....

 schist

Schist

The schists constitute a group of medium-grade metamorphic rocks, chiefly notable for the preponderance of lamellar minerals such as micas, chlorite, talc, hornblende, graphite, and others. Quartz often occurs in drawn-out grains to such an extent that a particular form called quartz schist is...

 within a serpentinite

Serpentinite

Serpentinite is a rock composed of one or more serpentine group minerals. Minerals in this group are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle...

 body. In Japan, the mineral occurs in a magnesio-riebeckite

Riebeckite

Riebeckite is a sodium-rich member of the amphibole group of silicate minerals, chemical formula [][Na2][32][2|Si8O22]. It forms a series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long prismatic crystals showing a diamond-shaped cross section, but also in...

-quartz

Quartz

Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

-phlogopite

Phlogopite

Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O102. Iron substitutes for magnesium in variable amounts...

-albite

Albite

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. As such it represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi3O8. It is a tectosilicate. Its color is usually pure white, hence...

 dike

Dike (geology)

A dike or dyke in geology is a type of sheet intrusion referring to any geologic body that cuts discordantly across* planar wall rock structures, such as bedding or foliation...

 cutting a serpentinite body.

In 1985 benitoite was named as the official state gem of California

California

California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...

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