Black tin is the raw ore

Ore

An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....

 of tin

Tin

Tin is a chemical element with the symbol Sn and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows chemical similarity to both neighboring group 14 elements, germanium and lead and has two possible oxidation states, +2 and the slightly more stable +4...

, usually cassiterite

Cassiterite

Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem...

, as sold by a tin mine to a smelting

Smelting

Smelting is a form of extractive metallurgy; its main use is to produce a metal from its ore. This includes iron extraction from iron ore, and copper extraction and other base metals from their ores...

 company. After mining, the ore has to be concentrated by a number of processes to reduce the amount of gangue

Gangue

In mining, gangue is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. The separation of mineral from gangue is known as mineral processing, mineral dressing or ore dressing and it is a necessary and often significant aspect of mining...

 it contains before it can be sold. It contrasts with white tin

White tin

White tin is refined, metallic tin. It contrasts with black tin, which is unrefined tin ore as extracted from the ground. The term "white tin" was historically associated with tin mining in Devon and Cornwall where it was smelted from black tin in blowing houses....

, which is the refined

Refining

Refining is the process of purification of a substance or a form. The term is usually used of a natural resource that is almost in a usable form, but which is more useful in its pure form. For instance, most types of natural petroleum will burn straight from the ground, but it will burn poorly...

, metallic tin produced after smelting.

The term "black tin" was historically associated with tin mining in Devon

Devon

Devon is a large county in southwestern England. The county is sometimes referred to as Devonshire, although the term is rarely used inside the county itself as the county has never been officially "shired", it often indicates a traditional or historical context.The county shares borders with...

 and Cornwall

Cornwall

Cornwall is a unitary authority and ceremonial county of England, within the United Kingdom. It is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar. Cornwall has a population of , and covers an area of...

.