Cacoxenite
Encyclopedia
Cacoxenite is an iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

 phosphate mineral with formula: Fe3+24Al(PO4)17O6(OH)12·17(H2O). It is associated with iron ores. The name comes from the Greek κăκός for "bad" or "evil" and ξένος for "guest" because the phosphorus content of cacoxenite lessens the quality of iron smelted from ore containing it.

It was first described in 1825 for an occurrence in the Hrbek Mine, Bohemia
Bohemia
Bohemia is a historical region in central Europe, occupying the western two-thirds of the traditional Czech Lands. It is located in the contemporary Czech Republic with its capital in Prague...

, Czech Republic
Czech Republic
The Czech Republic is a landlocked country in Central Europe. The country is bordered by Poland to the northeast, Slovakia to the east, Austria to the south, and Germany to the west and northwest....

. It occurs as a secondary phase in oxidized magnetite
Magnetite
Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

 and limonite
Limonite
Limonite is an ore consisting in a mixture of hydrated iron oxide-hydroxide of varying composition. The generic formula is frequently written as FeO·nH2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.Together with hematite, it has...

 deposits. It also occurs in novaculite
Novaculite
Novaculite is a form of chert or flint found in the Ouachita Mountains of Arkansas and Oklahoma and in the Marathon Uplift of Texas. Novaculite is considered to be highly siliceous sediments and may be a product of the low-grade metamorphism of chert beds...

s and in iron and phosphorus rich sediment
Sediment
Sediment is naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of fluids such as wind, water, or ice, and/or by the force of gravity acting on the particle itself....

s.
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