Caesium oxide or cesium oxide describes inorganic compound

Inorganic compound

Inorganic compounds have traditionally been considered to be of inanimate, non-biological origin. In contrast, organic compounds have an explicit biological origin. However, over the past century, the classification of inorganic vs organic compounds has become less important to scientists,...

s composed of caesium

Caesium

Caesium or cesium is the chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-gold alkali metal with a melting point of 28 °C , which makes it one of only five elemental metals that are liquid at room temperature...

 and oxygen

Oxygen

Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

. The following binary (containing only Cs and O) oxides of caesium are known: Cs₁₁O₃, Cs₄O, Cs₇O, and Cs₂O. Both the oxide and suboxide

Suboxide

Suboxides are a class of oxides wherein the electropositive element is in excess relative to the “normal” oxides. When the electropositive element is a metal, the compounds are sometimes referred to as “metal-rich”. Thus the normal oxide of caesium is Cs2O, which is described as a Cs+ salt of O2−...

s are brightly coloured. The species Cs₂O forms yellow-orange hexagonal

Hexagonal crystal system

In crystallography, the hexagonal crystal system is one of the 7 crystal systems, the hexagonal lattice system is one of the 7 lattice systems, and the hexagonal crystal family is one of the 6 crystal families...

 crystals.

Uses

Caesium oxide is used in photocathode

Photocathode

A photocathode is a negatively charged electrode in a light detection device such as a photomultiplier or phototube that is coated with a photosensitive compound...

s to detect infrared

Infrared

Infrared light is electromagnetic radiation with a wavelength longer than that of visible light, measured from the nominal edge of visible red light at 0.74 micrometres , and extending conventionally to 300 µm...

 signals in devices such as image intensifier

Image intensifier

An image intensifier tube is a vacuum tube device for increasing the intensity of available light in an optical system to allow use under low light conditions such as at night, to facilitate visual imaging of low-light processes such as fluorescence of materials to X-rays or gamma rays, or for...

s, vacuum photodiode

Photodiode

A photodiode is a type of photodetector capable of converting light into either current or voltage, depending upon the mode of operation.The common, traditional solar cell used to generateelectric solar power is a large area photodiode....

s, photomultiplier

Photomultiplier

Photomultiplier tubes , members of the class of vacuum tubes, and more specifically phototubes, are extremely sensitive detectors of light in the ultraviolet, visible, and near-infrared ranges of the electromagnetic spectrum...

s, and TV camera tubes
L. R. Koller described the first modern photoemissive surface in 1929–30 as a layer of caesium on a layer of caesium oxide on a layer of silver

Silver

Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...

. It is a good electron

Electron

The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...

 emitter; however, its high vapor pressure

Vapor pressure

Vapor pressure or equilibrium vapor pressure is the pressure of a vapor in thermodynamic equilibrium with its condensed phases in a closed system. All liquids have a tendency to evaporate, and some solids can sublimate into a gaseous form...

 limits its usefulness.

Reactions

Elemental magnesium

Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

 reduces

Redox

Redox reactions describe all chemical reactions in which atoms have their oxidation state changed....

 caesium oxide to elemental caesium, forming magnesium oxide

Magnesium oxide

Magnesium oxide , or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium . It has an empirical formula of and consists of a lattice of Mg2+ ions and O2– ions held together by ionic bonds...

as a side-product:

Cs₂O + Mg → Cs + MgO

Cs₂O is hygroscopic, forming the corrosive CsOH on contact with water.