Carbon ring
Encyclopedia
Carbon rings are rings of carbon
atom
s. Rings of five and six carbons are by far the most common, as they allow bond angles close to the ideal angle of 109.5°. Rings of three and four are possible, but with bond
angles of 60° and 90°, they have a larger ring strain
and are unstable. Ring strain decreases with an increasing number of carbon atoms until cyclohexane
, which is a six-membered ring. After cyclohexane, ring strain increases again until cyclotetradecane, with 14 carbon atoms. Ring strain starts to decrease again, but slowly; very large rings have little ring strain, as they are almost linear.
Compounds such as cycloalkene
s or benzene
, or the non-benzenoid aromatic tropone
, have a single carbon ring; rings can also be joined, with some atoms being a part of more than one ring. Naphthalene
is the simplest such multi-ringed hydrocarbon, having the structure of two fused benzene rings.
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...
atom
Atom
The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons...
s. Rings of five and six carbons are by far the most common, as they allow bond angles close to the ideal angle of 109.5°. Rings of three and four are possible, but with bond
Chemical bond
A chemical bond is an attraction between atoms that allows the formation of chemical substances that contain two or more atoms. The bond is caused by the electromagnetic force attraction between opposite charges, either between electrons and nuclei, or as the result of a dipole attraction...
angles of 60° and 90°, they have a larger ring strain
Ring strain
In organic chemistry, ring strain is the tendency of a cyclic molecule, such as cyclopropane, to destabilize when its atoms are in non-favorable high energy spatial orientations...
and are unstable. Ring strain decreases with an increasing number of carbon atoms until cyclohexane
Cyclohexane
Cyclohexane is a cycloalkane with the molecular formula C6H12. Cyclohexane is used as a nonpolar solvent for the chemical industry, and also as a raw material for the industrial production of adipic acid and caprolactam, both of which being intermediates used in the production of nylon...
, which is a six-membered ring. After cyclohexane, ring strain increases again until cyclotetradecane, with 14 carbon atoms. Ring strain starts to decrease again, but slowly; very large rings have little ring strain, as they are almost linear.
Compounds such as cycloalkene
Cycloalkene
A cycloalkene or cycloolefin is a type of alkene hydrocarbon which contains a closed ring of carbon atoms, but has no aromatic character. Some cycloalkenes, such as cyclobutene and cyclopentene, can be used as monomers to produce polymer chains. Unless the rings are very large, cycloalkenes are...
s or benzene
Benzene
Benzene is an organic chemical compound. It is composed of 6 carbon atoms in a ring, with 1 hydrogen atom attached to each carbon atom, with the molecular formula C6H6....
, or the non-benzenoid aromatic tropone
Tropone
Tropone or 2,4,6-cycloheptatrien-1-one is an organic compound with some importance in organic chemistry as a non-benzenoid aromatic. The compound consists of a ring of seven carbon atoms with three conjugated alkene groups and a ketone group...
, have a single carbon ring; rings can also be joined, with some atoms being a part of more than one ring. Naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...
is the simplest such multi-ringed hydrocarbon, having the structure of two fused benzene rings.