Chlorinated polyvinyl chloride
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Chlorinated Polyvinyl chloride
Density
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...

1.56 g/cm3
Young's modulus
Young's modulus
Young's modulus is a measure of the stiffness of an elastic material and is a quantity used to characterize materials. It is defined as the ratio of the uniaxial stress over the uniaxial strain in the range of stress in which Hooke's Law holds. In solid mechanics, the slope of the stress-strain...

 (E)
2.9-3.4 G
Giga
Giga is a unit prefix in the metric system denoting a factor of billion . It has the symbol G.Giga is derived from the Greek γίγας, meaning 'giant'...

Pa
Pascal (unit)
The pascal is the SI derived unit of pressure, internal pressure, stress, Young's modulus and tensile strength, named after the French mathematician, physicist, inventor, writer, and philosopher Blaise Pascal. It is a measure of force per unit area, defined as one newton per square metre...

Tensile strength
Tensile strength
Ultimate tensile strength , often shortened to tensile strength or ultimate strength, is the maximum stress that a material can withstand while being stretched or pulled before necking, which is when the specimen's cross-section starts to significantly contract...

t)
50-80 MPa
Pascal (unit)
The pascal is the SI derived unit of pressure, internal pressure, stress, Young's modulus and tensile strength, named after the French mathematician, physicist, inventor, writer, and philosopher Blaise Pascal. It is a measure of force per unit area, defined as one newton per square metre...

Elongation @ break20-40%
Notch test2-5 kJ
Joule
The joule ; symbol J) is a derived unit of energy or work in the International System of Units. It is equal to the energy expended in applying a force of one newton through a distance of one metre , or in passing an electric current of one ampere through a resistance of one ohm for one second...

/m2
Glass temperature 106 - 115 °C
Melting point
Melting point
The melting point of a solid is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at standard atmospheric pressure...

212 °C
Vicat B106 to 115 °C
Thermal conductivity (k)0.16 W/(m·K
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...

)
Linear Expansion Coefficient (α)8 x 10−5 /K
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...

Specific heat (c)0.9 kJ/(kg·K)
Water absorption (ASTM)0.04-0.4
Price0.5-1.25 €/kg

Chlorinated polyvinyl chloride (CPVC) is a thermoplastic
Thermoplastic
Thermoplastic, also known as a thermosoftening plastic, is a polymer that turns to a liquid when heated and freezes to a very glassy state when cooled sufficiently...

 produced by chlorination of polyvinyl chloride
Polyvinyl chloride
Polyvinyl chloride, commonly abbreviated PVC, is a thermoplastic polymer. It is a vinyl polymer constructed of repeating vinyl groups having one hydrogen replaced by chloride. Polyvinyl chloride is the third most widely produced plastic, after polyethylene and polypropylene. PVC is widely used in...

 (PVC) resin
Resin
Resin in the most specific use of the term is a hydrocarbon secretion of many plants, particularly coniferous trees. Resins are valued for their chemical properties and associated uses, such as the production of varnishes, adhesives, and food glazing agents; as an important source of raw materials...

. Uses include hot and cold water pipe, and industrial liquid handling.

Production process

CPVC is PVC (polyvinyl chloride) that has been chlorinated via a free radical chlorination
Free radical halogenation
In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of heat or UV light. The reaction is used for the industrial synthesis of chloroform , dichloromethane , and hexachlorobutadiene...

 reaction. This reaction is typically initiated by application of thermal or UV
Ultraviolet
Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...

 energy utilizing various approaches. In the process, chlorine
Chlorine
Chlorine is the chemical element with atomic number 17 and symbol Cl. It is the second lightest halogen, found in the periodic table in group 17. The element forms diatomic molecules under standard conditions, called dichlorine...

 gas is decomposed into free radical
Radical (chemistry)
Radicals are atoms, molecules, or ions with unpaired electrons on an open shell configuration. Free radicals may have positive, negative, or zero charge...

 chlorine which is then reacted with PVC in a post-production step, essentially replacing a portion of the hydrogen in the PVC with chlorine.

Depending on the method, a varying amount of chlorine is introduced into the polymer allowing for a measured way to fine tune the final properties. The chlorine content may vary from manufacturer to manufacturer; the base can be as low as PVC 56.7% to as high as 74% by mass, although most commercial resins have chlorine content from 63% to 69%. As the chlorine content in CPVC is increased, its glass transition temperature (Tg) increases significantly. Under normal operating conditions, CPVC becomes unstable at 70% mass of chlorine.

Various additives are also introduced into the resin in order to make the material processable. These additives may consist of stabilizers, impact modifiers, pigments and lubricants.

Physical properties

CPVC shares most of the features and properties of PVC. It is also readily workable, including machining, welding, and forming. Because of its excellent corrosion resistance at elevated temperatures, CPVC is ideally suited for self-supporting constructions where temperatures up to 200 °F (90 °C) are present. The ability to bend, shape, and weld CPVC enables its use in a wide variety of processes and applications. It exhibits fire-retardant
Flammability
Flammability is defined as how easily something will burn or ignite, causing fire or combustion. The degree of difficulty required to cause the combustion of a substance is quantified through fire testing. Internationally, a variety of test protocols exist to quantify flammability...

 properties.

Heat resistance

CPVC can withstand corrosive water at temperatures greater than PVC, typically 40°C to 50°C (104°F to 122°F) or higher, contributing to its popularity as a material for water piping systems in residential as well as commercial construction.

Mechanical properties

The principal mechanical difference between CPVC and PVC is that CPVC is significantly more ductile
Ductility
In materials science, ductility is a solid material's ability to deform under tensile stress; this is often characterized by the material's ability to be stretched into a wire. Malleability, a similar property, is a material's ability to deform under compressive stress; this is often characterized...

, allowing greater flexure and crush resistance. Additionally, the mechanical strength of CPVC makes it a viable candidate to replace many types of metal pipe in conditions where metal's susceptibility to corrosion
Corrosion
Corrosion is the disintegration of an engineered material into its constituent atoms due to chemical reactions with its surroundings. In the most common use of the word, this means electrochemical oxidation of metals in reaction with an oxidant such as oxygen...

 limits its use.

Fire properties

CPVC is similar to PVC in resistance to fire. It is typically very difficult to ignite and tends to self-extinguish when not in a directly applied flame.

Due to its chlorine content, the incineration of CPVC, either in a fire or in an industrial disposal process, can result in the creation of dioxins.
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