Chromium(III) sulfide
Encyclopedia
Chromium Sulfide is the sulfide
salt of trivalent chromium
.
with chromium(III) oxide
or other chromium salts.
at 1350 C. It is essentially insoluble
in water. When heated sufficiently, it will oxidize in the presence of air or oxygen
, though it is otherwise fairly stable.
in humans. However, because chromium(III) sulfide is fairly insoluble in water, it is much less toxic than other chromium compounds.
Sulfide
A sulfide is an anion of sulfur in its lowest oxidation state of 2-. Sulfide is also a slightly archaic term for thioethers, a common type of organosulfur compound that are well known for their bad odors.- Properties :...
salt of trivalent chromium
Chromium
Chromium is a chemical element which has the symbol Cr and atomic number 24. It is the first element in Group 6. It is a steely-gray, lustrous, hard metal that takes a high polish and has a high melting point. It is also odorless, tasteless, and malleable...
.
Preparation
It may be formed by the reaction of hydrogen sulfideHydrogen sulfide
Hydrogen sulfide is the chemical compound with the formula . It is a colorless, very poisonous, flammable gas with the characteristic foul odor of expired eggs perceptible at concentrations as low as 0.00047 parts per million...
with chromium(III) oxide
Chromium(III) oxide
Chromium oxide is the inorganic compound of the formula Cr2O3. It is one of principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.-Structure and properties:...
or other chromium salts.
Properties
Chromium(III) sulfide appears as a brownish black powder that meltsMelting point
The melting point of a solid is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at standard atmospheric pressure...
at 1350 C. It is essentially insoluble
Solubility
Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent to form a homogeneous solution of the solute in the solvent. The solubility of a substance fundamentally depends on the used solvent as well as on...
in water. When heated sufficiently, it will oxidize in the presence of air or oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
, though it is otherwise fairly stable.
Health effects
Chromium is not a confirmed carcinogenCarcinogen
A carcinogen is any substance, radionuclide, or radiation that is an agent directly involved in causing cancer. This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes...
in humans. However, because chromium(III) sulfide is fairly insoluble in water, it is much less toxic than other chromium compounds.