Coal upgrading technology
Encyclopedia
Coal upgrading technology refers to a class of technologies developed to remove moisture and certain pollutants from low rank coals such as sub-Bituminous coal
and lignite
(brown coal) and raise their calorific values. Companies located in Australia, Germany and the United States are the principal drivers of the research, development and commercialisation of these technologies.
, attract environmental criticism. Many modern economies including Greece
and Victoria
(Australia) are highly dependent on brown coal for electricity. Improved environemntal performance and the need for stable economic environment provide incentive for investment to substantially reduce the negative environmental impact of burning raw ('as mined') brown coal.
product that is considered to be a Black coal equivalent
product suitable for burning in black coal boilers.
Victorian brown coal with a characteristic moisture content of 60% by weight is regarded as the 'wettest' brown coal in the world. The high moisture content is the key reason why the state's three major power stations are collectively regarded as the dirtiest carbon emitters in the world. Studies undertaken by the University of Melbourne
and Monash University
confirm that when moisture is removed from Victorian brown coal, naturally low levels of ash, sulfur and other elements rank it as being one of the cleanest coals in the world. When dewatered upgraded brown coal can compete in the export market at comparable prices to black coal.
With significant levels of brown coal mining occurring around the world, and mining levels increasing, the need for coal upgrading technologies has become more apparent. the technologies will help to address global environmental concern of rising emissions from the burning of brown coal and provide alternative fuel options to rapidly emerging economies such as Vietnam that face difficulty competing for black coal with China, India, Japan and other nations.
Bituminous coal
Bituminous coal or black coal is a relatively soft coal containing a tarlike substance called bitumen. It is of higher quality than lignite coal but of poorer quality than Anthracite...
and lignite
Lignite
Lignite, often referred to as brown coal, or Rosebud coal by Northern Pacific Railroad,is a soft brown fuel with characteristics that put it somewhere between coal and peat...
(brown coal) and raise their calorific values. Companies located in Australia, Germany and the United States are the principal drivers of the research, development and commercialisation of these technologies.
Environmental rationale
Around 30 nations collectively operate more than 1,400 brown coal fired power stations around the world. Brown coal power stations that cannot economically dewater brown coal are inefficient and cause of high levels of carbon emissions. High emitting power stations, notably the Hazelwood power station in AustraliaAustralia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...
, attract environmental criticism. Many modern economies including Greece
Greece
Greece , officially the Hellenic Republic , and historically Hellas or the Republic of Greece in English, is a country in southeastern Europe....
and Victoria
Victoria (Australia)
Victoria is the second most populous state in Australia. Geographically the smallest mainland state, Victoria is bordered by New South Wales, South Australia, and Tasmania on Boundary Islet to the north, west and south respectively....
(Australia) are highly dependent on brown coal for electricity. Improved environemntal performance and the need for stable economic environment provide incentive for investment to substantially reduce the negative environmental impact of burning raw ('as mined') brown coal.
Economic rationale
Coal upgrading technologies remove moisture from 'as mined' brown coal and transform the calorific performance of brown coal to a 'cleaner' burning status relatively equivalent to high calorific value black coal. Some coal upgrading processes result in a densified coalDensified coal
Densified coal is the product of the Coldry Process coal upgrading technology that removes moisture from low-rank coals such as sub-bituminous and lignite/brown coal. The densification process raises the calorific value of low rank coal to equal or exceed that of many export grade black coals...
product that is considered to be a Black coal equivalent
Black coal equivalent
Black coal equivalent is a term applied to describe the properties of an export coal product derived from the Coldry Process, a patented coal upgrading technology operated by Environmental Clean Technologies Limited, in Victoria, Australia...
product suitable for burning in black coal boilers.
Victorian brown coal with a characteristic moisture content of 60% by weight is regarded as the 'wettest' brown coal in the world. The high moisture content is the key reason why the state's three major power stations are collectively regarded as the dirtiest carbon emitters in the world. Studies undertaken by the University of Melbourne
University of Melbourne
The University of Melbourne is a public university located in Melbourne, Victoria. Founded in 1853, it is the second oldest university in Australia and the oldest in Victoria...
and Monash University
Monash University
Monash University is a public university based in Melbourne, Victoria. It was founded in 1958 and is the second oldest university in the state. Monash is a member of Australia's Group of Eight and the ASAIHL....
confirm that when moisture is removed from Victorian brown coal, naturally low levels of ash, sulfur and other elements rank it as being one of the cleanest coals in the world. When dewatered upgraded brown coal can compete in the export market at comparable prices to black coal.
With significant levels of brown coal mining occurring around the world, and mining levels increasing, the need for coal upgrading technologies has become more apparent. the technologies will help to address global environmental concern of rising emissions from the burning of brown coal and provide alternative fuel options to rapidly emerging economies such as Vietnam that face difficulty competing for black coal with China, India, Japan and other nations.
Country | 1970 | 1980 | 1990 | 2000 | 2001 |
---|---|---|---|---|---|
Germany | 369.3 | 388.0 | 356.5 | 167.7 | 175.4 |
Russia | 127.0 | 141.0 | 137.3 | 86.4 | 83.2 |
United States | 5.4 | 42.3 | 82.6 | 83.5 | 80.5 |
Australia | 24.2 | 32.9 | 46.0 | 65.0 | 67.8 |
Greece | 8.1 | 23.2 | 51.7 | 63.3 | 67.0 |
Poland | 32.8 | 36.9 | 67.6 | 61.3 | 59.5 |
Turkey | 4.4 | 15.0 | 43.8 | 63.0 | 57.2 |
Czech Republic | 67.0 | 87.0 | 71.0 | 50.1 | 50.7 |
People's Republic of China | 13.0 | 22.0 | 38.0 | 40.0 | 47.0 |
Socialist Federal Republic of Yugoslavia | 26.0 | 43.0 | 60.0 | - | - |
Serbia and Montenegro | - | - | - | 35.5 | 35.5 |
Kingdom of Romania | 14.1 | 27.1 | 33.5 | 17.9 | 29.8 |
North Korea | 5.7 | 10.0 | 10.0 | 26.0 | 26.5 |
Total | 804.0 | 1,028.0 | 1,214.0 | 877.4 | 894.8 |
Technology comparison
Because of inherent high moisture content, all lignites need to be dried prior to combustion. Depending on the technology type drying is achieved either via a discrete operation or part of a process. The comparison chart identifies different technology drying methods that are in development in different countries and provides a qualitative comparison.Option | Current Use | Coldry ProcessColdry Process, ECT Limited, Australia | RWE-WTARWE-WTE = RWE (Rhenish-Westphalian Electric) WTE technology | WEC-BCBWEC-BCB = White Energy Company, Binderless Coal Briquetting | UBCUBC = Upgraded Brown Coal Process, Japan Coal Energy Center & Kobe Steel Ltd. | Exergen CHTDExergen company, Continuous Hydrothermal Dewatering technology | MTEMTE = Mechanical Thermal Expression, developed by the CRC for Clean Power | KfuelKFuel = Koppelman Fuel, Evergreen Energy, Denver, Colorado, USA |
---|---|---|---|---|---|---|---|---|
Country of origin | n/a | Australia | Germany | Australia | Indonesia/Japan | Australia | Australia | United States |
Process Description | mine lignite 'as is'. Combust untreated. Burn in standard brown coal boiler |
exothermic reaction. natural evaporation. accelerated drying at 25-30°C |
fluidised bed stream drying |
flash dry coal fines. use pressure to form briquettes |
mixing crushed coal with oil, heating the mixture to 130-160°C under 19-19.5 Bar pressure, separating the slurry cake from the oil by a centrifuge and then drying and briquetting it |
Continuous Hydrothermal Dewatering decarboxylation reaction in slurry form at 300 degC and 100 Bar, followed by gas/liquid/solid separation and press drying |
heat and squeeze at 250°C and 125 Bar, express water from coal |
heat and squeeze at 200°C and 100 Bar |
Drying Description | drying achieved in recirculated steam of boiler exhaust gases via high temperature | drying achieved using low temperature waste heat to provide evaporative drying | drying achieved using >100°C low pressure steam | drying achieved via exposure to high pressure combustion stream (flash drying) | drying achieved by exposure to 130-160°C under 19-19.5 Bar pressure in oil slurry | drying achieved by exposure to high pressure and temperature in a vertical autoclave, followed by a flashing step | drying achieved via high pressure and temperature compression | drying achieved via high pressure and temperature compression |
Grade of heat used for drying | High | Low | Medium | High | Medium | Medium | High | High |
Alternative uses for energy consumed in drying | steam generation | none | power generation | coal sales (fines used for combustion | n/a | electrical energy | electrical energy | electrical energy |
Pretreatment requirement | crushing/screening (normal) | (normal) plus mechanical mastication and extrusion | (normal) | (normal) | crushing and mixing with oils | slurrying and high pressure pumping | (normal) | (normal) |
CO2 exposures | high end exposure to CO2 - default position | Up to 40% reduction in CO2. Net beneficial CO2 position due to low heat and low pressure | Up to 30-40% CO2 reduction from the boiler. (Lost steam energy utilised in fluid bed dryer not accounted for) | zero net improvement due to energy source for drying is coal combustion | n/a | Up to 40% reduction in CO2 | ~15% CO2 reduction in combustion (detailed analysis not available). Zero net improvement, due to energy used for heating and compression | ~15% CO2 reduction in combustion (detailed analysis not available). Utilises energy for heating and compression |
Waste streams generated from drying | none | none | none | none | waste water stream | none | waste water stream | waste water stream |
Byproduct streams possible | none | demineralised water | none | none | n/a | demineralised water | none | none |
Coal output stream description | input coal for power generation only | coal pellets for use and export | input coal for power generation only | coal briquettes for use and export | coal briquettes for use and export | coal for use and export | input coal for power generation only | input coal for power generation only |
Coal output moisture level | n/a | 12-14% | 12-14% | 10-15% | n/a | 5-10% | ~18% | ~20% |
Coal output - transportable or exportable | n/a | non-pyrophoric | direct to boiler only | non-pyrophoric | non-pyrophoric | non-pyrophoric | pyrophoric | pyrophoric |
Industrial maturity | status quo - well established | pilot plant operational for 7 years; extensive database of global testing; commencing feasibility for full scale commercial operation by 2014 | commercial operations in several locations | one commercial scale plant, operations have not exceeded 30% of nameplate capacity | pilot plant operational | Pilot Plant 2002 - 2008, ready for commercialisation. Tested on Victorian and Indonesian coals | pilot plant abandoned | pilot plant operational |
See also
- Bituminous coalBituminous coalBituminous coal or black coal is a relatively soft coal containing a tarlike substance called bitumen. It is of higher quality than lignite coal but of poorer quality than Anthracite...
- Bergius processBergius processThe Bergius Process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of high-volatile bituminous coal at high temperature and pressure...
- Coal assayCoal assayCoal Analysis techniques are specific analytical methods designed to measure the particular physical and chemical properties of coals. These methods are used primarily to determine the suitability of coal for coking, power generation or for iron ore smelting in the manufacture of steel.-Chemical...
- Coldry ProcessColdry ProcessColdry Process is a coal upgrading technology developed in Victoria, Australia by Environmental Clean Technologies Limited to specifically beneficiate low-rank brown coal and sub-bituminous coal by removing natural high moisture content and certain pollutants; harden and densify the coal; raise...
- Densified coalDensified coalDensified coal is the product of the Coldry Process coal upgrading technology that removes moisture from low-rank coals such as sub-bituminous and lignite/brown coal. The densification process raises the calorific value of low rank coal to equal or exceed that of many export grade black coals...
- Energy value of coalEnergy value of coalThe energy value of coal, or the fuel content, raj is the amount of potential energy in coal that can be converted into actual heating ability. The value can be calculated and compared with different grades of coal or even other materials...
- Orders of magnitude (specific energy density)Orders of magnitude (specific energy density)This is a table of specific energy densities by magnitude. Unless otherwise noted, these values assume standard ambient temperature and pressure....
- Fischer-Tropsch processFischer-Tropsch processThe Fischer–Tropsch process is a set of chemical reactions that convert a mixture of carbon monoxide and hydrogen into liquid hydrocarbons. The process, a key component of gas to liquids technology, produces a petroleum substitute, typically from coal, natural gas, or biomass for use as synthetic...
- Karrick processKarrick processThe Karrick process is a low-temperature carbonization and pyrolysis process of carbonaceous materials. Although primarily meant for coal carbonization, it also could be used for processing of oil shale, lignite or any carbonaceous materials. These are heated at to in the absence of air to...
- LeonarditeLeonarditeLeonardite is a soft waxy, black or brown, shiny, vitreous mineraloid that is easily soluble in alkaline solutions. It is an oxidation product of lignite, associated with near-surface mining...
- Maddingley MineMaddingley MineMaddingley Mine near Bacchus Marsh Railway Station, Victoria, Australia contains a concentration of a particular brown coal formation called Leonardite. A relatively high altitude formation, Maddingley brown coal is distinguished as having 60 per cent moisture content and a rich fulvic acid and...
- List of CO2 emitted per million Joule of energy from various fuels