Color photography
Encyclopedia


Color photography is photography
Photography
Photography is the art, science and practice of creating durable images by recording light or other electromagnetic radiation, either electronically by means of an image sensor or chemically by means of a light-sensitive material such as photographic film...

 that uses media capable of representing color
Color
Color or colour is the visual perceptual property corresponding in humans to the categories called red, green, blue and others. Color derives from the spectrum of light interacting in the eye with the spectral sensitivities of the light receptors...

s, which are traditionally produced chemically during the photographic processing phase. By contrast, black-and-white
Black-and-white
Black-and-white, often abbreviated B/W or B&W, is a term referring to a number of monochrome forms in visual arts.Black-and-white as a description is also something of a misnomer, for in addition to black and white, most of these media included varying shades of gray...

 (monochrome) photography records only a single channel of luminance
Luminance
Luminance is a photometric measure of the luminous intensity per unit area of light travelling in a given direction. It describes the amount of light that passes through or is emitted from a particular area, and falls within a given solid angle. The SI unit for luminance is candela per square...

 (brightness) and uses media capable only of showing shades of gray.

In color photography, light-sensitive chemicals or electronic sensors record color information at the time of exposure. This is usually done by analyzing the spectrum of colors into three channels of information, one dominated by red, another by green and the third by blue, in imitation of the way the normal human eye senses color. The recorded information is then used to reproduce the original colors by mixing together various proportions of red, green and blue light (RGB color, used by video displays, digital projectors and some historical photographic processes), or by using dyes or pigments to remove various proportions of the red, green and blue which are present in white light
Light
Light or visible light is electromagnetic radiation that is visible to the human eye, and is responsible for the sense of sight. Visible light has wavelength in a range from about 380 nanometres to about 740 nm, with a frequency range of about 405 THz to 790 THz...

 (CMY color
CMYK color model
The CMYK color model is a subtractive color model, used in color printing, and is also used to describe the printing process itself. CMYK refers to the four inks used in some color printing: cyan, magenta, yellow, and key...

, used for prints on paper and transparencies on film).

Monochrome images which have been "colorized" by tinting selected areas by hand or mechanically or with the aid of a computer are "colored photographs," not "color photographs." Their colors are not dependent on the actual colors of the objects photographed and may be very inaccurate or completely imaginary.

Early experiments

Color photography was attempted beginning in the 1840s. Early experiments were directed at finding a "chameleon substance" which would assume the color of the light falling on it. Some encouraging early results, typically obtained by projecting a solar spectrum
Spectrum
A spectrum is a condition that is not limited to a specific set of values but can vary infinitely within a continuum. The word saw its first scientific use within the field of optics to describe the rainbow of colors in visible light when separated using a prism; it has since been applied by...

 directly onto the sensitive surface, seemed to promise eventual success, but the comparatively dim image formed in a camera required exposures lasting for hours or even days. The quality and range of the color was sometimes severely limited, as in the chemically complicated "Hillotype" process invented by American Daguerreotypist Levi Hill
Levi Hill
Levi Hill was an American minister in Upstate New York who claimed to have invented the first color photographic process in 1850. Hill called his process "Heliochromy", though the plates created became commonly referred to as "Hillotypes"...

 around 1850. Other experimenters, such as Edmond Becquerel
A. E. Becquerel
Alexandre-Edmond Becquerel , known as Edmond Becquerel, was a French physicist who studied the solar spectrum, magnetism, electricity, and optics. He is known for his work in luminescence and phosphorescence. He is credited with the discovery of the photovoltaic effect, the operating principle of...

, achieved better results but could find no way to prevent the colors from quickly fading when the images were exposed to light for viewing. Over the following several decades, renewed experiments along these lines periodically raised hopes and then dashed them, yielding nothing of practical value.

Three-color processes

The three-color method, which is the foundation of virtually all practical color processes whether chemical or electronic, was first suggested in an 1855 paper on color vision
Color vision
Color vision is the capacity of an organism or machine to distinguish objects based on the wavelengths of the light they reflect, emit, or transmit...

 by Scottish physicist James Clerk Maxwell
James Clerk Maxwell
James Clerk Maxwell of Glenlair was a Scottish physicist and mathematician. His most prominent achievement was formulating classical electromagnetic theory. This united all previously unrelated observations, experiments and equations of electricity, magnetism and optics into a consistent theory...

.

It is based on the fact that the normal human eye sees color because its inner surface is covered with millions of intermingled cone cells
Cone cell
Cone cells, or cones, are photoreceptor cells in the retina of the eye that are responsible for color vision; they function best in relatively bright light, as opposed to rod cells that work better in dim light. If the retina is exposed to an intense visual stimulus, a negative afterimage will be...

 of three types: one more sensitive than the others to the end of the spectrum
Spectrum
A spectrum is a condition that is not limited to a specific set of values but can vary infinitely within a continuum. The word saw its first scientific use within the field of optics to describe the rainbow of colors in visible light when separated using a prism; it has since been applied by...

 we call "red", one more sensitive to the middle or "green" region, and one which is most strongly stimulated by "blue". The named colors have no objective existence in physical reality but simply describe the sensations experienced when these three types of cells are unequally stimulated by various wavelengths of light
Light
Light or visible light is electromagnetic radiation that is visible to the human eye, and is responsible for the sense of sight. Visible light has wavelength in a range from about 380 nanometres to about 740 nm, with a frequency range of about 405 THz to 790 THz...

.

From his studies of color vision, Maxwell found that any hue could be made by mixing only three pure colors of light – red, green and blue – in proportions that would stimulate the three types of cells to the same degrees that the "real" colors did. To emphasize that each type of cell by itself did not actually see color but was simply more or less stimulated, he drew an analogy to black-and-white photography: if three colorless photographs of the same scene were taken through red, green and blue filters, and transparencies ("slides") made from them were projected through the same filters and superimposed on a screen, the result would be an image reproducing not only red, green and blue, but all of the colors in the original scene.

The first color photograph made according to Maxwell's prescription, a set of three monochrome "color separations", was taken by Thomas Sutton in 1861 for use in illustrating a lecture on color by Maxwell, where it was shown in color by the triple projection method. The test subject was a bow made of ribbon with stripes of various colors, apparently including red and green. During the lecture, which was about physics and physiology, not photography, Maxwell commented on the inadequacy of the results and the need for a photographic material more sensitive to red and green light. A century later, historians were mystified by the reproduction of any red at all, because the photographic process used by Sutton was for all practical purposes totally insensitive to red light and only marginally sensitive to green. In 1961, researchers found that many red dyes also reflect ultraviolet light, coincidentally transmitted by Sutton’s red filter, and surmised that the three images were probably due to ultra-violet, blue-green and blue wavelengths, rather than to red, green and blue.

Maxwell's 1855 suggestion and this seriously defective 1861 demonstration appear to have been quickly and completely forgotten until being brought to light again in the 1890s. In the intervening decades, the basic concept was independently re-invented by several people.

Additive color

Creating colors by mixing together colored lights (usually red, green and blue) in various proportions is the additive method of color reproduction. LCD, LED, plasma and CRT (picture tube) color video displays all use this method. If one of these displays is examined with a sufficiently strong magnifier, it will be seen that each pixel is actually composed of red, green and blue sub-pixels which blend together at normal viewing distances, reproducing a wide range of colors as well as white and shades of gray. This is also known as the RGB color model
RGB color model
The RGB color model is an additive color model in which red, green, and blue light is added together in various ways to reproduce a broad array of colors...

.

Subtractive color

The same three images taken through red, green and blue filters which are used for additive color synthesis may also be used to produce color prints and transparencies by the subtractive method, in which colors are subtracted from white light by dyes or pigments. In photography, the dye colors are normally cyan, a greenish-blue which absorbs red; magenta, a purplish-pink which absorbs green; and yellow, which absorbs blue. The red-filtered image is used to create a cyan dye image, the green-filtered image to create a magenta dye image, and the blue-filtered image to create a yellow dye image. When the three dye images are superimposed they form a complete color image.

This is also known as the CMYK color model
CMYK color model
The CMYK color model is a subtractive color model, used in color printing, and is also used to describe the printing process itself. CMYK refers to the four inks used in some color printing: cyan, magenta, yellow, and key...

. The "K" is a black component normally added in ink-jet and other mechanical printing processes to compensate for the imperfections of the colored inks used, which ideally should absorb or transmit various parts of the spectrum but not reflect any color, and to improve image definition.

At first it may seem that each image ought to be printed in the color of the filter used in making it, but by following any given color through the process the reason for printing in complimentary colors should become apparent. A red object, for example, will be very pale in the red-filtered image but very dark in the other two images, so the result will be an area with just a trace of cyan, absorbing just a bit of red light, but a large amount of magenta and yellow, which together absorb most of the green and blue light, leaving mainly red light to be reflected back from the white paper in the case of a print, or transmitted through a clear support in the case of a transparency.

Before the technical innovations of the years 1935 to 1942, the only way to create a subtractive full-color print or transparency was by means of one of several labor-intensive and time-consuming procedures. Most commonly, three pigment images were first created separately by the so-called carbon process
Carbon print
A carbon print is a photographic print with an image consisting of pigmented gelatin, rather than of silver or other metallic particles suspended in a uniform layer of gelatin, as in typical black-and-white prints, or of chromogenic dyes, as in typical photographic color prints.In the original...

 and then carefully combined in register. Sometimes, related processes were used to make three gelatin matrices which were dyed and assembled or used to transfer the three dye images into a single layer of gelatin coated on a final support. Chemical toning could be used to convert three black-and-white silver images into cyan, magenta and yellow images which were then assembled. In a few processes, the three images were created one on top of another by repeated coating or re-sensitizing, negative registration, exposure and development operations. A number of variations were devised and marketed during the first half of the 20th century, some of them short-lived, others, such as the Trichrome Carbro process, enduring for several decades. Because some of these processes allow very stable and light-fast coloring matter to be used, yielding images which can remain virtually unchanged for centuries, they are still not quite completely extinct.

The production of photographic three-color prints on paper was pioneered by Louis Ducos du Hauron
Louis Ducos du Hauron
Louis Arthur Ducos du Hauron was a French pioneer of color photography. He was born in Langon, Gironde and died in Agen....

, whose comprehensive 1868 French patent also included the basic concepts of most of the color photographic processes which were subsequently developed. For making the three color-filtered negatives required, he was able to develop materials and methods which were not as completely blind to red and green light as those used by Thomas Sutton in 1861, but they were still very insensitive to those colors. Exposure times were impractically long, the red or orange-filtered negative requiring hours of exposure in the camera. His earliest surviving color prints are "sun prints" of pressed flowers and leaves, each of the three negatives having been made without a camera by exposing the light-sensitive surface to direct sunlight passing first through a color filter and then through the vegetation.

Color sensitization

As long as photographic materials were usefully sensitive only to blue-green, blue, violet and ultraviolet, three-color photography could never be practical. In 1873 German chemist Hermann Wilhelm Vogel discovered that the addition of small amounts of certain aniline dyes to a photographic emulsion could add sensitivity to colors which the dyes absorbed. He identified dyes which variously sensitized for all the previously ineffective colors except true red, to which only a marginal trace of sensitivity could be added. In the following year, Edmond Becquerel discovered that chlorophyll was a good sensitizer for red. Although it would be many more years before these sensitizers (and better ones developed later) found much use beyond scientific applications such as spectrography, they were quickly and eagerly adopted by Louis Ducos du Hauron, Charles Cros and other color photography pioneers. Exposure times for the "problem" colors could now be reduced from hours to minutes. As ever-more-sensitive gelatin emulsions replaced the old wet and dry collodion processes, the minutes became seconds. New sensitizing dyes introduced early in the 20th century eventually made so-called "instantaneous" color exposures possible.

Color cameras

Making color separations by reloading the camera and changing the filter between exposures was inconvenient, added delays to the already long exposure times and could result in the camera being accidentally shifted out of position. To improve the actual picture-taking, a number of experimenters designed one or more special cameras for color photography. They were usually of two main types.

The first type used a system of partially-reflecting surfaces to divide the light coming through the lens into three parts, each part passing through a different color filter and forming a separate image, so that the three images could be photographed at the same time on three plates (flexible film had not yet replaced glass plates as the support for the emulsion) or different areas of one plate. Later known as "one-shot" cameras, refined versions continued to be used as late as the 1950s for special purposes such as commercial photography for publication, in which a set of color separations was ultimately required in order to prepare printing plates.

The second type, known variously as a multiple back, repeating back or drop back camera, still exposed the images one at a time but used a sliding holder for the filters and plates which allowed each filter and the corresponding unexposed area of emulsion to be quickly shifted into place. German photochemistry professor Adolf Miethe designed a high-quality camera of this type which was commercially introduced by Bermpohl in 1903. It was probably this Miethe-Bermpohl camera which was used by Miethe's pupil Sergei Mikhailovich Prokudin-Gorskii
Sergei Mikhailovich Prokudin-Gorskii
Sergey Mikhaylovich Prokudin-Gorsky was a Russian chemist and photographer. He is best known for his pioneering work in color photography of early 20th-century Russia.. Library of Congress. Retrieved 13 August 2006.-Early life:...

 to make his now-celebrated color photographic surveys of Russia before the 1917 revolution. One sophisticated variant, patented by Frederic Eugene Ives in 1897, was driven by clockwork and could be adjusted to automatically make each of the exposures for a different length of time according to the particular color sensitivities of the emulsion being used.

Otherwise simple cameras with multiple color-filtered lenses were sometimes tried, but unless everything in the scene was at a great distance, or all in a plane at the same distance, the difference in the viewpoints of the lenses (parallax
Parallax
Parallax is a displacement or difference in the apparent position of an object viewed along two different lines of sight, and is measured by the angle or semi-angle of inclination between those two lines. The term is derived from the Greek παράλλαξις , meaning "alteration"...

) made it impossible to completely "register" all parts of the resulting images at the same time.

Color photography leaves the laboratory

Prior to the late 1890s, color photography was strictly the domain of a very few intrepid experimenters willing to build their own equipment, do their own color-sensitizing of photographic emulsions, make and test their own color filters and otherwise devote a large amount of time and effort to their pursuits. There were many opportunities for something to go wrong during the series of operations required and problem-free results were rare. Most photographers still regarded the whole idea of color photography as a pipe dream, something only madmen and swindlers would claim to have accomplished.

In 1898, however, it was possible for anyone with the price in hand to buy the required equipment and supplies ready-made. Two adequately red-sensitive photographic plates were already on the market, and two very different systems of color photography with which to use them, tantalizingly described in photographic magazines for several years past, were finally available to the public.

The most extensive and expensive of the two was the "Kromskop" system developed by Frederic Eugene Ives. This was a straightforward additive system and its essential elements had been described by James Clerk Maxwell, Louis Ducos du Hauron and Charles Cros much earlier, but Ives invested years of careful work and ingenuity in refining the methods and materials to optimize color quality, in overcoming problems inherent in the optical systems involved, and in simplifying the apparatus to bring down the cost of producing it commercially. The color images, dubbed "Kromograms," were in the form of sets of three black-and-white transparencies on glass, mounted onto special cloth-tape-hinged triple cardboard frames. To see a Kromogram in color it had to be inserted into a "Kromskop" (generic name "chromoscope" or "photochromoscope"), a viewing device which used an arrangement of colored glass filters to illuminate each slide with the correct color of light and transparent reflectors to visually combine them into a single full-color image. The most popular model was stereoscopic. By looking through its pair of lenses, an image in full natural color and 3-D was seen, a startling novelty in the late Victorian age.

The results won near-universal praise for excellence and realism. At demonstrations, Ives sometimes placed a viewer displaying a still-life subject next to the actual objects photographed, inviting direct comparison. A Kromskop triple "lantern" could be used to project the three images, mounted in a special metal or wooden frame for this purpose, through filters as Maxwell had done in 1861. Prepared Kromograms of still-life subjects, landscapes, famous buildings and works of art were sold and these were the Kromskop viewer's usual fodder, but a "multiple back" camera attachment and a set of three specially adjusted color filters could be bought by "Kromskopists" wishing to make their own Kromograms.

Kromskops and ready-made Kromograms were bought by educational institutions for their value in teaching about color and color vision, and by individuals who were in a position to pay a substantial sum for an intriguing optical toy. A few people did, indeed, make their own Kromograms. Unfortunately for Ives, this was not enough to sustain the businesses which had been set up to exploit the system and they soon failed, but the viewers, projectors, Kromograms and several varieties of Kromskop cameras and camera attachments continued to be available through the Scientific Shop in Chicago as late as 1907.

The Screen Plate era

The simpler and somewhat more economical alternative was the Joly Screen process. This required no special camera or viewer, just a special color-compensating filter for the camera lens and a special holder for the photographic plates. The holder contained the heart of the system: a clear glass plate on which very fine lines of three colors had been ruled in a regular repeating pattern, completely covering its surface. The idea was that instead of taking three separate complete photographs through three colored filters, the filters could be in the form of a large number of very narrow strips (the colored lines) allowing the necessary color information to be recorded in a single compound image. After the negative was developed, a positive transparency was printed from it and a viewing screen with red, green and blue lines in the same pattern as the lines of the taking screen was applied and carefully aligned. The colors then appeared as if by magic. The transparency and screen were very like the layer of monochrome liquid crystal elements and overlay of hair-thin red, green and blue color filter stripes which create the color image in a typical LCD display. This was the invention of Irish scientist John Joly, although he, like so many other inventors, eventually discovered that his basic concept had been anticipated in Louis Ducos du Hauron's long-since-expired 1868 patent.

The Joly Screen process had some problems. First and foremost, although the colored lines were reasonably fine (about 75 sets of three colored lines to the inch) they were still disturbingly visible at normal viewing distances and nearly intolerable when enlarged by projection. This problem was exacerbated by the fact that each screen was individually ruled on a machine which used three pens to apply the transparent colored inks, resulting in irregularities, high reject rates and high cost. The glass used for photographic plates at the time was not perfectly flat, and lack of uniform good contact between the screen and the image gave rise to areas of degraded color. Poor contact also caused false colors to appear if the sandwich was viewed at an angle. Although much simpler than the Kromskop system, the Joly system was not inexpensive. The starter kit of plate holder, compensating filter, one taking screen and one viewing screen cost $30 (the equivalent of at least $750 in 2010 dollars) and additional viewing screens were $1 each (the equivalent of at least $25 in 2010 dollars). This system, too, soon died of neglect, although in fact it pointed the way to the future.

Surviving examples of the Joly process usually show extremely poor color now. The colors in the viewing screens have badly faded and shifted, making it impossible to judge their original appearance. In some specimens the viewing screen is also misaligned.

The first commercially successful color process, the Lumière Autochrome
Autochrome Lumière
The Autochrome Lumière is an early color photography process. Patented in 1903 by the Lumière brothers in France and first marketed in 1907, it was the principal color photography process in use before the advent of subtractive color film in the mid-1930s....

, invented by the French Lumière brothers
Auguste and Louis Lumière
The Lumière brothers, Auguste Marie Louis Nicolas and Louis Jean , were among the earliest filmmakers in history...

, reached the market in 1907. It was based on an irregular screen plate filter made of dyed grains of potato starch
Potato starch
Potato starch is starch extracted from potatoes. The cells of the root tubers of the potato plant contain starch grains . To extract the starch, the potatoes are crushed; the starch grains are released from the destroyed cells...

 which were too small to be individually visible. The light-sensitive emulsion was coated directly onto the screen, eliminating problems due to imperfect contact between the screen and image. Reversal processing was used to convert the negative image which was initially produced into a positive image, so no printing or screen registration was required. The shortcomings of the Autochrome process were the expense (one plate cost about as much as a dozen black-and-white plates of the same size), the relatively long exposure times which made hand-held "snapshots" and photographs of moving subjects impractical, and the density of the finished image due to the presence of the light-absorbing color screen.

Viewed under optimum conditions and by daylight as intended, a well-made and well-preserved Autochrome can look startlingly fresh and vivid. Unfortunately, modern film and digital copies are usually made with a highly diffused light source, which causes loss of color saturation and other ill effects due to light scatter within the structure of the screen and emulsion, and by fluorescent or other artificial light which alters the color balance. The capabilities of the process should not be judged by the dull, washed-out, odd-colored reproductions commonly seen.

Millions of Autochrome plates were manufactured and used during the quarter century before the plates were replaced by film-based versions in the 1930s. The very last film version, named Alticolor, brought the Autochrome process into the 1950s but was discontinued in 1955. Many additive color screen products were available between the 1890s and the 1950s, but none, with the possible exception of Dufaycolor
Dufaycolor
Dufaycolor is an early French and British additive color photographic film process for motion pictures and stills photography. It was based on a four-color screen photographic process invented in 1908 by Frenchman Louis Dufay...

, introduced as film for still photography in 1935, was as popular or successful as the Lumière Autochrome. The presumably final use of the additive screen process for non-digital photography was in Polachrome, an "instant" 35mm slide film introduced in 1983 and discontinued about twenty years later.

Tripacks

Louis Ducos du Hauron had suggested using a sandwich of three differently color-recording emulsions on transparent supports which could be exposed together in an ordinary camera, then taken apart and used like any other set of three-color separations. The problem was that although two of the emulsions could be in contact face-to-face, the third would have to be separated by the thickness of one transparent support layer. Because all silver halide emulsions are inherently sensitive to blue, the blue-recording layer ought to be on top and have a blue-blocking yellow filter layer behind it. This blue-recording layer, used to make the yellow print which could most afford to be "soft," would end up producing the sharpest image. The two layers behind it, one sensitized to red but not green and the other to green but not red, would suffer from scattering of the light as it passed through the topmost emulsion, and one or both would further suffer by being spaced away from it.

Despite these limitations, some "tripacks" were commercially produced, such as the Hess-Ives "Hiblock" which sandwiched an emulsion on film between emulsions coated on glass plates. For a brief period in the early 1930s, the American Agfa-Ansco company produced Colorol, a roll-film tripack for snapshot cameras. The three emulsions were on unusually thin film bases. After exposure, the roll was sent to Agfa-Ansco for processing and the triple negatives were returned to the customer with a set of color prints. The images were not sharp and the color was not very good, but they were genuine "natural color" snapshots.

"Bipacks" using only two emulsions face-to-face were the subject of some development. Although the range of colors which could be reproduced by only two components was limited, skin tones and most hair and eye colors could be rendered with surprising fidelity, making bipack processes a viable option for color portraiture. In commercial practice, however, the use of bipacks was almost entirely confined to two-color motion picture systems.

If the three layers of emulsion in a tripack did not have to be taken apart in order to produce the cyan, magenta and yellow dye images from them, they could be coated directly on top of each other, eliminating the most serious problems. In fact, some chemical magic was under development which would make that possible.

"Modern" color film

In 1935, American Kodak introduced the first modern "integral tripack" color film and called it Kodachrome
Kodachrome
Kodachrome is the trademarked brand name of a type of color reversal film that was manufactured by Eastman Kodak from 1935 to 2009.-Background:...

, a name recycled from an earlier and completely different two-color process. Its development was led by the improbable team of Leopold Mannes
Leopold Mannes
Leopold Damrosch Mannes was a Jewish-American musician, born in New York City, who, together with Leopold Godowsky, Jr., created the first practical color transparency film, Kodachrome....

 and Leopold Godowsky, Jr.
Leopold Godowsky, Jr.
Leopold Godowsky, Jr. was an American violinist and chemist, who together with Leopold Mannes created the first practical color transparency film, Kodachrome.-Beginning:...

 (nicknamed "Man" and "God"), two highly regarded classical musicians who had started tinkering with color photographic processes and ended up working with the Kodak Research Laboratories. Kodachrome
Kodachrome
Kodachrome is the trademarked brand name of a type of color reversal film that was manufactured by Eastman Kodak from 1935 to 2009.-Background:...

 had three layers of emulsion coated on a single base, each layer recording one of the three additive primaries, red, green, and blue. In keeping with Kodak's old "you press the button, we do the rest" slogan, the film was simply loaded into the camera, exposed in the ordinary way, then mailed to Kodak for processing. The complicated part, if the complexities of manufacturing the film are ignored, was the processing, which involved the controlled penetration of chemicals into the three layers of emulsion. Only a simplified description of the process is appropriate in a short history: as each layer was developed into a black-and-white silver image, a "dye coupler" added during that stage of development caused a cyan, magenta or yellow dye image to be created along with it. The silver images were chemically removed, leaving only the three layers of dye images in the finished film.

Initially, Kodachrome
Kodachrome
Kodachrome is the trademarked brand name of a type of color reversal film that was manufactured by Eastman Kodak from 1935 to 2009.-Background:...

 was available only as 16mm film for home movies, but in 1936 it was also introduced as 8mm home movie film and short lengths of 35mm film for still photography. In 1938, sheet film in various sizes for professional photographers was introduced, some changes were made to cure early problems with unstable colors, and a somewhat simplified processing method was instituted.

In 1936, the German Agfa followed with their own integral tripack film, Agfacolor Neu
Agfacolor
thumb|An Agfacolor slide dating from the early 1940s. While the colors themselves hold up well after 60 years, damages visible include dust and [[Newton's rings]].Agfacolor is a series of color photographic products produced by Agfa of Germany...

, which was generally similar to Kodachrome but had one important advantage: Agfa had found a way to incorporate the dye couplers into the emulsion layers during manufacture, allowing all three layers to be developed at the same time and greatly simplifying the processing. Most modern color films, excepting the now-discontinued Kodachrome, use the incorporated dye coupler technique, but since the 1970s nearly all have used a modification developed by Kodak rather than the original Agfa version.

In 1941, Kodak made it possible to order prints from Kodachrome slides. The print "paper" was actually a white plastic coated with a multilayer emulsion similar to that on the film. These were the first commercially available color prints created by the chromogenic
Chromogenic
Chromogenic refers to color photographic processes in which a traditional silver image is first formed, and then later replaced with a colored dye image.- Description :...

 dye coupler method. In the following year, Kodacolor film was introduced. Unlike Kodachrome, it was designed to be processed into a negative image which showed not only light and dark reversed but also complementary colors. The use of such a negative for making prints on paper simplified the processing of the prints, reducing their cost.

The expense of color film as compared to black-and-white and the difficulty of using it with indoor lighting combined to delay its widespread adoption by amateurs. In 1950, black-and-white snapshots were still the norm. By 1960, color was much more common but still tended to be reserved for travel photos and special occasions. Color film and color prints still cost several times as much as black-and-white, and taking color snapshots in deep shade or indoors required the use of flash bulbs
Flash (photography)
A flash is a device used in photography producing a flash of artificial light at a color temperature of about 5500 K to help illuminate a scene. A major purpose of a flash is to illuminate a dark scene. Other uses are capturing quickly moving objects or changing the quality of light...

, an inconvenience and an additional expense. By 1970, prices were coming down, film sensitivity had been improved, electronic flash units
Flash (photography)
A flash is a device used in photography producing a flash of artificial light at a color temperature of about 5500 K to help illuminate a scene. A major purpose of a flash is to illuminate a dark scene. Other uses are capturing quickly moving objects or changing the quality of light...

 were replacing flash bulbs, and in most families color had become the norm for snapshot-taking. Black-and-white film continued to be used by some photographers who preferred it for aesthetic reasons or who wanted to take pictures by existing light in low-light conditions, which was still difficult to do with color film. They usually did their own developing and printing. By 1980, black-and-white film in the formats used by typical snapshot cameras, as well as commercial developing and printing service for it, had nearly disappeared.

Instant color film
Instant film
Instant film is a type of photographic film first introduced by Polaroid that is designed to be used in an instant camera...

 was introduced by Polaroid
Polaroid Corporation
Polaroid Corporation is an American-based international consumer electronics and eyewear company, originally founded in 1937 by Edwin H. Land. It is most famous for its instant film cameras, which reached the market in 1948, and continued to be the company's flagship product line until the February...

 in 1963. Like Polaroid's contemporary instant black-and-white film, their first color product was a negative-positive peel-apart process which produced a unique print on paper. The negative could not be re-used and was discarded. The blight created by carelessly discarded caustic-chemical-laden Polaroid negatives, which tended to accumulate most heavily at the prettiest, most snapshot-worthy locations, horrified Polaroid founder Edwin Land and prompted him to develop the later SX-70 system, which produced no separate negative to discard.

Current use of color film

Color film has now been relegated to a niche market by inexpensive multi-megapixel digital cameras. Film continues to be the preference of some photographers because of its high image quality (when used with a high-quality camera and lens) and its distinctive "look." In medium and large formats, its effective pixel count has not yet (as of 2010) been equaled by any commercially available and reasonably priced digital camera.

The changeover from chemical to electronic photography may prove to be comparable to the shift from black-and-white to color, in which black-and-white retained some distinctive merits and was never entirely replaced. As exampled by the discontinuation of Kodachrome, however, the variety of film types available is liable to become increasingly limited.

Some currently available color films are designed to produce positive transparencies for use in a slide projector
Slide projector
A slide projector is an opto-mechanical device to view photographic slides. Slide projectors were common in the 1950s to the 1970s as a form of entertainment; family members and friends would gather to view slide shows...

 or magnifying viewer, although paper prints can also be made from them. Transparencies are preferred by some professional photographers who use film because they can be judged without having to print them first. Transparencies are also capable of a wider dynamic range, and therefore of a greater degree of realism, than the more convenient medium of prints on paper. The early popularity of color "slides" among amateurs went into decline after the introduction of automated printing equipment started bringing print quality up and prices down.

Other currently available films are designed to produce color negatives for use in creating enlarged positive prints on color photographic paper. Color negatives may also be digitally scanned and then printed by non-photographic means or viewed as positives electronically. Unlike reversal-film transparency processes, negative-positive processes are, within limits, forgiving of incorrect exposure and poor color lighting, because a considerable degree of correction is possible at the time of printing. Negative film is therefore more suitable for casual use by amateurs. Virtually all single-use cameras employ negative film. Photographic transparencies can be made from negatives by printing them on special "positive film," but this has always been unusual outside of the motion picture industry and commercial service to do it for still images may no longer be available. Negative films and paper prints are by far the most common form of non-digital color photography today.

Preservation issues

Experimentation with creating photographs that mirrored the colors of real life began in the 1840s. Each process may require different methods of preservation.

Color photographic materials are impermanent and are by nature unstable. Chromogenic
Chromogenic
Chromogenic refers to color photographic processes in which a traditional silver image is first formed, and then later replaced with a colored dye image.- Description :...

 color photographs, for example, are composed of yellow
Yellow
Yellow is the color evoked by light that stimulates both the L and M cone cells of the retina about equally, with no significant stimulation of the S cone cells. Light with a wavelength of 570–590 nm is yellow, as is light with a suitable mixture of red and green...

, magenta
Magenta
Magenta is a color evoked by light stronger in blue and red wavelengths than in yellowish-green wavelengths . In light experiments, magenta can be produced by removing the lime-green wavelengths from white light...

, and cyan
Cyan
Cyan from , transliterated: kýanos, meaning "dark blue substance") may be used as the name of any of a number of colors in the blue/green range of the spectrum. In reference to the visible spectrum cyan is used to refer to the color obtained by mixing equal amounts of green and blue light or the...

 organic dye
Dye
A dye is a colored substance that has an affinity to the substrate to which it is being applied. The dye is generally applied in an aqueous solution, and requires a mordant to improve the fastness of the dye on the fiber....

s, which fade at different rates. Even when in dark storage and enclosed in the proper archival materials, deterioration is unavoidable. However, when given the proper preservation care, fading, color shifting, and discoloration can be delayed.

Factors

Numerous factors can deteriorate and even destroy photographs. Some examples include:
  • High temperature and high relative humidity
    Relative humidity
    Relative humidity is a term used to describe the amount of water vapor in a mixture of air and water vapor. It is defined as the partial pressure of water vapor in the air-water mixture, given as a percentage of the saturated vapor pressure under those conditions...

     (RH)
  • Air pollution
    Air pollution
    Air pollution is the introduction of chemicals, particulate matter, or biological materials that cause harm or discomfort to humans or other living organisms, or cause damage to the natural environment or built environment, into the atmosphere....

     and dirt
  • Light exposure
  • Biological threats such as fungi
    Fungus
    A fungus is a member of a large group of eukaryotic organisms that includes microorganisms such as yeasts and molds , as well as the more familiar mushrooms. These organisms are classified as a kingdom, Fungi, which is separate from plants, animals, and bacteria...

     and insect
    Insect
    Insects are a class of living creatures within the arthropods that have a chitinous exoskeleton, a three-part body , three pairs of jointed legs, compound eyes, and two antennae...

    s
  • Residual processing chemicals
  • Base and emulsion deterioration
  • Handling and usage
  • Improper storage and enclosures


Three signs of age that affect color photography are:
  • Dark fading occurs regardless of the procedures taken to preserve a photograph and is unavoidable. It is instigated by temperature and RH. Cyan dyes will typically fade more quickly, which will make the image appear too red in color.

  • Light fading occurs when materials are exposed to light, e.g. while on display. The intensity of the light source and ultraviolet (UV) rays will affect the rate of change and fade. Magenta dyes will typically fade the quickest.

  • Highlight staining occurs with older color photographic papers, and is a yellowing of the border and highlight areas of a photograph.

Storage

In general, the colder the storage, the longer the "life" of color photographs. Frost-free refrigeration, more commonly known as cold storage (below freezing) is one of the most effective ways to bring a halt to developing damage to color photographic materials. Selecting this type of storage environment is costly and requires special training to remove and return items. Therefore, cool storage (above freezing) is more common and less costly, which requires that the temperature is consistently between 10 – with 30–40% relative humidity with special attention to dew point to eliminate concerns for condensation. General dark storage in light tight enclosures and storage boxes is always advised for individual items. When materials are exposed to light during handling, usage, or display, light sources should be UV-filtered and intensity kept at minimum. In storage areas, 200–400 lux
Lux
The lux is the SI unit of illuminance and luminous emittance, measuring luminous flux per unit area. It is used in photometry as a measure of the intensity, as perceived by the human eye, of light that hits or passes through a surface...

 is recommended.

Recommended storage

The usage of enclosures is the easiest method of preserving photographic materials from being damaged through handling and light exposure. All protective materials should pass the Photographic Activity Test
Photographic Activity Test
Photographic Activity Test is an ISO standard test detailed in ISO 18916:2007 . Previous versions of the standard were numbered ISO 14523:1999, however it was updated and renumbered in 2007....

(PAT) as described both by the American National Standards Institute
American National Standards Institute
The American National Standards Institute is a private non-profit organization that oversees the development of voluntary consensus standards for products, services, processes, systems, and personnel in the United States. The organization also coordinates U.S. standards with international...

 (ANSI) in standard IT9.2-1988, and the International Organization for Standardization
International Organization for Standardization
The International Organization for Standardization , widely known as ISO, is an international standard-setting body composed of representatives from various national standards organizations. Founded on February 23, 1947, the organization promulgates worldwide proprietary, industrial and commercial...

 (ISO) in standard 18916:2007(E), Photography – Processed Photographic Materials – Photographic Activity Test for Enclosure Materials. The PAT is an archival science
Archival science
Archival science is the theory and study of storing, cataloguing, and retrieving documents and items. Archival science evolved from mankind's need to classify the world around them...

 test that determines what kind of enclosures will preserve, prevent, and/or prolong from further deterioration while in storage.

The recommended use of archival enclosures includes each item having its own enclosure and that each enclosure is of the appropriate size. Archival enclosures may come in two different forms: paper or plastic. Choosing either option has its advantages and disadvantages.
  • Paper enclosures should be non-acidic, lignin-free paper and may come in either buffered or non-buffered stock. An advantage of paper is that it is generally less costly than plastic enclosures. The opaque quality of paper protects photographs from light exposure, and the porous quality protects photographs from humidity and gaseous pollutants. However, for images to be viewed, they must be removed from the enclosure, putting the materials at risk for mishandling and/or vandalism.

  • Archival quality plastic enclosures are made of uncoated polyester, polypropylene, or polyethylene. The transparent quality of plastic lends itself to easier access to the image because there is no extra step to remove the photograph. Plastic is also less resistant to tears in comparison to paper. Some disadvantages include being prone to static electricity and a risk of ferrotyping (the act of moisture becoming trapped between the enclosure and item, causing the materials to stick to one another).


After photographic materials are individually enclosed, housing or storage containers provide another protective barrier such as folders and boxes made from archival paperboard as addressed in ISO Standards 18916:2007 and 18902. Sometimes these containers have to be custom-made in order to properly store odd sizes. In general, flat storage of in boxes is recommended because it provides more stable support, particularly for materials that are in more fragile condition. Still, boxes and folders should never be over-filled with materials.

People

  • George Eastman
    George Eastman
    George Eastman was an American innovator and entrepreneur who founded the Eastman Kodak Company and invented roll film, helping to bring photography to the mainstream...

  • William Eggleston
    William Eggleston
    William Eggleston , is an American photographer. He is widely credited with increasing recognition for color photography as a legitimate artistic medium to display in art galleries—which, until the 1970s, often tended to privilege work by photographers making black-and-white prints.- Early years...

  • Sergey Prokudin-Gorsky
  • Gabriel Lippmann
    Gabriel Lippmann
    Jonas Ferdinand Gabriel Lippmann was a Franco-Luxembourgish physicist and inventor, and Nobel laureate in physics for his method of reproducing colours photographically based on the phenomenon of interference....

  • Luis Marden
    Luis Marden
    Luis Marden was an American photographer, explorer, writer, filmmaker, diver, navigator, and linguist who worked for National Geographic Magazine. He worked as a photographer and reporter before serving as chief of the National Geographic foreign editorial staff...

  • Stephen Shore
    Stephen Shore
    Stephen Shore is an American photographer known for his deadpan images of banal scenes and objects in the United States, and for his pioneering use of color in art photography.- Life and work :...

  • Jules Gervais-Courtellemont
    Jules Gervais-Courtellemont
    Jules Gervais-Courtellemont was a French photographer who was famous for taking color autochromes during World War I. He was born in the province of Seine-et-Marne, near Paris, but grew up in Algeria, where he developed a passion for the pre-colonial Orient and devoted most of his professional...

  • Léon Gimpel
    Léon Gimpel
    Léon Gimpel was a French photographer.Born in Paris in 1878 , Gimpel worked for his family's fabric company, managed by his older brother Eugene. In 1897 his interest in photography was kindled when he acquired a Kodak detective camera, he soon swapped this for a Spido Gaumont which allowed him...


Other topics

  • Hand-coloring
    Hand-colouring
    Hand-colouring refers to any method of manually adding colour to a black-and-white photograph, generally either to heighten the realism of the photograph or for artistic purposes...

     (easily mistaken for early color photography)
  • Color motion picture film
  • Chromogenic
    Chromogenic
    Chromogenic refers to color photographic processes in which a traditional silver image is first formed, and then later replaced with a colored dye image.- Description :...

  • Color printing
    Color printing
    Color printing or Colour printing is the reproduction of an image or text in color...

  • Color television
    Color television
    Color television is part of the history of television, the technology of television and practices associated with television's transmission of moving images in color video....

  • Film colorization
    Film colorization
    Film colorization is any process that adds color to black-and-white, sepia or monochrome moving-picture images. It may be done as a special effect, or to modernize black-and-white films, or to restore color films...

  • Potassium ferricyanide
    Potassium ferricyanide
    Potassium ferricyanide is the chemical compound with the formula K3[Fe6]. This bright red salt contains the octahedrally coordinated [Fe6]3− ion. It is soluble in water and its solution shows some green-yellow fluorescence.-Preparation:...

  • Timeline of historic inventions
  • Photochrome
  • The Shackleton Expedition, on which Paget color photography was used, among other types

External links


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Standards

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