Fluorosilicate glass
Encyclopedia
Fluorosilicate glass is a low-k dielectric used in between copper metal layers during silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...

 integrated circuit
Integrated circuit
An integrated circuit or monolithic integrated circuit is an electronic circuit manufactured by the patterned diffusion of trace elements into the surface of a thin substrate of semiconductor material...

 fabrication process. It has a low dielectric constant
Dielectric constant
The relative permittivity of a material under given conditions reflects the extent to which it concentrates electrostatic lines of flux. In technical terms, it is the ratio of the amount of electrical energy stored in a material by an applied voltage, relative to that stored in a vacuum...

 (k) and is now widely adopted by semiconductor foundries on geometries sub 0.25μ.
Fluorosilicate glass is effectively a fluorine
Fluorine
Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...

-containing silicon dioxide
Silicon dioxide
The chemical compound silicon dioxide, also known as silica , is an oxide of silicon with the chemical formula '. It has been known for its hardness since antiquity...

 (k=3.5, while k of undoped silicon dioxide is 3.9).
Fluorosilicate glass is used by IBM
IBM
International Business Machines Corporation or IBM is an American multinational technology and consulting corporation headquartered in Armonk, New York, United States. IBM manufactures and sells computer hardware and software, and it offers infrastructure, hosting and consulting services in areas...

. Intel started using Cu metal layers and FSG on its 1.2 GHz Pentium processor at 130 nm CMOS
CMOS
Complementary metal–oxide–semiconductor is a technology for constructing integrated circuits. CMOS technology is used in microprocessors, microcontrollers, static RAM, and other digital logic circuits...

. TSMC
TSMC
Taiwan Semiconductor Manufacturing Company, Limited or TSMC is the world's largest dedicated independent semiconductor foundry, with its headquarters and main operations located in the Hsinchu Science Park in Hsinchu, Taiwan.-Overview:...

 (Taiwan Semiconductor Manufacturing Company) brought in FSG and copper together in the Altera
Altera
Altera Corporation is a Silicon Valley manufacturer of PLDs . The company offered its first programmable logic device in 1984. PLDs can be reprogrammed during the design cycle as well as in the field to perform multiple functions, and they support a fairly fast design process...

 APEX.

Fluorosilicate glass-ceramic
Glass-ceramic
Glass-ceramics are polycrystalline material produced through controlled crystallization of base glass. Glass-ceramic materials share many properties with both glasses and ceramics...

s have good mechanical properties. Potassium fluorrichterite based materials are composed from tiny interlocked rod-shaped amphibole
Amphibole
Amphibole is the name of an important group of generally dark-colored rock-forming inosilicate minerals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures.-Mineralogy:...

 crystals; they have good resistance to chemicals and can be used in microwave oven
Microwave oven
A microwave oven is a kitchen appliance that heats food by dielectric heating, using microwave radiation to heat polarized molecules within the food...

s. Richterite
Richterite
Richterite is a sodium calcium magnesium silicate mineral belonging to the amphibole group. If iron replaces the magnesium within the structure of the mineral, it is called ferrorichterite; if fluorine replaces the hydroxyl, it is called fluororichterite. Richterite crystals are long and prismatic,...

 glass-ceramics are used for high-performance tableware
Tableware
Tableware is the dishes or dishware , dinnerware , or china used for setting a table, serving food, and for dining. Tableware can be meant to include flatware and glassware...

.

Fluorosilicate glass-ceramics with sheet structure, derived from mica
Mica
The mica group of sheet silicate minerals includes several closely related materials having highly perfect basal cleavage. All are monoclinic, with a tendency towards pseudohexagonal crystals, and are similar in chemical composition...

, are strong and machinable. They find a number of uses and can be used in high vacuum and as dielectrics and precision ceramic components. A number of mica and mica-fluoroapatite glass-ceramics were studied as biomaterial
Biomaterial
A biomaterial is any matter, surface, or construct that interacts with biological systems. The development of biomaterials, as a science, is about fifty years old. The study of biomaterials is called biomaterials science. It has experienced steady and strong growth over its history, with many...

s.
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