Gelcoat
Encyclopedia
Gelcoat is a material used to provide a high-quality finish on the visible surface of a fibre-reinforced composite material
. The most common gelcoats are based on epoxy
or unsaturated polyester
resin
chemistry. Gelcoats are modified resins which are applied to moulds in the liquid state. They are cured to form crosslinked polymer
s and are subsequently backed with composite polymer matrices, often mixtures of polyester resin and fiberglass
or epoxy resin with glass.
The manufactured component, when sufficiently cured
and removed from the mold, presents the gelcoated surface. This is usually pigment
ed to provide a coloured, glossy surface which improves the aesthetic appearance of the article, such as a counter made with cultured marble.
Many marine craft and aircraft are manufactured using composite materials with an outer layer of gelcoat, typically 0.5 mm to 0.8 mm (0.02 in to 0.03 in) thick. Gelcoats are designed to be durable, providing resistance to ultraviolet
degradation and hydrolysis
.
Specialized gelcoats can be used to manufacture the moulds which in turn are used to manufacture components. These require very high levels of durability to overcome the mechanical and thermal stresses
encountered during the curing and demoulding processes.
Suitable resin chemistries for the manufacture of gelcoats vary, but the most commonly encountered are unsaturated
polyesters or epoxies. Within each of these categories, the resin chemistries are further subdivided.
In addition to any pigment a gelcoat will, if necessary, contain a thixotropic
additive to assist its tenacity to vertical portions of the mould whilst it cures.
Composite material
Composite materials, often shortened to composites or called composition materials, are engineered or naturally occurring materials made from two or more constituent materials with significantly different physical or chemical properties which remain separate and distinct at the macroscopic or...
. The most common gelcoats are based on epoxy
Epoxy
Epoxy, also known as polyepoxide, is a thermosetting polymer formed from reaction of an epoxide "resin" with polyamine "hardener". Epoxy has a wide range of applications, including fiber-reinforced plastic materials and general purpose adhesives....
or unsaturated polyester
Polyester
Polyester is a category of polymers which contain the ester functional group in their main chain. Although there are many polyesters, the term "polyester" as a specific material most commonly refers to polyethylene terephthalate...
resin
Resin
Resin in the most specific use of the term is a hydrocarbon secretion of many plants, particularly coniferous trees. Resins are valued for their chemical properties and associated uses, such as the production of varnishes, adhesives, and food glazing agents; as an important source of raw materials...
chemistry. Gelcoats are modified resins which are applied to moulds in the liquid state. They are cured to form crosslinked polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...
s and are subsequently backed with composite polymer matrices, often mixtures of polyester resin and fiberglass
Fiberglass
Glass fiber is a material consisting of numerous extremely fine fibers of glass.Glassmakers throughout history have experimented with glass fibers, but mass manufacture of glass fiber was only made possible with the invention of finer machine tooling...
or epoxy resin with glass.
The manufactured component, when sufficiently cured
Curing (chemistry)
Curing is a term in polymer chemistry and process engineering that refers to the toughening or hardening of a polymer material by cross-linking of polymer chains, brought about by chemical additives, ultraviolet radiation, electron beam or heat...
and removed from the mold, presents the gelcoated surface. This is usually pigment
Pigment
A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, in which a material emits light.Many materials selectively absorb...
ed to provide a coloured, glossy surface which improves the aesthetic appearance of the article, such as a counter made with cultured marble.
Many marine craft and aircraft are manufactured using composite materials with an outer layer of gelcoat, typically 0.5 mm to 0.8 mm (0.02 in to 0.03 in) thick. Gelcoats are designed to be durable, providing resistance to ultraviolet
Ultraviolet
Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...
degradation and hydrolysis
Hydrolysis
Hydrolysis is a chemical reaction during which molecules of water are split into hydrogen cations and hydroxide anions in the process of a chemical mechanism. It is the type of reaction that is used to break down certain polymers, especially those made by condensation polymerization...
.
Specialized gelcoats can be used to manufacture the moulds which in turn are used to manufacture components. These require very high levels of durability to overcome the mechanical and thermal stresses
Stress (physics)
In continuum mechanics, stress is a measure of the internal forces acting within a deformable body. Quantitatively, it is a measure of the average force per unit area of a surface within the body on which internal forces act. These internal forces are a reaction to external forces applied on the body...
encountered during the curing and demoulding processes.
Suitable resin chemistries for the manufacture of gelcoats vary, but the most commonly encountered are unsaturated
Saturation (chemistry)
In chemistry, saturation has six different meanings, all based on reaching a maximum capacity...
polyesters or epoxies. Within each of these categories, the resin chemistries are further subdivided.
In addition to any pigment a gelcoat will, if necessary, contain a thixotropic
Thixotropy
Thixotropy is the property of certain gels or fluids that are thick under normal conditions, but flow over time when shaken, agitated, or otherwise stressed...
additive to assist its tenacity to vertical portions of the mould whilst it cures.