Gossan
Encyclopedia
Gossan is intensely oxidized, weathered
Weathering
Weathering is the breaking down of rocks, soils and minerals as well as artificial materials through contact with the Earth's atmosphere, biota and waters...

 or decomposed rock, usually the upper and exposed part of an ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....

 deposit or mineral vein. In the classic gossan or iron cap all that remains is iron oxide
Iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides.Iron oxides and oxide-hydroxides are widespread in nature, play an important role in many geological and biological processes, and are widely utilized by humans, e.g.,...

s and quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

 often in the form of boxworks, quartz lined cavities retaining the shape of the dissolved ore minerals. In other cases quartz and iron oxides, limonite
Limonite
Limonite is an ore consisting in a mixture of hydrated iron oxide-hydroxide of varying composition. The generic formula is frequently written as FeO·nH2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.Together with hematite, it has...

, goethite
Goethite
Goethite , named after the German polymath Johann Wolfgang von Goethe, is an iron bearing oxide mineral found in soil and other low-temperature environments. Goethite has been well known since prehistoric times for its use as a pigment. Evidence has been found of its use in paint pigment samples...

, and jarosite
Jarosite
Jarosite is a basic hydrous sulfate of potassium and iron with a chemical formula of KFe3+362. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides...

, exist as pseudomorphs replacing the pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...

 and primary ore minerals. Frequently gossan appears as a red stain against the background rock and soil due to the abundance of oxidized iron and the gossan may be a topographic
Topography
Topography is the study of Earth's surface shape and features or those ofplanets, moons, and asteroids...

 positive area due to the abundance of erosion
Erosion
Erosion is when materials are removed from the surface and changed into something else. It only works by hydraulic actions and transport of solids in the natural environment, and leads to the deposition of these materials elsewhere...

 resistant quartz and iron oxides.

In the 19th and 20th centuries gossans were important guides to buried ore deposits used by prospectors in their quest for metal ores. An experienced prospector could read the clues in the structure of the gossans to determine the type of mineralization likely to be found below the iron cap.
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