Magnetic ionic liquid
Encyclopedia
A magnetic ionic liquid was identified by Satoshi Hayashi and Hiro-o Hamaguchi of the University of Tokyo
in 2004 as an ionic liquid
based on the imidazole
1-butyl-3-methylimidazolium chloride and ferric chloride.
Due to the presence of high spin FeCl4−, the liquid is paramagnetic
and a magnetic susceptibility
of 40.6 × 10-6 emu g-1 is reported. A simple magnet suffices to attract the liquid in a test tube.
University of Tokyo
, abbreviated as , is a major research university located in Tokyo, Japan. The University has 10 faculties with a total of around 30,000 students, 2,100 of whom are foreign. Its five campuses are in Hongō, Komaba, Kashiwa, Shirokane and Nakano. It is considered to be the most prestigious university...
in 2004 as an ionic liquid
Ionic liquid
An ionic liquid is a salt in the liquid state. In some contexts, the term has been restricted to salts whose melting point is below some arbitrary temperature, such as . While ordinary liquids such as water and gasoline are predominantly made of electrically neutral molecules, ILs are largely made...
based on the imidazole
Imidazole
Imidazole is an organic compound with the formula C3H4N2. This aromatic heterocyclic is a diazole and is classified as an alkaloid. Imidazole refers to the parent compound, whereas imidazoles are a class of heterocycles with similar ring structure, but varying substituents...
1-butyl-3-methylimidazolium chloride and ferric chloride.
Due to the presence of high spin FeCl4−, the liquid is paramagnetic
Paramagnetism
Paramagnetism is a form of magnetism whereby the paramagnetic material is only attracted when in the presence of an externally applied magnetic field. In contrast with this, diamagnetic materials are repulsive when placed in a magnetic field...
and a magnetic susceptibility
Magnetic susceptibility
In electromagnetism, the magnetic susceptibility \chi_m is a dimensionless proportionality constant that indicates the degree of magnetization of a material in response to an applied magnetic field...
of 40.6 × 10-6 emu g-1 is reported. A simple magnet suffices to attract the liquid in a test tube.