Metatorbernite
Encyclopedia
Metatorbernite is a radioactive
phosphate mineral
, and is a dehydration
pseudomorph
of torbernite
. Chemically, it is a copper
uranyl
phosphate
and usually occurs in the form of green platy deposits. It can form by direct deposition from a supersaturated
solution, which produces true crystalline metatorbernite, with a dark green colour, translucent diaphaneity, and vitreous lustre. However, more commonly, it is formed by the dehydration of torbernite, which causes internal stress and breakage within the crystal lattice
, resulting in crystals composed of microscopic powder held together using electrostatic
force, and having a lighter green colour, opaque diaphaneity, and a relatively dull lustre. As with torbernite, it is named after the Swedish
chemist
Tornbern Bergmann. It is especially closely associated with torbernite, but is also found amongside autunite
, meta-autunite and uraninite
.
Radioactive decay
Radioactive decay is the process by which an atomic nucleus of an unstable atom loses energy by emitting ionizing particles . The emission is spontaneous, in that the atom decays without any physical interaction with another particle from outside the atom...
phosphate mineral
Phosphate minerals
Phosphate minerals are those minerals that contain the tetrahedrally coordinated phosphate anion along with the freely substituting arsenate and vanadate...
, and is a dehydration
Dehydration
In physiology and medicine, dehydration is defined as the excessive loss of body fluid. It is literally the removal of water from an object; however, in physiological terms, it entails a deficiency of fluid within an organism...
pseudomorph
Pseudomorph
In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form , resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by another...
of torbernite
Torbernite
The chemical formula of torbenite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+. The number of water hydration molecules can vary between 12 and 8, giving rise to the variety of metatorbernite when torbernite spontaneously dehydrates...
. Chemically, it is a copper
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
uranyl
Uranyl
The uranyl ion is an oxycation of uranium in the oxidation state +6, with the chemical formula [UO2]2+. It has a linear structure with short U-O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands are bound to the uranyl ion in an equatorial plane...
phosphate
Phosphate
A phosphate, an inorganic chemical, is a salt of phosphoric acid. In organic chemistry, a phosphate, or organophosphate, is an ester of phosphoric acid. Organic phosphates are important in biochemistry and biogeochemistry or ecology. Inorganic phosphates are mined to obtain phosphorus for use in...
and usually occurs in the form of green platy deposits. It can form by direct deposition from a supersaturated
Supersaturation
The term supersaturation refers to a solution that contains more of the dissolved material than could be dissolved by the solvent under normal circumstances...
solution, which produces true crystalline metatorbernite, with a dark green colour, translucent diaphaneity, and vitreous lustre. However, more commonly, it is formed by the dehydration of torbernite, which causes internal stress and breakage within the crystal lattice
Crystal structure
In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry...
, resulting in crystals composed of microscopic powder held together using electrostatic
Electrostatics
Electrostatics is the branch of physics that deals with the phenomena and properties of stationary or slow-moving electric charges....
force, and having a lighter green colour, opaque diaphaneity, and a relatively dull lustre. As with torbernite, it is named after the Swedish
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....
chemist
Chemist
A chemist is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties such as density and acidity. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms...
Tornbern Bergmann. It is especially closely associated with torbernite, but is also found amongside autunite
Autunite
Autunite with formula: Ca22·10-12H2O is a yellow - greenish fluorescent mineral with a hardness of 2 - 2½. Autunite crystallizes in the tetragonal system and often occurs as tabular square crystals. Due to the moderate uranium content of 48.27% it is radioactive and also used as uranium ore...
, meta-autunite and uraninite
Uraninite
Uraninite is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2, but also contains UO3 and oxides of lead, thorium, and rare earth elements...
.