Oxygen-17
Encyclopedia
Oxygen-17 is a low abundant isotope of oxygen
(0.0373% in seawater; approx. twice as abundant as Deuterium
). Being the only stable isotope of oxygen possessing a nuclear spin
and the unique characteristic of field-independent relaxation
it enables NMR studies
of metabolic pathways of compounds incorporating oxygen
at high magnetic fields (i.e. metabolic H217O water produced by oxidative phosphorylation
in mitochondria
).
in Rutherford's lab 1924:
It was a product out of the first man-made transmutation
of 14N and 4He2+ conducted by Frederick Soddy
and Ernest Rutherford
in 1917-1919. Finally its natural abundance in earth atmosphere was detected in 1929 by Giauque
and Johnson in absorption spectra.
Isotopes of oxygen
There are three stable isotopes of oxygen that lead to oxygen having a standard atomic mass of 15.9994 u. 17 radioactive isotopes have also been characterized, with mass numbers from 12O to 28O, all short-lived, with the longest-lived being 15O with a half-life of 122.24 seconds...
(0.0373% in seawater; approx. twice as abundant as Deuterium
Deuterium
Deuterium, also called heavy hydrogen, is one of two stable isotopes of hydrogen. It has a natural abundance in Earth's oceans of about one atom in of hydrogen . Deuterium accounts for approximately 0.0156% of all naturally occurring hydrogen in Earth's oceans, while the most common isotope ...
). Being the only stable isotope of oxygen possessing a nuclear spin
Spin (physics)
In quantum mechanics and particle physics, spin is a fundamental characteristic property of elementary particles, composite particles , and atomic nuclei.It is worth noting that the intrinsic property of subatomic particles called spin and discussed in this article, is related in some small ways,...
and the unique characteristic of field-independent relaxation
Relaxation (NMR)
In nuclear magnetic resonance spectroscopy and magnetic resonance imaging the term relaxation describes several processes by which nuclear magnetization prepared in a non-equilibrium state return to the equilibrium distribution. In other words, relaxation describes how fast spins "forget" the...
it enables NMR studies
Nuclear magnetic resonance
Nuclear magnetic resonance is a physical phenomenon in which magnetic nuclei in a magnetic field absorb and re-emit electromagnetic radiation...
of metabolic pathways of compounds incorporating oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
at high magnetic fields (i.e. metabolic H217O water produced by oxidative phosphorylation
Oxidative phosphorylation
Oxidative phosphorylation is a metabolic pathway that uses energy released by the oxidation of nutrients to produce adenosine triphosphate . Although the many forms of life on earth use a range of different nutrients, almost all aerobic organisms carry out oxidative phosphorylation to produce ATP,...
in mitochondria
Mitochondrion
In cell biology, a mitochondrion is a membrane-enclosed organelle found in most eukaryotic cells. These organelles range from 0.5 to 1.0 micrometers in diameter...
).
History
The isotope was first hypothesized and subsequently imaged by Patrick BlackettPatrick Blackett, Baron Blackett
Patrick Maynard Stuart Blackett, Baron Blackett OM CH FRS was an English experimental physicist known for his work on cloud chambers, cosmic rays, and paleomagnetism. He also made a major contribution in World War II advising on military strategy and developing Operational Research...
in Rutherford's lab 1924:
It was a product out of the first man-made transmutation
Nuclear transmutation
Nuclear transmutation is the conversion of one chemical element or isotope into another. In other words, atoms of one element can be changed into atoms of other element by 'transmutation'...
of 14N and 4He2+ conducted by Frederick Soddy
Frederick Soddy
Frederick Soddy was an English radiochemist who explained, with Ernest Rutherford, that radioactivity is due to the transmutation of elements, now known to involve nuclear reactions. He also proved the existence of isotopes of certain radioactive elements...
and Ernest Rutherford
Ernest Rutherford
Ernest Rutherford, 1st Baron Rutherford of Nelson OM, FRS was a New Zealand-born British chemist and physicist who became known as the father of nuclear physics...
in 1917-1919. Finally its natural abundance in earth atmosphere was detected in 1929 by Giauque
William Giauque
William Francis Giauque was an American chemist and Nobel laureate recognised in 1949 for his studies in the properties of matter at temperatures close to absolute zero...
and Johnson in absorption spectra.
Characteristics
- Excess mass: -809 keV
- Possible parent nuclides: β from 17N, electron capture from 17F