Ozokerite
Encyclopedia
Paraffin
In chemistry, paraffin is a term that can be used synonymously with "alkane", indicating hydrocarbons with the general formula CnH2n+2. Paraffin wax refers to a mixture of alkanes that falls within the 20 ≤ n ≤ 40 range; they are found in the solid state at room temperature and begin to enter the...
found in many localities.
Sources
Specimens have been obtained from ScotlandScotland
Scotland is a country that is part of the United Kingdom. Occupying the northern third of the island of Great Britain, it shares a border with England to the south and is bounded by the North Sea to the east, the Atlantic Ocean to the north and west, and the North Channel and Irish Sea to the...
, Northumberland
Northumberland
Northumberland is the northernmost ceremonial county and a unitary district in North East England. For Eurostat purposes Northumberland is a NUTS 3 region and is one of three boroughs or unitary districts that comprise the "Northumberland and Tyne and Wear" NUTS 2 region...
and Wales
Wales
Wales is a country that is part of the United Kingdom and the island of Great Britain, bordered by England to its east and the Atlantic Ocean and Irish Sea to its west. It has a population of three million, and a total area of 20,779 km²...
, as well as from about thirty different countries. Of these occurrences the ozokerite of the island (now peninsula) of Cheleken, near Turkmenbashi
Türkmenbasy, Turkmenistan
Türkmenbaşy , formerly known as Krasnovodsk and, more properly, Kyzyl-Su, is a city in Balkan Province in Turkmenistan, on the Krasnovodsk Gulf of the Caspian Sea. It is located at latitude 40.0231 North; longitude 52.9697 East, at an altitude of 27 meters. The population was 86,800, mostly...
, parts of the Himalayas
Himalayas
The Himalaya Range or Himalaya Mountains Sanskrit: Devanagari: हिमालय, literally "abode of snow"), usually called the Himalayas or Himalaya for short, is a mountain range in Asia, separating the Indian subcontinent from the Tibetan Plateau...
in India
India
India , officially the Republic of India , is a country in South Asia. It is the seventh-largest country by geographical area, the second-most populous country with over 1.2 billion people, and the most populous democracy in the world...
and the deposits of Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
in the US, deserve mention, though the last-named have been largely worked out. The sole sources of commercial supply are in Galicia, at Boryslaw
Boryslaw
Borysław may refer to:* Boryslav, Ukraine, called Borysław in Polish*Borysław, Łódź Voivodeship...
, Dzwiniacz and Starunia
Starunia
Starunya or Starunia is a village in the Bohorodchany Raion, Ivano-Frankivsk Oblast, Ukraine....
, though the mineral is found at other points on both flanks of the Carpathians
Carpathian Mountains
The Carpathian Mountains or Carpathians are a range of mountains forming an arc roughly long across Central and Eastern Europe, making them the second-longest mountain range in Europe...
.
Ozokerite deposits are believed to have originated in much the same way as mineral veins, the slow evaporation and oxidation of petroleum
Petroleum
Petroleum or crude oil is a naturally occurring, flammable liquid consisting of a complex mixture of hydrocarbons of various molecular weights and other liquid organic compounds, that are found in geologic formations beneath the Earth's surface. Petroleum is recovered mostly through oil drilling...
having resulted in the deposition of its dissolved paraffin in the fissures and crevices previously occupied by the liquid. As found native, ozokerite varies from a very soft wax to a black mass as hard as gypsum
Gypsum
Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...
.
Properties
Its specific gravity ranges from 0.85 to 0.95, and its melting point from 58 to 100 °C. It is soluble in etherDiethyl ether
Diethyl ether, also known as ethyl ether, simply ether, or ethoxyethane, is an organic compound in the ether class with the formula . It is a colorless, highly volatile flammable liquid with a characteristic odor...
, petroleum, benzene
Benzene
Benzene is an organic chemical compound. It is composed of 6 carbon atoms in a ring, with 1 hydrogen atom attached to each carbon atom, with the molecular formula C6H6....
, turpentine
Turpentine
Turpentine is a fluid obtained by the distillation of resin obtained from trees, mainly pine trees. It is composed of terpenes, mainly the monoterpenes alpha-pinene and beta-pinene...
, chloroform
Chloroform
Chloroform is an organic compound with formula CHCl3. It is one of the four chloromethanes. The colorless, sweet-smelling, dense liquid is a trihalomethane, and is considered somewhat hazardous...
, carbon disulfide
Carbon disulfide
Carbon disulfide is a colorless volatile liquid with the formula CS2. The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent...
, &c. Galician ozokerite varies in color from light yellow to dark brown, and frequently appears green owing to dichroism. It usually melts at 62 °C. Chemically, ozokerite consists of a mixture of various hydrocarbon
Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons from which one hydrogen atom has been removed are functional groups, called hydrocarbyls....
s, containing 85-7% by weight of carbon and 14-3% of hydrogen.
Mining
The mining of ozokerite was formerly carried on in Galicia by means of hand-labor, but in the ozokerite mines owned by the Boryslaw Actien Gesellschaft and the Galizische Kreditbank, the workings of which extend to a depth of 200 metres, and 225 metres respectively, electrical power is employed for hauling, pumping and ventilating. In these mines there are the usual main shafts and galleries, the ozokerite being reached by levels driven along the strike of the deposit. The wax, as it reaches the surface, varies in purity, and, in new workings especially, only hand-picking is needed to separate the pure material. In other cases much earthy matter is mixed with the material, and then the rock or shale having been eliminated by hand-picking, the "wax-stone" is boiled with water in large coppers, when the pure wax rises to the surface. This is again melted without water, and the impurities are skimmed off, the material being then run into slightly conical cylindrical mouldsMolding (process)
Molding or moulding is the process of manufacturing by shaping pliable raw material using a rigid frame or model called a pattern....
, and thus made into blocks for the market. The crude ozokerite is refined by treatment first with oil of vitriol, and subsequently with charcoal
Charcoal
Charcoal is the dark grey residue consisting of carbon, and any remaining ash, obtained by removing water and other volatile constituents from animal and vegetation substances. Charcoal is usually produced by slow pyrolysis, the heating of wood or other substances in the absence of oxygen...
, when the ceresine or cerasin of commerce is obtained. The refined ozokerite or ceresine, which usually has a melting-point of 61 to 78 °C, is largely used as an adulterant
Adulterant
An adulterant is a chemical substance which should not be contained within other substances for legal or other reasons. Adulterants may be intentionally added to more expensive substances to increase visible quantities and reduce manufacturing costs or for some other deceptive or malicious purpose...
of beeswax
Beeswax
Beeswax is a natural wax produced in the bee hive of honey bees of the genus Apis. It is mainly esters of fatty acids and various long chain alcohols...
, and is frequently colored artificially to resemble that product in appearance.
On distillation in a current of superheated steam, ozokerite yields a candle
Candle
A candle is a solid block or cylinder of wax with an embedded wick, which is lit to provide light, and sometimes heat.Today, most candles are made from paraffin. Candles can also be made from beeswax, soy, other plant waxes, and tallow...
-making material resembling the paraffin obtained from petroleum and shale-oil but of higher melting-point, and therefore of greater value if the candles made from it are to be used in hot climates. There are also obtained in the distillation light oils and a product resembling vaseline
Vaseline
Vaseline is a brand of petroleum jelly based products owned by Anglo-Dutch company Unilever. Products include plain petroleum jelly and a selection of skin creams, soaps, lotions, cleansers, deodorants and personal lubricants....
. The residue in the stills consists of a hard, black, waxy substance, which in admixture with India-rubber was employed under the name of okonite as an electrical insulator. From the residue a form of the material known as heel-ball, used to impart a polished surface to the heels and soles of boots, was also manufactured.
Mining of ozokerite fell off after 1940 due to competition from paraffin
Paraffin
In chemistry, paraffin is a term that can be used synonymously with "alkane", indicating hydrocarbons with the general formula CnH2n+2. Paraffin wax refers to a mixture of alkanes that falls within the 20 ≤ n ≤ 40 range; they are found in the solid state at room temperature and begin to enter the...
s manufactured from petroleum
Petroleum
Petroleum or crude oil is a naturally occurring, flammable liquid consisting of a complex mixture of hydrocarbons of various molecular weights and other liquid organic compounds, that are found in geologic formations beneath the Earth's surface. Petroleum is recovered mostly through oil drilling...
, but as it has a higher melting point than most petroleum waxes, it is still favored for some applications, such as electrical insulators and candles, or in extra-soft paper tissues.