Peroxodisulfate
Encyclopedia
The peroxodisulfate ion, S2O82−, is a sulfur
oxoanion
. It is commonly referred to as the persulfate
ion, but this term also refers to the peroxomonosulfate
ion, SO52−.
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...
oxoanion
Oxyanion
An oxyanion or oxoanion is a chemical compound with the generic formula AxOyz− . Oxoanions are formed by a large majority of the chemical elements. The formulae of simple oxoanions are determined by the octet rule...
. It is commonly referred to as the persulfate
Persulfate
The term persulfate refers to ions or compounds with more oxygen than normal sulfates.These do not have sulfur in a different oxidation state; rather, they contain peroxide units, where two oxygens take the place of one in a normal sulfate; the oxygen atoms are in oxidation state −1.The main forms...
ion, but this term also refers to the peroxomonosulfate
Peroxomonosulfate
The peroxomonosulfate ion, SO52−, is a sulfur oxoanion. It is sometimes referred to as the persulfate ion, but this term also refers to the peroxodisulfate ion, S2O82−....
ion, SO52−.
Compounds containing peroxodisulfate
- Na2S2O8Sodium persulfateSodium persulfate is a chemical compound. It is a strong oxidizer. It is a severe irritant of skin, eyes, and respiratory system. It is almost non-hygroscopic and has particularly good ability to be stored for long time. It is easy and safe to handle...
- K2S2O8
- (NH4)2S2O8Ammonium persulfateAmmonium persulfate 2S2O8 is a strong oxidizing agent. It is very soluble in water; the dissolution of the salt in water is endothermic. It is a radical initiator. It is used to etch copper on printed circuit boards as an alternative to ferric chloride solution...
Reactions that use peroxodisulfate
- Elbs persulfate oxidationElbs persulfate oxidationThe Elbs persulfate oxidation is the organic reaction of phenols with alkaline potassium persulfate to form para-diphenols.Several reviews have been published.-Reaction mechanism:...
- Oxidation of Ag+ to Ag2+