Planetary differentiation
Encyclopedia
In planetary science
Planetary science
Planetary science is the scientific study of planets , moons, and planetary systems, in particular those of the Solar System and the processes that form them. It studies objects ranging in size from micrometeoroids to gas giants, aiming to determine their composition, dynamics, formation,...

, planetary differentiation is the process of separating out different constituents of a planetary body as a consequence of their physical or chemical behaviour, where the body develops into compositionally distinct layers; the denser
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...

 materials of a planet
Planet
A planet is a celestial body orbiting a star or stellar remnant that is massive enough to be rounded by its own gravity, is not massive enough to cause thermonuclear fusion, and has cleared its neighbouring region of planetesimals.The term planet is ancient, with ties to history, science,...

 sink to the center, while less dense materials rise to the surface. Such a process tends to create a core
Planetary core
The planetary core consists of the innermost layer of a planet.The core may be composed of solid and liquid layers, while the cores of Mars and Venus are thought to be completely solid as they lack an internally generated magnetic field. In our solar system, core size can range from about 20% to...

 and mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

. Sometimes a chemically distinct crust
Crust (geology)
In geology, the crust is the outermost solid shell of a rocky planet or natural satellite, which is chemically distinct from the underlying mantle...

 forms on top of the mantle. The process of planetary differentiation has occurred on planets, dwarf planet
Dwarf planet
A dwarf planet, as defined by the International Astronomical Union , is a celestial body orbiting the Sun that is massive enough to be spherical as a result of its own gravity but has not cleared its neighboring region of planetesimals and is not a satellite...

s, the asteroid 4 Vesta
4 Vesta
Vesta, formally designated 4 Vesta, is one of the largest asteroids, with a mean diameter of about . It was discovered by Heinrich Wilhelm Olbers on March 29, 1807, and is named after the Roman virgin goddess of home and hearth, Vesta....

, and natural satellite
Natural satellite
A natural satellite or moon is a celestial body that orbits a planet or smaller body, which is called its primary. The two terms are used synonymously for non-artificial satellites of planets, of dwarf planets, and of minor planets....

s (such as the Moon
Moon
The Moon is Earth's only known natural satellite,There are a number of near-Earth asteroids including 3753 Cruithne that are co-orbital with Earth: their orbits bring them close to Earth for periods of time but then alter in the long term . These are quasi-satellites and not true moons. For more...

).

Heating

When the Sun
Sun
The Sun is the star at the center of the Solar System. It is almost perfectly spherical and consists of hot plasma interwoven with magnetic fields...

 ignited in the solar nebula
Solar nebula
In cosmogony, the nebular hypothesis is the most widely accepted model explaining the formation and evolution of the Solar System. There is evidence that it was first proposed in 1734 by Emanuel Swedenborg. Originally applied only to our own Solar System, this method of planetary system formation...

, hydrogen
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

, helium
Helium
Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas that heads the noble gas group in the periodic table...

 and other volatile materials were evaporated in the area near the Sun. The solar wind
Solar wind
The solar wind is a stream of charged particles ejected from the upper atmosphere of the Sun. It mostly consists of electrons and protons with energies usually between 1.5 and 10 keV. The stream of particles varies in temperature and speed over time...

 and radiation pressure
Radiation pressure
Radiation pressure is the pressure exerted upon any surface exposed to electromagnetic radiation. If absorbed, the pressure is the power flux density divided by the speed of light...

 forced such low-density material away from the Sun. Rocks, and the elements comprising them, were stripped of their early atmospheres, but themselves remained, to accumulate in protoplanet
Protoplanet
Protoplanets are large planetary embryos that originate within protoplanetary discs and have undergone internal melting to produce differentiated interiors. They are believed to form out of kilometer-sized planetesimals that attract each other gravitationally and collide...

s.

Protoplanets had higher concentrations of radioactive elements early in their history, the quantity of which has reduced over time due to radioactive decay
Radioactive decay
Radioactive decay is the process by which an atomic nucleus of an unstable atom loses energy by emitting ionizing particles . The emission is spontaneous, in that the atom decays without any physical interaction with another particle from outside the atom...

. Heating due to radioactivity, impacts, and gravitational pressure melted parts of protoplanets as they grew toward being planet
Planet
A planet is a celestial body orbiting a star or stellar remnant that is massive enough to be rounded by its own gravity, is not massive enough to cause thermonuclear fusion, and has cleared its neighbouring region of planetesimals.The term planet is ancient, with ties to history, science,...

s. In melted zones, it was possible for denser materials to sink towards the center, while lighter materials rose to the surface. The compositions of some meteorite
Meteorite
A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

s show that differentiation took place in some asteroids.

When protoplanets accrete
Accretion (astrophysics)
In astrophysics, the term accretion is used for at least two distinct processes.The first and most common is the growth of a massive object by gravitationally attracting more matter, typically gaseous matter in an accretion disc. Accretion discs are common around smaller stars or stellar remnants...

 more material, the energy at impact causes local heating. In addition to this temporary heating, the gravitational force in a sufficiently large body create pressures and temperatures which are sufficient to melt some of the materials. This allows chemical reaction
Chemical reaction
A chemical reaction is a process that leads to the transformation of one set of chemical substances to another. Chemical reactions can be either spontaneous, requiring no input of energy, or non-spontaneous, typically following the input of some type of energy, such as heat, light or electricity...

s and density
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...

 differences to mix and separate materials, and soft materials to spread out over the surface.

On Earth
Earth
Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets...

, a large piece of molten iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 is sufficiently denser than continental-crust
Continental crust
The continental crust is the layer of igneous, sedimentary, and metamorphic rocks which form the continents and the areas of shallow seabed close to their shores, known as continental shelves. This layer is sometimes called sial due to more felsic, or granitic, bulk composition, which lies in...

 material that it can force its way down through the crust to the mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

. In the outer Solar System a similar process may take place but with lighter materials: they may be hydrocarbons such as methane
Methane
Methane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel...

, water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 as liquid or ice, or frozen carbon dioxide
Carbon dioxide
Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom...

.

Chemical differentiation

Note that although bulk materials differentiate outward or inward according to their density, the elements that are chemically bound in them fractionate
Fractionation
See also: Fractionated spacecraftFractionation is a separation process in which a certain quantity of a mixture is divided up in a number of smaller quantities in which the composition changes according to a gradient. Fractions are collected based on differences in a specific property of the...

 according to their chemical affinities, "carried along" by more abundant materials that they're associated with. For instance, although the rare element uranium
Uranium
Uranium is a silvery-white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons...

 is very dense as a pure element, it is chemically more compatible as a trace element in the Earth's light, silicate-rich crust than in the dense metallic core.

Gravitational separation

High-density
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...

 materials tend to sink through lighter materials. This tendency is affected by the relative structural strengths, but such strength is reduced at temperatures where both materials are plastic or molten. Iron, the commonest element that is likely to form a very dense molten metal phase, tends to congregate towards planetary interiors. With it, many siderophile
Siderophile
Siderophile means "iron-loving". This can refer to:* Siderophilic bacteria, bacteria that require or are facilitated by free iron* Siderophile elements, chemical elements such as iridium or gold that tend to bond with metallic iron, as described by the Goldschmidt classification* Siderophilia,...

 elements (i.e. materials that like to alloy with iron) also travel downward. However, not all heavy elements make this transition as some chalcophilic heavy elements bind into low-density silicate and oxide compounds, which differentiate in the opposite direction.

The main compositionally differentiated zones in the solid Earth are the very dense iron-rich metallic core
Planetary core
The planetary core consists of the innermost layer of a planet.The core may be composed of solid and liquid layers, while the cores of Mars and Venus are thought to be completely solid as they lack an internally generated magnetic field. In our solar system, core size can range from about 20% to...

, the less dense magnesium-silicate
Talc
Talc is a mineral composed of hydrated magnesium silicate with the chemical formula H2Mg34 or Mg3Si4O102. In loose form, it is the widely-used substance known as talcum powder. It occurs as foliated to fibrous masses, its crystals being so rare as to be almost unknown...

-rich mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

 and the relatively thin, light crust
Crust (geology)
In geology, the crust is the outermost solid shell of a rocky planet or natural satellite, which is chemically distinct from the underlying mantle...

 composed mainly of silicates of aluminium, sodium, calcium and potassium. Even lighter still are the watery liquid hydrosphere
Hydrosphere
A hydrosphere in physical geography describes the combined mass of water found on, under, and over the surface of a planet....

 and the gaseous, nitrogen-rich atmosphere
Atmosphere
An atmosphere is a layer of gases that may surround a material body of sufficient mass, and that is held in place by the gravity of the body. An atmosphere may be retained for a longer duration, if the gravity is high and the atmosphere's temperature is low...

.

Lighter materials try to rise through material with a higher density. They may take on dome-shaped forms called diapir
Diapir
A diapir is a type of intrusion in which a more mobile and ductily-deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh-Taylor instability-type structures in regions with low tectonic stress...

s when doing so. On Earth, salt dome
Salt dome
A salt dome is a type of structural dome formed when a thick bed of evaporite minerals found at depth intrudes vertically into surrounding rock strata, forming a diapir....

s are salt diapirs in the crust which rise through surrounding rock. Diapirs of molten low-density silicate rocks such as granite
Granite
Granite is a common and widely occurring type of intrusive, felsic, igneous rock. Granite usually has a medium- to coarse-grained texture. Occasionally some individual crystals are larger than the groundmass, in which case the texture is known as porphyritic. A granitic rock with a porphyritic...

 are well known and abundant in the Earth's upper crust. The hydrated, low-density serpentinite
Serpentinite
Serpentinite is a rock composed of one or more serpentine group minerals. Minerals in this group are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle...

 formed by alteration of mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

 material at subduction zones can also rise to the surface as diapirs. Other materials do likewise: a low-temperature, near-surface example is provided by mud volcano
Mud volcano
The term mud volcano or mud dome are used to refer to formations created by geo-excreted liquids and gases, although there are several different processes which may cause such activity. Hot water mixes with mud and surface deposits. Mud volcanoes are associated with subduction zones and about 700...

s.

Moon's KREEP

On the Moon, a distinctive basalt
Basalt
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey...

ic material has been found that is high in "incompatible elements" such as potassium
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...

 (periodic table
Periodic table
The periodic table of the chemical elements is a tabular display of the 118 known chemical elements organized by selected properties of their atomic structures. Elements are presented by increasing atomic number, the number of protons in an atom's atomic nucleus...

 symbol K), rare earth element
Rare earth element
As defined by IUPAC, rare earth elements or rare earth metals are a set of seventeen chemical elements in the periodic table, specifically the fifteen lanthanides plus scandium and yttrium...

s, and phosphorus
Phosphorus
Phosphorus is the chemical element that has the symbol P and atomic number 15. A multivalent nonmetal of the nitrogen group, phosphorus as a mineral is almost always present in its maximally oxidized state, as inorganic phosphate rocks...

 and is often referred to by the abbreviation KREEP
KREEP
KREEP, an acronym built from the letters K , REE and P , is a geochemical component of some lunar impact melt breccia and basalt rocks...

. It is also high in uranium
Uranium
Uranium is a silvery-white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons...

 and thorium
Thorium
Thorium is a natural radioactive chemical element with the symbol Th and atomic number 90. It was discovered in 1828 and named after Thor, the Norse god of thunder....

. These elements are excluded from the major minerals of the lunar crust which crystallized out from its primeval magma ocean
Lunar magma ocean
According to the giant impact hypothesis a large amount of energy was liberated in the formation of the Moon and it is predicted that as a result a large portion of the Moon was once completely molten, forming a lunar magma ocean...

, and the KREEP basalt may have been trapped as a chemical differentiate between the crust and the mantle, with occasional eruptions to the surface.

Fractional melting and crystallization

Magma
Magma
Magma is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and is expected to exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and dissolved gas and sometimes also gas bubbles. Magma often collects in...

 in the Earth is produced by partial melting
Partial melting
Partial melting occurs when only a portion of a solid is melted. For mixed substances, such as a rock containing several different minerals or a mineral that displays solid solution, this melt can be different from the bulk composition of the solid....

 of a source rock, ultimately in the mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....

. The melt extracts from its source a large portion of the "incompatible elements" that are not stable in the major minerals. When magma rises above a certain depth the dissolved minerals start to crystallize at particular pressures and temperatures. The resulting solids remove various elements from the melt, and melt is thus depleted of those elements. Study of trace elements in igneous rock
Igneous rock
Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava...

s thus gives us information about what source melted by how much to produce a magma, and which minerals have been lost from the melt.

Thermal diffusion

When material is unevenly heated, lighter material migrates toward hotter zones and heavier material migrates towards colder areas, which is known as thermophoresis
Thermophoresis
Thermophoresis, thermodiffusion, or Soret effect , is a phenomenon observed when a mixture of two or more types of motile particles are subjected to the force of a temperature gradient and the different types of particles respond to it differently. The term "Soret effect" normally means...

, thermomigration, or the Soret effect. This process can affect differentiation in magma chamber
Magma chamber
A magma chamber is a large underground pool of molten rock found beneath the surface of the Earth. The molten rock in such a chamber is under great pressure, and given enough time, that pressure can gradually fracture the rock around it creating outlets for the magma...

s.

Differentiation through collision

Earth
Earth
Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets...

's Moon
Moon
The Moon is Earth's only known natural satellite,There are a number of near-Earth asteroids including 3753 Cruithne that are co-orbital with Earth: their orbits bring them close to Earth for periods of time but then alter in the long term . These are quasi-satellites and not true moons. For more...

 has probably formed out of material splashed into orbit by the impact of a large body into the early Earth. Differentiation on Earth had probably already separated many lighter materials toward the surface already, so that the impact removed a disproportionate amount of silicate material from Earth, and left the majority of the dense metal behind. The Moon's density is substantially less than that of Earth, due to its lack of a large iron core.

Density differences on Earth

On Earth
Earth
Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets...

, physical and chemical differentiation processes led to a crustal density of approximately 2700 kg/m3 compared to the 3400 kg/m3 density of the compositionally different mantle just below, and the average density of the planet as a whole is 5515 kg/m3.
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