Protocrystalline
Encyclopedia
A protocrystalline phase is a distinct phase
occurring during crystal growth
which evolves into a microcrystalline
form. The term is typically associated with silicon
films in optical applications such as solar cells.
Phase (matter)
In the physical sciences, a phase is a region of space , throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, and chemical composition...
occurring during crystal growth
Crystal growth
A crystal is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. Crystal growth is a major stage of a crystallization process, and consists in the addition of new atoms, ions, or polymer strings into...
which evolves into a microcrystalline
Microcrystalline
A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination.-See also:* Macrocrystalline* Microcrystalline silicon* Protocrystalline* Rock microstructure...
form. The term is typically associated with silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...
films in optical applications such as solar cells.
Silicon solar cells
Amorphous silicon (a-Si) is a popular solar cell material owing to its low cost and ease of production. Owing to disordered structure (Urbach tail), its absorption extends to the energies below the band gap resulting in a wide-range spectral response; however, it has a relatively low solar cell efficiency. The efficiency is a few orders of magnitude higher in protocrystalline silicon, which also has a relatively low absorption near the band gap owing to its more ordered crystalline structure. Thus, protocrystalline and amorphous silicon can be combined in a tandem solar cell where the top layer of thin protocrystalline silicon absorbs short-wavelength light whereas the longer wavelengths are absorbed by the underlying a-Si substrate. Such two-layer cells can be produced at a relatively low temperature of 75 °C and have an efficiency of about 5%, and a four-layer cells yield an open circuit voltage above 3.1 V.See also
- Amorphous siliconAmorphous siliconAmorphous silicon is the non-crystalline allotropic form of silicon. It can be deposited in thin films at low temperatures onto a variety of substrates, offering some unique capabilities for a variety of electronics.-Description:...
- CrystalliteCrystalliteCrystallites are small, often microscopic crystals that, held together through highly defective boundaries, constitute a polycrystalline solid. Metallurgists often refer to crystallites as grains.- Details :...
- Multijunction
- PolycarbonatePolycarbonatePolycarbonatePhysical PropertiesDensity 1.20–1.22 g/cm3Abbe number 34.0Refractive index 1.584–1.586FlammabilityV0-V2Limiting oxygen index25–27%Water absorption – Equilibrium0.16–0.35%Water absorption – over 24 hours0.1%...
(PC) - Polyethylene terephtalate (PET)