Quartz-porphyry
Encyclopedia
Quartz-porphyry, in petrology
Petrology
Petrology is the branch of geology that studies rocks, and the conditions in which rocks form....

, is the name given to a group of hemi-crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

line acid
Acid
An acid is a substance which reacts with a base. Commonly, acids can be identified as tasting sour, reacting with metals such as calcium, and bases like sodium carbonate. Aqueous acids have a pH of less than 7, where an acid of lower pH is typically stronger, and turn blue litmus paper red...

 rocks containing porphyritic
Porphyritic
Porphyritic is an adjective used in geology, specifically for igneous rocks, for a rock that has a distinct difference in the size of the crystals, with at least one group of crystals obviously larger than another group...

 crystals of quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

 in a fine-grained matrix
Matrix (geology)
The matrix or groundmass of rock is the finer grained mass of material in which larger grains, crystals or clasts are embedded.The matrix of an igneous rock consists of finer grained, often microscopic, crystals in which larger crystals are embedded. This porphyritic texture is indicative of...

, usually of micro-crystalline or felsitic structure. In specimens, the quartz appears as small rounded, clear, greyish, vitreous blebs, which are crystals, double hexagonal pyramid
Pyramid
A pyramid is a structure whose outer surfaces are triangular and converge at a single point. The base of a pyramid can be trilateral, quadrilateral, or any polygon shape, meaning that a pyramid has at least three triangular surfaces...

s, with their edges and corners rounded by resorption or corrosion.

Under the microscope
Microscope
A microscope is an instrument used to see objects that are too small for the naked eye. The science of investigating small objects using such an instrument is called microscopy...

 they are often seen to contain rounded enclosures of the ground-mass or fluid cavities, which are frequently negative crystals with regular outlines resembling those of perfect quartz crystals. Many of the latter contain liquid carbonic acid
Carbonic acid
Carbonic acid is the inorganic compound with the formula H2CO3 . It is also a name sometimes given to solutions of carbon dioxide in water, because such solutions contain small amounts of H2CO3. Carbonic acid forms two kinds of salts, the carbonates and the bicarbonates...

 and a bubble of gas that may exhibit vibratile motion under high magnifying powers.

Variants

In addition to quartz there are usually phenocryst
Phenocryst
thumb|right|300px|[[Granite]]s often have large [[feldspar|feldspatic]] phenocrysts. This granite, from the [[Switzerland|Swiss]] side of the [[Mont Blanc]] massif, has large white [[plagioclase]] phenocrysts, [[triclinic]] [[mineral]]s that give [[trapezium|trapezoid]] shapes when cut through)...

s of feldspar
Feldspar
Feldspars are a group of rock-forming tectosilicate minerals which make up as much as 60% of the Earth's crust....

, mostly orthoclase
Orthoclase
Orthoclase is an important tectosilicate mineral which forms igneous rock. The name is from the Greek for "straight fracture," because its two cleavage planes are at right angles to each other. Alternate names are alkali feldspar and potassium feldspar...

, though a varying amount of plagioclase
Plagioclase
Plagioclase is an important series of tectosilicate minerals within the feldspar family. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a solid solution series, more properly known as the plagioclase feldspar series...

 is often present. The feldspars are usually full and cloudy from the formation of secondary kaolin and muscovite
Muscovite
Muscovite is a phyllosilicate mineral of aluminium and potassium with formula KAl22, or 236. It has a highly-perfect basal cleavage yielding remarkably-thin laminæ which are often highly elastic...

 throughout their substance. Their crystals are larger than those of quartz and sometimes attain a length of two inches.

Not uncommonly scales of biotite
Biotite
Biotite is a common phyllosilicate mineral within the mica group, with the approximate chemical formula . More generally, it refers to the dark mica series, primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous endmembers...

 are visible in the specimens, being hexagonal plates, which may be weathered
Weathered
Weathered is the third album by Creed, released on November 20, 2001. Some versions are enhanced CDs and include videos. It has been certified 6× platinum by the RIAA...

 into a mixture of chlorite
Chlorite
The chlorite ion is ClO2−. A chlorite is a compound that contains this group,with chlorine in oxidation state +3. Chlorites are also known as salts of chlorous acid.-Oxidation states:...

 and epidote
Epidote
Epidote is a calcium aluminium iron sorosilicate mineral, Ca2Al2O, crystallizing in the monoclinic system. Well-developed crystals are of frequent occurrence: they are commonly prismatic in habit, the direction of elongation being perpendicular to the single plane of symmetry. The faces are often...

.

Common Minerals

Apatite
Apatite
Apatite is a group of phosphate minerals, usually referring to hydroxylapatite, fluorapatite, chlorapatite and bromapatite, named for high concentrations of OH−, F−, Cl− or Br− ions, respectively, in the crystal...

, magnetite
Magnetite
Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

, and zircon
Zircon
Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is 1–x4x–y...

, all in small but frequently perfect crystals, are almost universal minerals of the quartz-porphyries. The ground-mass is finely crystalline and to the unaided eye has usually a dull aspect resembling common earthenware
Earthenware
Earthenware is a common ceramic material, which is used extensively for pottery tableware and decorative objects.-Types of earthenware:Although body formulations vary between countries and even between individual makers, a generic composition is 25% ball clay, 28% kaolin, 32% quartz, and 15%...

; it is grey, green, reddish or white. Often it is streaked or banded by fluxion
Fluxion
Fluxion may refer to:* An alternate spelling of fluxon, a quantum of magnetic flux, such as in a superconductor* Fluxion was Isaac Newton's term for the derivative of a "fluent", or continuous function....

 during cooling, but as a rule these rocks are not vesicular
Vesicular texture
Vesicular texture is a volcanic rock texture characterised by a rock being pitted with many cavities at its surface and inside. The texture is often found in extrusive aphanitic, or glassy, igneous rock...

.

Two main types may be recognized by means of the microscope; the felsitic and the microcrystalline. In the former the ingredients are so fine-grained that in the thinnest slices they cannot be determined by means of the microscope. Some of these rocks show perlitic or spherulitic structure, and such rocks were probably originally glass
Glass
Glass is an amorphous solid material. Glasses are typically brittle and optically transparent.The most familiar type of glass, used for centuries in windows and drinking vessels, is soda-lime glass, composed of about 75% silica plus Na2O, CaO, and several minor additives...

y (obsidian
Obsidian
Obsidian is a naturally occurring volcanic glass formed as an extrusive igneous rock.It is produced when felsic lava extruded from a volcano cools rapidly with minimum crystal growth...

s or pitchstone
Pitchstone
Pitchstone is a dull black glassy volcanic rock formed when viscous lava or magma cools swiftly. It is similar to but coarser than obsidian. It is a volcanic glass with a conchoidal fracture , a resinous lustre, and a variable composition. Its colour may be mottled, streaked, or uniform brown,...

s), but by lapse of time and processes of alteration have slowly passed into very finely crystal-line state. This change is called devitrification; it is common in glasses, as these are essentially unstable. A large number of the finer quartz-porphyries are also in some degree silicified of impregnated by quartz, chalcedony
Chalcedony
Chalcedony is a cryptocrystalline form of silica, composed of very fine intergrowths of the minerals quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monoclinic...

 and opal
Opal
Opal is an amorphous form of silica related to quartz, a mineraloid form, not a mineral. 3% to 21% of the total weight is water, but the content is usually between 6% to 10%. It is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most...

, derived from the silica set free by decomposition (kaolinization) of the original feldspar. This re-deposited silica forms veins and patches of indefinite shape or may bodily replace a considerable area of the rock by metasomatic substitution. The opal is amorphous, the chalcedony finely crystalline and often arranged in spherulitic growths that yield an excellent black cross in polarized light. The microcrystalline ground-masses are those that can be resolved into their component minerals in thin slices by use of the microscope. They prove to consist essentially of quartz and feldspars, which are often in grains of quite irregular shape (microgranitic).

In other cases these two minerals are in graphic intergrowth, often forming radiate growths of spherulites consisting of fibers of extreme tenuity; this type is known as granophyric. There is another group in which the matrix contains small rounded or shapeless patches of quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

 in which many rectangular feldspar
Feldspar
Feldspars are a group of rock-forming tectosilicate minerals which make up as much as 60% of the Earth's crust....

s are embedded; this structure is called micropoikilitic, and though often primary is sometimes developed by secondary changes that involve the deposit of new quartz in the ground-mass. As a whole those quartz-porphyries that have microcrystalline ground-masses are rocks of intrusive origin. Elvan
Elvan
Elvan is a name used in Cornwall and Devon for the native varieties of quartz-porphyry. They are dispersed irregularly in the Upper Devonian series of rocks and some of them make very fine building stones...

 is a name given locally to the quartz-porphyries that occur as dikes
Dike (geology)
A dike or dyke in geology is a type of sheet intrusion referring to any geologic body that cuts discordantly across* planar wall rock structures, such as bedding or foliation...

 in Cornwall
Cornwall
Cornwall is a unitary authority and ceremonial county of England, within the United Kingdom. It is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar. Cornwall has a population of , and covers an area of...

. In many of them the matrix contains scales of colorless muscovite
Muscovite
Muscovite is a phyllosilicate mineral of aluminium and potassium with formula KAl22, or 236. It has a highly-perfect basal cleavage yielding remarkably-thin laminæ which are often highly elastic...

 or minute needles of blue tourmaline
Tourmaline
Tourmaline is a crystal boron silicate mineral compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is classified as a semi-precious stone and the gem comes in a wide variety of colors...

. Fluorite
Fluorite
Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...

 and kaolin appear also in these rocks, and the whole of these minerals are due to pneumatolytic action by vapors permeating the porphyry
Porphyry (geology)
Porphyry is a variety of igneous rock consisting of large-grained crystals, such as feldspar or quartz, dispersed in a fine-grained feldspathic matrix or groundmass. The larger crystals are called phenocrysts...

 after it had consolidated but probably before it had entirely cooled. Many ancient rhyolitic quartz-porphyries show on their weathered surfaces numerous globular projections. They may be several inches in diameter, and vary from this size down to a minute fraction of an inch. When struck with a hammer
Hammer
A hammer is a tool meant to deliver an impact to an object. The most common uses are for driving nails, fitting parts, forging metal and breaking up objects. Hammers are often designed for a specific purpose, and vary widely in their shape and structure. The usual features are a handle and a head,...

 they may detach readily from the matrix as if their margins were defined by a fissure. If they are broken across their inner portions are often seen to be filled with secondary quartz, chalcedony
Chalcedony
Chalcedony is a cryptocrystalline form of silica, composed of very fine intergrowths of the minerals quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monoclinic...

 or agate
Agate
Agate is a microcrystalline variety of silica, chiefly chalcedony, characterised by its fineness of grain and brightness of color. Although agates may be found in various kinds of rock, they are classically associated with volcanic rocks and can be common in certain metamorphic rocks.-Etymology...

: some of them have a central cavity, often with deposits of quartz crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

s; they also frequently exhibit a succession of rounded cracks or dark lines occupied by secondary products. Rocks having these structures are common in north Wales
Wales
Wales is a country that is part of the United Kingdom and the island of Great Britain, bordered by England to its east and the Atlantic Ocean and Irish Sea to its west. It has a population of three million, and a total area of 20,779 km²...

 and Cumberland
Cumberland
Cumberland is a historic county of North West England, on the border with Scotland, from the 12th century until 1974. It formed an administrative county from 1889 to 1974 and now forms part of Cumbria....

; they occur also in Jersey
Jersey
Jersey, officially the Bailiwick of Jersey is a British Crown Dependency off the coast of Normandy, France. As well as the island of Jersey itself, the bailiwick includes two groups of small islands that are no longer permanently inhabited, the Minquiers and Écréhous, and the Pierres de Lecq and...

, the Vosges
Vosges
Vosges is a French department, named after the local mountain range. It contains the hometown of Joan of Arc, Domrémy.-History:The Vosges department is one of the original 83 departments of France, created on February 9, 1790 during the French Revolution. It was made of territories that had been...

 and Hungary
Hungary
Hungary , officially the Republic of Hungary , is a landlocked country in Central Europe. It is situated in the Carpathian Basin and is bordered by Slovakia to the north, Ukraine and Romania to the east, Serbia and Croatia to the south, Slovenia to the southwest and Austria to the west. The...

. It has been proposed to call them pyromerides.

Much discussion has taken place regarding the origin of these spheroids, but it is generally admitted that most of them were originally spherulites, and that they have suffered extensive changes through decomposition
Decomposition
Decomposition is the process by which organic material is broken down into simpler forms of matter. The process is essential for recycling the finite matter that occupies physical space in the biome. Bodies of living organisms begin to decompose shortly after death...

 and silicification. Many of the older quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

-porphyries that occur in Paleozoic
Paleozoic
The Paleozoic era is the earliest of three geologic eras of the Phanerozoic eon, spanning from roughly...

 and Pre-Cambrian rocks have been affected by earth movements, and have experienced crushing and shearing. In this way they become schistose, and from their feldspar
Feldspar
Feldspars are a group of rock-forming tectosilicate minerals which make up as much as 60% of the Earth's crust....

 minute plates of sericitic white mica
Mica
The mica group of sheet silicate minerals includes several closely related materials having highly perfect basal cleavage. All are monoclinic, with a tendency towards pseudohexagonal crystals, and are similar in chemical composition...

 are developed, giving the rock in some cases very much of the appearance of mica-schists. If there have been no phenocryst
Phenocryst
thumb|right|300px|[[Granite]]s often have large [[feldspar|feldspatic]] phenocrysts. This granite, from the [[Switzerland|Swiss]] side of the [[Mont Blanc]] massif, has large white [[plagioclase]] phenocrysts, [[triclinic]] [[mineral]]s that give [[trapezium|trapezoid]] shapes when cut through)...

s in the original rock, very perfect mica-schists may be produced, which can hardly be distinguished from sedimentary schists, though chemically somewhat different on account of the larger amounts of alkali
Alkali
In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Some authors also define an alkali as a base that dissolves in water. A solution of a soluble base has a pH greater than 7. The adjective alkaline is commonly used in English as a synonym for base,...

s igneous rock
Igneous rock
Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava...

s contain. When phenocrysts were present they often remain, though rounded and dragged apart while the matrix flows around them. The glassy or felsitic enclosures in the quartz are then very suggestive of an igneous origin for the rock. Such porphyry-schists have been called porphyroids or porphyroid-schists, and in the United States
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...

 the name aporhyolite has been used for them. They are well known in some parts of the Alps
Alps
The Alps is one of the great mountain range systems of Europe, stretching from Austria and Slovenia in the east through Italy, Switzerland, Liechtenstein and Germany to France in the west....

, Westphalia
Westphalia
Westphalia is a region in Germany, centred on the cities of Arnsberg, Bielefeld, Dortmund, Minden and Münster.Westphalia is roughly the region between the rivers Rhine and Weser, located north and south of the Ruhr River. No exact definition of borders can be given, because the name "Westphalia"...

, Charnwood
Charnwood (borough)
Charnwood is a borough of northern Leicestershire, England. It is named after Charnwood Forest, which it contains. Loughborough is the largest town in the district and serves as the borough's administrative and commercial centre.-History:...

 (England
England
England is a country that is part of the United Kingdom. It shares land borders with Scotland to the north and Wales to the west; the Irish Sea is to the north west, the Celtic Sea to the south west, with the North Sea to the east and the English Channel to the south separating it from continental...

), and Pennsylvania
Pennsylvania
The Commonwealth of Pennsylvania is a U.S. state that is located in the Northeastern and Mid-Atlantic regions of the United States. The state borders Delaware and Maryland to the south, West Virginia to the southwest, Ohio to the west, New York and Ontario, Canada, to the north, and New Jersey to...

. The halleflintas of Sweden
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....

 are also in part acid
Acid
An acid is a substance which reacts with a base. Commonly, acids can be identified as tasting sour, reacting with metals such as calcium, and bases like sodium carbonate. Aqueous acids have a pH of less than 7, where an acid of lower pH is typically stronger, and turn blue litmus paper red...

 igneous rocks with a well-banded schistose or granulitic texture. The quartz-porphyries are distinguished from the rhyolite
Rhyolite
This page is about a volcanic rock. For the ghost town see Rhyolite, Nevada, and for the satellite system, see Rhyolite/Aquacade.Rhyolite is an igneous, volcanic rock, of felsic composition . It may have any texture from glassy to aphanitic to porphyritic...

s by being either intrusive rocks or Palaeozoic lava
Lava
Lava refers both to molten rock expelled by a volcano during an eruption and the resulting rock after solidification and cooling. This molten rock is formed in the interior of some planets, including Earth, and some of their satellites. When first erupted from a volcanic vent, lava is a liquid at...

s. All Tertiary
Tertiary
The Tertiary is a deprecated term for a geologic period 65 million to 2.6 million years ago. The Tertiary covered the time span between the superseded Secondary period and the Quaternary...

 acid lavas are included under rhyolites. The intrusive quartz-porphyries are equally well described as granite
Granite
Granite is a common and widely occurring type of intrusive, felsic, igneous rock. Granite usually has a medium- to coarse-grained texture. Occasionally some individual crystals are larger than the groundmass, in which case the texture is known as porphyritic. A granitic rock with a porphyritic...

-porphyries.

Other Minerals

Other porphyritic mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

s are few, but hornblende
Hornblende
Hornblende is a complex inosilicate series of minerals .It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole....

, augite
Augite
Augite is a single chain inosilicate mineral, 2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.-Characteristics:Augite is a solid solution in the pyroxene group...

 and bronzite
Bronzite
Bronzite is a member of the orthopyroxene group of minerals, belonging with enstatite and hypersthene to the orthorhombic series of the group...

 are sometimes found, and garnet
Garnet
The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...

, cordierite
Cordierite
Cordierite or iolite is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: 2 to 2...

 and muscovite
Muscovite
Muscovite is a phyllosilicate mineral of aluminium and potassium with formula KAl22, or 236. It has a highly-perfect basal cleavage yielding remarkably-thin laminæ which are often highly elastic...

 may also occur.

The garnets are small, of rounded shape and red or brownish color; in some cases they appear to have been corroded or absorbed.

Cordierite forms six-sided prisms with flat ends; these divide, between crossed nicols, into six triangular areas radiating from a center, as the crystals, which belong to the rhombic system, are not simple but consist of three twins interpenetrating and crossing. In the vast majority of cases the cordierite has weathered to an aggregate of scaly chlorite and muscovite; this is known as pinite and is or dark green color and very soft. The quartz-porphyries or elvans that occur as dike
Dike (geology)
A dike or dyke in geology is a type of sheet intrusion referring to any geologic body that cuts discordantly across* planar wall rock structures, such as bedding or foliation...

s in Cornwall
Cornwall
Cornwall is a unitary authority and ceremonial county of England, within the United Kingdom. It is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar. Cornwall has a population of , and covers an area of...

 and Devon
Devon
Devon is a large county in southwestern England. The county is sometimes referred to as Devonshire, although the term is rarely used inside the county itself as the county has never been officially "shired", it often indicates a traditional or historical context.The county shares borders with...

 frequently contain this mineral.

The augite and hornblende of these rocks are in most cases green, and are frequently decomposed into chlorite, but even then can usually be identified by their shape. A colorless rhombic pyroxene
Pyroxene
The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. They share a common structure consisting of single chains of silica tetrahedra and they crystallize in the monoclinic and orthorhombic systems...

 (enstatite
Enstatite
Enstatite is the magnesium endmember of the pyroxene silicate mineral series enstatite - ferrosilite . The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks...

or bronzite) occurs in a limited number of the rocks of this group and readily weathers to bastite.
The source of this article is wikipedia, the free encyclopedia.  The text of this article is licensed under the GFDL.
 
x
OK