Raschig process
Encyclopedia
The Raschig process is a chemical process
for producing hydroxylamine
(used for making caprolactam
for nylon manufacture). The process converts ammonium carbonate
to ammonium nitrite
, and this is converted to hydroxylamine disulfonate and thence to hydroxylamine sulfate.
Another similarly named process is the Raschig-Hooker process, an industrial
process to create phenol
. It is done by the hydrolysis
of chlorobenzene
.
The Olin Raschig process is an industrial process
used to produce hydrazine
and developed by the Olin Corporation. Sodium hypochlorite solution is mixed with ammonia
at 5 °C
to form chloramine
and sodium hydroxide, which is then rapidly added to anhydrous ammonia under pressure and heated to 130 °C to generate hydrazine, water and sodium chloride
(waste product). Ammonia is used in a 33 fold excess.
Chemical process
In a "scientific" sense, a chemical process is a method or means of somehow changing one or more chemicals or chemical compounds. Such a chemical process can occur by itself or be caused by somebody. Such a chemical process commonly involves a chemical reaction of some sort...
for producing hydroxylamine
Hydroxylamine
Hydroxylamine is an inorganic compound with the formula NH2OH. The pure material is a white, unstable crystalline, hygroscopic compound. However, hydroxylamine is almost always provided and used as an aqueous solution. It is used to prepare oximes, an important functional group. It is also an...
(used for making caprolactam
Caprolactam
Caprolactam is an organic compound with the formula 5CNH. This colourless solid is a lactam or a cyclic amide of caproic acid. Approximately 2 billion kilograms are produced annually...
for nylon manufacture). The process converts ammonium carbonate
Ammonium carbonate
Ammonium carbonate is a commercial salt with the chemical formula 2CO3. It is used when crushed as a smelling salt. It can be crushed when needed in order to revive someone who has fainted...
to ammonium nitrite
Ammonium nitrite
Ammonium nitrite, NH4NO2, is the ammonia salt of nitrous acid. It is used as a rodenticide, microbiocide and agricultural pesticide, and is acutely toxic to both humans and aquatic organisms.-Preparation:...
, and this is converted to hydroxylamine disulfonate and thence to hydroxylamine sulfate.
Another similarly named process is the Raschig-Hooker process, an industrial
Industry
Industry refers to the production of an economic good or service within an economy.-Industrial sectors:There are four key industrial economic sectors: the primary sector, largely raw material extraction industries such as mining and farming; the secondary sector, involving refining, construction,...
process to create phenol
Phenol
Phenol, also known as carbolic acid, phenic acid, is an organic compound with the chemical formula C6H5OH. It is a white crystalline solid. The molecule consists of a phenyl , bonded to a hydroxyl group. It is produced on a large scale as a precursor to many materials and useful compounds...
. It is done by the hydrolysis
Hydrolysis
Hydrolysis is a chemical reaction during which molecules of water are split into hydrogen cations and hydroxide anions in the process of a chemical mechanism. It is the type of reaction that is used to break down certain polymers, especially those made by condensation polymerization...
of chlorobenzene
Chlorobenzene
Chlorobenzene is an aromatic organic compound with the chemical formula C6H5Cl. This colorless, flammable liquid is a common solvent and a widely used intermediate in the manufacture of other chemicals.-Uses:...
.
The Olin Raschig process is an industrial process
Industrial process
Industrial processes are procedures involving chemical or mechanical steps to aid in the manufacture of an item or items, usually carried out on a very large scale. Industrial processes are the key components of heavy industry....
used to produce hydrazine
Hydrazine
Hydrazine is an inorganic compound with the formula N2H4. It is a colourless flammable liquid with an ammonia-like odor. Hydrazine is highly toxic and dangerously unstable unless handled in solution. Approximately 260,000 tons are manufactured annually...
and developed by the Olin Corporation. Sodium hypochlorite solution is mixed with ammonia
Ammonia
Ammonia is a compound of nitrogen and hydrogen with the formula . It is a colourless gas with a characteristic pungent odour. Ammonia contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to food and fertilizers. Ammonia, either directly or...
at 5 °C
Celsius
Celsius is a scale and unit of measurement for temperature. It is named after the Swedish astronomer Anders Celsius , who developed a similar temperature scale two years before his death...
to form chloramine
Chloramine
Chloramines are derivatives of ammonia by substitution of one, two or three hydrogen atoms with chlorine atoms. Monochloramine is an inorganic compound with the formula NH2Cl. It is an unstable colourless liquid at its melting point of -66° temperature, but it is usually handled as a dilute...
and sodium hydroxide, which is then rapidly added to anhydrous ammonia under pressure and heated to 130 °C to generate hydrazine, water and sodium chloride
Sodium chloride
Sodium chloride, also known as salt, common salt, table salt or halite, is an inorganic compound with the formula NaCl. Sodium chloride is the salt most responsible for the salinity of the ocean and of the extracellular fluid of many multicellular organisms...
(waste product). Ammonia is used in a 33 fold excess.