Rhenium(VII) oxide
Overview
 
Rhenium oxide is the chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 with the formula Re2
Rhenium
Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-white, heavy, third-row transition metal in group 7 of the periodic table. With an average concentration of 1 part per billion , rhenium is one of the rarest elements in the Earth's crust. The free element has...

O7
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

. It is the anhydride of the hypothetical acid (HOReO3). Perrhenic acid
Perrhenic acid
Perrhenic acid is the chemical compound with the formula Re2O72. It is obtained by evaporating aqueous solutions of Re2O7. Conventionally, perrhenic acid is considered to have the formula HReO4, and a species of this formula forms when rhenium oxide sublimes in the presence of water or steam...

, Re2O7·2H2O, however is closely related structurally to Re2O7. Solid Re2O7 is polymeric consisting, unusually, of the metal centers in two coordination environments - octahedral and tetrahedral.
 
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