Saul Winstein
Encyclopedia
Saul Winstein was the Canadian chemist who discovered the Winstein reaction, in which he argued a non-classical cation was needed to explain the stability of the norbornyl cation. This fueled a debate with Herbert C. Brown
over the existence of delocalized cations such as this. Richard F. Heck
, who earlier in his career had undertaken postgraduate studies with Winstein, won the 2010 Nobel Prize in Chemistry
. Co-author of the Grunwald-Winstein equation
concerning solvolysis rates.
Herbert C. Brown
Herbert Charles Brown was a chemist and Nobel Prize in Chemistry laureate for his work with organoboranes....
over the existence of delocalized cations such as this. Richard F. Heck
Richard F. Heck
Richard Fred Heck is an American chemist noted for the discovery and development of the Heck reaction, which uses palladium to catalyze organic chemical reactions that couple aryl halides with alkenes....
, who earlier in his career had undertaken postgraduate studies with Winstein, won the 2010 Nobel Prize in Chemistry
Nobel Prize in Chemistry
The Nobel Prize in Chemistry is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outstanding contributions in chemistry, physics, literature,...
. Co-author of the Grunwald-Winstein equation
Grunwald-Winstein equation
In physical organic chemistry, the Grunwald–Winstein equation is a linear free energy relationship between relative rate constants and the ionizing power of various solvent systems, describing the effect of solvent as nucleophile on different substrates...
concerning solvolysis rates.