Symmetry number
Encyclopedia
The symmetry number or symmetry order of an object is the number of different but indistinguishable (or equivalent) arrangements (or views) of the object, i.e. the order
of its symmetry group
. The object can be a molecule, crystal lattice, lattice, tiling, or in a general case any mathematical object in N-dimensions.
In statistical thermodynamics, the symmetry number corrects for any overcounting of equivalent molecular conformations in the partition function. In this sense, the symmetry number depends upon how the partition function is formulated. For example, if one writes the partition function of ethane
so that the integral includes full rotation of a methyl, then the 3-fold rotational symmetry of the methyl group contributes a factor of 3 to the symmetry number; but if one writes the partition function so that the integral includes only one rotational energy well of the methyl, then the methyl rotation does not contribute to the symmetry number.
Order (group theory)
In group theory, a branch of mathematics, the term order is used in two closely related senses:* The order of a group is its cardinality, i.e., the number of its elements....
of its symmetry group
Symmetry group
The symmetry group of an object is the group of all isometries under which it is invariant with composition as the operation...
. The object can be a molecule, crystal lattice, lattice, tiling, or in a general case any mathematical object in N-dimensions.
In statistical thermodynamics, the symmetry number corrects for any overcounting of equivalent molecular conformations in the partition function. In this sense, the symmetry number depends upon how the partition function is formulated. For example, if one writes the partition function of ethane
Ethane
Ethane is a chemical compound with chemical formula C2H6. It is the only two-carbon alkane that is an aliphatic hydrocarbon. At standard temperature and pressure, ethane is a colorless, odorless gas....
so that the integral includes full rotation of a methyl, then the 3-fold rotational symmetry of the methyl group contributes a factor of 3 to the symmetry number; but if one writes the partition function so that the integral includes only one rotational energy well of the methyl, then the methyl rotation does not contribute to the symmetry number.
See also
- Group theoryGroup theoryIn mathematics and abstract algebra, group theory studies the algebraic structures known as groups.The concept of a group is central to abstract algebra: other well-known algebraic structures, such as rings, fields, and vector spaces can all be seen as groups endowed with additional operations and...
, a branch of mathematics which discusses symmetry, symmetry groups, symmetry spaces, symmetry operations - Point groups in three dimensionsPoint groups in three dimensionsIn geometry, a point group in three dimensions is an isometry group in three dimensions that leaves the origin fixed, or correspondingly, an isometry group of a sphere. It is a subgroup of the orthogonal group O, the group of all isometries that leave the origin fixed, or correspondingly, the group...
- Space groupSpace groupIn mathematics and geometry, a space group is a symmetry group, usually for three dimensions, that divides space into discrete repeatable domains.In three dimensions, there are 219 unique types, or counted as 230 if chiral copies are considered distinct...
in 3 dimensions - Symmetry combinations in 2 dimensions
- Molecular symmetryMolecular symmetryMolecular symmetry in chemistry describes the symmetry present in molecules and the classification of molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can predict or explain many of a molecule's chemical properties, such as its dipole moment...
- List of the 230 crystallographic 3D space groups
- Fixed points of isometry groups in Euclidean spaceFixed points of isometry groups in Euclidean spaceA fixed point of an isometry group is a point that is a fixed point for every isometry in the group. For any isometry group in Euclidean space the set of fixed points is either empty or an affine space....
- Symmetric groupSymmetric groupIn mathematics, the symmetric group Sn on a finite set of n symbols is the group whose elements are all the permutations of the n symbols, and whose group operation is the composition of such permutations, which are treated as bijective functions from the set of symbols to itself...
, mathematics - Symmetry groupSymmetry groupThe symmetry group of an object is the group of all isometries under which it is invariant with composition as the operation...
, mathematics