Telluroxide
Encyclopedia
Telluroxide is a type of organotellurium compound with the formula R2TeO. These compounds are analogous to sulfoxide
s in some respects. Reflecting the decreased tendency of Te to form multiple bonds, telluroxides exist both the monomer and the polymer
, which are favored in solution and the solid state, respectively. They are prepared from the telluroethers by halogenation]] followed by base hydrolysis:
Sulfoxide
A sulfoxide is a chemical compound containing a sulfinyl functional group attached to two carbon atoms. Sulfoxides can be considered as oxidized sulfides...
s in some respects. Reflecting the decreased tendency of Te to form multiple bonds, telluroxides exist both the monomer and the polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...
, which are favored in solution and the solid state, respectively. They are prepared from the telluroethers by halogenation]] followed by base hydrolysis:
- R2Te + Br2 → R2TeBr2
- R2TeBr2 + 2 NaOH → R2TeO + 2 NaBr + H2O