Third phase
Encyclopedia
Third phase is the term for a stable emulsion
which forms in a solvent
extraction system when the original two phases (aqueous and organic
) are mixed.
The third phase can be caused by a detergent
(surfactant
) or a fine solid. While third phase is a term for an unwanted emulsion, a stable emulsion is wanted in emulsion polymerization
all the things which can be used to make a stable 'emulsion' for a latex
synthesis can prove to encourgae a third phase to form.
One term for the third phase found in PUREX
plants is crud (Chalk River Unknown Deposit). One common crud is formed by the reaction of zirconium
salts (from fission) with degraded tributyl phosphate
(TBP). The TBP degrades into dibutyl hydrogen phosphate and then into butyl dihydrogen phosphate. The dibutyl hydrogen phosphate and the zirconium can form polymer
ic solid which is very insoluble.
Emulsion
An emulsion is a mixture of two or more liquids that are normally immiscible . Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion is used when both the dispersed and the...
which forms in a solvent
Solvent
A solvent is a liquid, solid, or gas that dissolves another solid, liquid, or gaseous solute, resulting in a solution that is soluble in a certain volume of solvent at a specified temperature...
extraction system when the original two phases (aqueous and organic
Organic compound
An organic compound is any member of a large class of gaseous, liquid, or solid chemical compounds whose molecules contain carbon. For historical reasons discussed below, a few types of carbon-containing compounds such as carbides, carbonates, simple oxides of carbon, and cyanides, as well as the...
) are mixed.
The third phase can be caused by a detergent
Detergent
A detergent is a surfactant or a mixture of surfactants with "cleaning properties in dilute solutions." In common usage, "detergent" refers to alkylbenzenesulfonates, a family of compounds that are similar to soap but are less affected by hard water...
(surfactant
Surfactant
Surfactants are compounds that lower the surface tension of a liquid, the interfacial tension between two liquids, or that between a liquid and a solid...
) or a fine solid. While third phase is a term for an unwanted emulsion, a stable emulsion is wanted in emulsion polymerization
Emulsion polymerization
Emulsion polymerization is a type of radical polymerization that usually starts with an emulsion incorporating water, monomer, and surfactant. The most common type of emulsion polymerization is an oil-in-water emulsion, in which droplets of monomer are emulsified in a continuous phase of water...
all the things which can be used to make a stable 'emulsion' for a latex
Latex
Latex is the stable dispersion of polymer microparticles in an aqueous medium. Latexes may be natural or synthetic.Latex as found in nature is a milky fluid found in 10% of all flowering plants . It is a complex emulsion consisting of proteins, alkaloids, starches, sugars, oils, tannins, resins,...
synthesis can prove to encourgae a third phase to form.
One term for the third phase found in PUREX
PUREX
PUREX is an acronym standing for Plutonium - URanium EXtraction — de facto standard aqueous nuclear reprocessing method for the recovery of uranium and plutonium from used nuclear fuel. It is based on liquid-liquid extraction ion-exchange.The PUREX process was invented by Herbert H. Anderson and...
plants is crud (Chalk River Unknown Deposit). One common crud is formed by the reaction of zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...
salts (from fission) with degraded tributyl phosphate
Tributyl phosphate
Tributyl phosphate, known commonly as TBP, is an organophosphorus compound with the formula 3PO. This colourless, odorless liquid finds some applications as an extractant and a plasticizer. It is an ester of orthophosphoric acid with n-butanol.- Production :Tributyl phosphate is manufactured by...
(TBP). The TBP degrades into dibutyl hydrogen phosphate and then into butyl dihydrogen phosphate. The dibutyl hydrogen phosphate and the zirconium can form polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...
ic solid which is very insoluble.