Total external reflection
Encyclopedia
Total external reflection is an optical phenomenon where electromagnetic radiation (e.g. visible light) can, at certain angles, be totally reflected from an interface between two media of different indices of refraction (see Snell's law
Snell's law
In optics and physics, Snell's law is a formula used to describe the relationship between the angles of incidence and refraction, when referring to light or other waves passing through a boundary between two different isotropic media, such as water and glass...

). Total internal reflection
Total internal reflection
Total internal reflection is an optical phenomenon that happens when a ray of light strikes a medium boundary at an angle larger than a particular critical angle with respect to the normal to the surface. If the refractive index is lower on the other side of the boundary and the incident angle is...

 occurs when the first medium has a larger refractive index
Refractive index
In optics the refractive index or index of refraction of a substance or medium is a measure of the speed of light in that medium. It is expressed as a ratio of the speed of light in vacuum relative to that in the considered medium....

 than the second medium, for example, light that emerges from under water. The optically denser material (water in this case) is the "internal" medium. For visible light, water has an index of refraction of 1.33 and for air it is very close to 1. For vacuum the index of refraction is exactly 1 for all wavelengths.

For X-rays, however, all materials have indices of refraction slightly below 1. This entails that total reflection of X-rays only can occur when they travel through vacuum and impinge on a surface (at a small glancing angle). Since this kind of total reflection takes place outside of the material it is termed total external reflection.
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