Trifluoromethylsulfonyl
Encyclopedia
Triflyl, more formally known as trifluoromethanesulfonyl, is a functional group
Functional group
In organic chemistry, functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. The same functional group will undergo the same or similar chemical reaction regardless of the size of the molecule it is a part of...

 with the formula F3CSO2–. The triflyl group is often represented by –Tf.

The closely related triflate group (trifluoromethanesulfonate) has the formula F3CSO2O–, and is represented by –OTf.

See also

  • Triflyl azide
    Trifluoromethanesulfonyl azide
    Trifluoromethanesulfonyl azide or triflyl azide is an organic azide used as a reagent in organic synthesis.-Preparation:Trifluoromethanesulfonyl azide is not commercially available. It is prepared before use by reacting trifluoromethanesulfonic anhydride with sodium azide, traditionally in...

    , TfN3
  • Triflic acid, TfOH
  • Methyl triflate, MeOTf
  • Trioctylmethylammonium bis(trifluoromethylsulfonyl)imide, [MeN(C8H17)3+][NTf2]
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