Yttrium iron garnet
Encyclopedia
Yttrium iron garnet is a kind of synthetic garnet
, with chemical composition 32(Fe4)3, or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 550 K
.
In YIG, the five iron(III) ions occupy two octahedral and three tetrahedral sites, with the yttrium(III) ions coordinated by eight oxygen ions in an irregular cube. The iron ions in the two coordination sites exhibit different spins
, resulting in magnetic behaviour. By substituting specific sites with rare earth elements, for example, interesting magnetic properties can be obtained.
YIG has a high Verdet constant
which results in the Faraday effect
, high Q factor
in microwave
frequencies, low absorption of infrared
wavelengths up to 600 nm, and very small linewidth in electron spin resonance. These properties make it useful for MOI (magnetic optical imaging) applications in superconductors.
YIG is used in microwave
, optical, and magneto-optical applications, e.g. microwave YIG filters. It is transparent for infrared
light wavelength
s over 600 nm. It also finds use in solid-state laser
s in Faraday rotator
s, in data storage
, and in various nonlinear optics
applications.
Garnet
The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...
, with chemical composition 32(Fe4)3, or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 550 K
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...
.
In YIG, the five iron(III) ions occupy two octahedral and three tetrahedral sites, with the yttrium(III) ions coordinated by eight oxygen ions in an irregular cube. The iron ions in the two coordination sites exhibit different spins
Spin (physics)
In quantum mechanics and particle physics, spin is a fundamental characteristic property of elementary particles, composite particles , and atomic nuclei.It is worth noting that the intrinsic property of subatomic particles called spin and discussed in this article, is related in some small ways,...
, resulting in magnetic behaviour. By substituting specific sites with rare earth elements, for example, interesting magnetic properties can be obtained.
YIG has a high Verdet constant
Verdet constant
The Verdet constant is an optical "constant" that describes the strength of the Faraday effect for a particular material.The Verdet constant for most materials is extremely small and is wavelength dependent. It is strongest in substances containing paramagnetic ions such as terbium...
which results in the Faraday effect
Faraday effect
In physics, the Faraday effect or Faraday rotation is a Magneto-optical phenomenon, that is, an interaction between light and a magnetic field in a medium...
, high Q factor
Q factor
In physics and engineering the quality factor or Q factor is a dimensionless parameter that describes how under-damped an oscillator or resonator is, or equivalently, characterizes a resonator's bandwidth relative to its center frequency....
in microwave
Microwave
Microwaves, a subset of radio waves, have wavelengths ranging from as long as one meter to as short as one millimeter, or equivalently, with frequencies between 300 MHz and 300 GHz. This broad definition includes both UHF and EHF , and various sources use different boundaries...
frequencies, low absorption of infrared
Infrared
Infrared light is electromagnetic radiation with a wavelength longer than that of visible light, measured from the nominal edge of visible red light at 0.74 micrometres , and extending conventionally to 300 µm...
wavelengths up to 600 nm, and very small linewidth in electron spin resonance. These properties make it useful for MOI (magnetic optical imaging) applications in superconductors.
YIG is used in microwave
Microwave
Microwaves, a subset of radio waves, have wavelengths ranging from as long as one meter to as short as one millimeter, or equivalently, with frequencies between 300 MHz and 300 GHz. This broad definition includes both UHF and EHF , and various sources use different boundaries...
, optical, and magneto-optical applications, e.g. microwave YIG filters. It is transparent for infrared
Infrared
Infrared light is electromagnetic radiation with a wavelength longer than that of visible light, measured from the nominal edge of visible red light at 0.74 micrometres , and extending conventionally to 300 µm...
light wavelength
Wavelength
In physics, the wavelength of a sinusoidal wave is the spatial period of the wave—the distance over which the wave's shape repeats.It is usually determined by considering the distance between consecutive corresponding points of the same phase, such as crests, troughs, or zero crossings, and is a...
s over 600 nm. It also finds use in solid-state laser
Solid-state laser
A solid-state laser is a laser that uses a gain medium that is a solid, rather than a liquid such as in dye lasers or a gas as in gas lasers. Semiconductor-based lasers are also in the solid state, but are generally considered as a separate class from solid-state lasers .-Solid-state...
s in Faraday rotator
Faraday rotator
A Faraday rotator is an optical device that rotates the polarization of light due to the Faraday effect, which in turn is based on a magneto-optic effect....
s, in data storage
Data storage device
thumb|200px|right|A reel-to-reel tape recorder .The magnetic tape is a data storage medium. The recorder is data storage equipment using a portable medium to store the data....
, and in various nonlinear optics
Nonlinear optics
Nonlinear optics is the branch of optics that describes the behavior of light in nonlinear media, that is, media in which the dielectric polarization P responds nonlinearly to the electric field E of the light...
applications.
See also
- Yttrium aluminium garnetYttrium aluminium garnetYttrium aluminium garnet is a synthetic crystalline material of the garnet group. It is also one of three phases of the yttria-aluminium composite, the other two being yttrium aluminium monoclinic and yttrium aluminium perovskite . YAG is commonly used as a host material in various solid-state...
- Gadolinium gallium garnetGadolinium gallium garnetGadolinium Gallium Garnet is a synthetic crystalline material of the garnet group, with good mechanical, thermal, and optical properties. It is typically colorless. It has cubic lattice, density 7.08 g/cm³ and Mohs hardness is variously noted as 6.5 and 7.5...
- Yttrium iron garnet filterYttrium iron garnet filterYttrium iron garnet spheres serve as magnetically tunable filters and resonators for microwave frequencies. These filters are used for their high Q factors....