Boron tribromide
Encyclopedia
Boron tribromide, BBr3, is a colorless, fuming liquid compound containing boron
and bromine
. It is usually made by heating boron trioxide
with carbon
in the presence of bromine: this generates free boron which reacts vigorously with the bromine. It is very volatile and fumes in air because it reacts vigorously with water
to form boric acid
and hydrogen bromide
.
. It is an excellent demethylating or dealkylating agent for ether
s, often in the production of pharmaceuticals
. Additionally, it also finds applications in olefin polymer
ization and in Friedel-Crafts
chemistry as a Lewis acid
catalyst. The electronics industry uses boron tribromide as a boron source in pre-deposition processes for doping
in the manufacture of semiconductors.
with bromine
at temperatures above 300 °C leads to the formation of boron tribromide. The product can be purified by vacuum distillation
.
An improvement of this method was developed by F. Wöhler
and Deville
in 1857. By starting from amorphous boron the reaction temperatures are lower and no carbon monoxide is produced:
Image Processing
Semiconductor Doping
Semiconductor Plasma Etching
Photovoltaic Manufacturing
Reagent for Various Chemical Processes.
Boron
Boron is the chemical element with atomic number 5 and the chemical symbol B. Boron is a metalloid. Because boron is not produced by stellar nucleosynthesis, it is a low-abundance element in both the solar system and the Earth's crust. However, boron is concentrated on Earth by the...
and bromine
Bromine
Bromine ") is a chemical element with the symbol Br, an atomic number of 35, and an atomic mass of 79.904. It is in the halogen element group. The element was isolated independently by two chemists, Carl Jacob Löwig and Antoine Jerome Balard, in 1825–1826...
. It is usually made by heating boron trioxide
Boron trioxide
Boron trioxide is one of the oxides of boron. It is a white, glassy solid with the formula B2O3. It is almost always found as the vitreous form; however, it can be crystallized after extensive annealing...
with carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...
in the presence of bromine: this generates free boron which reacts vigorously with the bromine. It is very volatile and fumes in air because it reacts vigorously with water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
to form boric acid
Boric acid
Boric acid, also called hydrogen borate or boracic acid or orthoboric acid or acidum boricum, is a weak acid of boron often used as an antiseptic, insecticide, flame retardant, as a neutron absorber, and as a precursor of other chemical compounds. It exists in the form of colorless crystals or a...
and hydrogen bromide
Hydrogen bromide
Hydrogen bromide is the diatomic molecule HBr. HBr is a gas at standard conditions. Hydrobromic acid forms upon dissolving HBr in water. Conversely, HBr can be liberated from hydrobromic acid solutions with the addition of a dehydration agent, but not by distillation. Hydrogen bromide and...
.
Chemical properties
Boron tribromide is commercially available and is a strong Lewis acidLewis acid
]The term Lewis acid refers to a definition of acid published by Gilbert N. Lewis in 1923, specifically: An acid substance is one which can employ a lone pair from another molecule in completing the stable group of one of its own atoms. Thus, H+ is a Lewis acid, since it can accept a lone pair,...
. It is an excellent demethylating or dealkylating agent for ether
Ether
Ethers are a class of organic compounds that contain an ether group — an oxygen atom connected to two alkyl or aryl groups — of general formula R–O–R'. A typical example is the solvent and anesthetic diethyl ether, commonly referred to simply as "ether"...
s, often in the production of pharmaceuticals
Medication
A pharmaceutical drug, also referred to as medicine, medication or medicament, can be loosely defined as any chemical substance intended for use in the medical diagnosis, cure, treatment, or prevention of disease.- Classification :...
. Additionally, it also finds applications in olefin polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...
ization and in Friedel-Crafts
chemistry as a Lewis acid
Lewis acid
]The term Lewis acid refers to a definition of acid published by Gilbert N. Lewis in 1923, specifically: An acid substance is one which can employ a lone pair from another molecule in completing the stable group of one of its own atoms. Thus, H+ is a Lewis acid, since it can accept a lone pair,...
catalyst. The electronics industry uses boron tribromide as a boron source in pre-deposition processes for doping
Doping (semiconductor)
In semiconductor production, doping intentionally introduces impurities into an extremely pure semiconductor for the purpose of modulating its electrical properties. The impurities are dependent upon the type of semiconductor. Lightly and moderately doped semiconductors are referred to as extrinsic...
in the manufacture of semiconductors.
Synthesis
The reaction of boron carbideBoron carbide
Boron carbide is an extremely hard boron–carbon ceramic material used in tank armor, bulletproof vests, and numerous industrial applications...
with bromine
Bromine
Bromine ") is a chemical element with the symbol Br, an atomic number of 35, and an atomic mass of 79.904. It is in the halogen element group. The element was isolated independently by two chemists, Carl Jacob Löwig and Antoine Jerome Balard, in 1825–1826...
at temperatures above 300 °C leads to the formation of boron tribromide. The product can be purified by vacuum distillation
Distillation
Distillation is a method of separating mixtures based on differences in volatilities of components in a boiling liquid mixture. Distillation is a unit operation, or a physical separation process, and not a chemical reaction....
.
History
The first synthesis was done by M. Poggiale in 1846 by reacting boron trioxide with carbon and bromine at high temperatures:- B2O3 + 3 C + 3 Br2 → 2 BBr3 + 3 CO
An improvement of this method was developed by F. Wöhler
Friedrich Wöhler
Friedrich Wöhler was a German chemist, best known for his synthesis of urea, but also the first to isolate several chemical elements.-Biography:He was born in Eschersheim, which belonged to aau...
and Deville
Henri Etienne Sainte-Claire Deville
Henri Étienne Sainte-Claire Deville was a French chemist.He was born in the island of St Thomas, West Indies, where his father was French consul. Together with his elder brother Charles he was educated in Paris at the College Rollin...
in 1857. By starting from amorphous boron the reaction temperatures are lower and no carbon monoxide is produced:
- 2 B + 3 Br2 → 2 BBr3
Applications
Pharmaceutical ManufacturingImage Processing
Semiconductor Doping
Semiconductor Plasma Etching
Photovoltaic Manufacturing
Reagent for Various Chemical Processes.