Evaporite
Encyclopedia
Evaporite is a name for a water-soluble mineral
sediment
that result from concentration and crystallization
by evaporation
from an aqueous solution. There are two types of evaporate deposits, marine which can also be described as ocean deposits, and non-marine which are found in standing bodies of water such as lakes. Evaporites are considered sedimentary rock
s.
environment with a small basin fed by a limited input of water. When evaporation occurs, the remaining water is enriched in salts, and they precipitate when the water becomes oversaturated.
begins to form, which is then followed by halite
at 10%. Excluding carbonate minerals which tend not to be evaporates. The most common minerals that are generally considered to be the most representative of marine evaporates are, calcite
, gypsum
and anhydrite
, halite
, sylvite
, carnellite, langbeinite
, polyhalite
, and kanite. Kieserite
(MgSO4) may also be included, which often will make up less than four percent of the overall content. However there are approximately 80 different minerals that have been reported found in evaporite deposits (Stewart,1963;Warren,1999) though only about a dozen are common enough to be considered important rock formers.
, epsomite
, gaylussite
, glauberite
, mangadile, mirabilite
, thenardite
and trona
. Non-marine deposites may also contain halite, gypsum, and anhydrite, and may in some cases even be dominated by these minerals, although they did not come from ocean deposits. This however does not make non-marine deposits any less important, these deposits often help to paint a picture into past earth climates. Some particular deposits even show important tectonic and climatic changes. These deposits also may contain important minerals that help in today's economy. Thick non-marine deposits that accumulate tend to form where evaporation rates will exceed the inflow rate, and where there is sufficient soluble supplies. The inflow also has to occur in a closed basin, or one with restricted outflow, so that the sediment has time to pool and form a lake or other standing body of water. Primary Examples of this are called "saline lake deposits". Saline lakes includes things such as perennial lakes which are lakes that are there year round, playa lakes which are lakes that only appear at during certain seasons, or any other terms that are used to define places that hold standing bodies of water intermittently or year round. Some examples of modern non-marine depositional environments is the Great Salt Lake
in Utah, and the Dead Sea
which lies between Jordan and Israel.
Evaporite depositional environments
which meet the above conditions include;
The most significant known evaporite depositions happened during the Messinian salinity crisis
in the basin of the Mediterranean.
salt. In fact, most evaporite formations do not contain more than a few percent of evaporite minerals, the remainder being composed of the more typical detrital
clastic rocks and carbonates. Examples of evaporate formations include occurrences of evaporite sulfur in Eastern Europe and West Asia.
For a formation to be recognised as evaporitic it may simply require recognition of halite pseudomorph
s, sequences composed of some proportion of evaporite minerals, and recognition of mud crack textures or other textures
.
Evaporite minerals, especially nitrate minerals, are economically important in Peru and Chile. Nitrate minerals are often mined for use in the production on fertilizer
and explosives.
Thick halite deposits are expected to become an important location for the disposal of nuclear waste because of their geologic stability, predictable engineering and physical behaviour and imperviousness to groundwater.
Halite formations are famous for their ability to form diapirs which produce ideal locations for trapping petroleum
deposits.
Evaporite minerals start to precipitate
when their concentration in water reaches such a level that they can no longer exist as solutes
.
The minerals precipitate out of solution in the reverse order of their solubilities, such that the order of precipitation from sea water is
The abundance of rocks formed by seawater precipitation is in the same order as the precipitation given above. Thus, limestone
(calcite
) and dolomite
are more common than gypsum
, which is more common than halite
, which is more common than potassium
and magnesium
salts.
Evaporites can also be easily recrystallized
in laboratories in order to investigate the conditions and characteristics of their formation.
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...
sediment
Sedimentary rock
Sedimentary rock are types of rock that are formed by the deposition of material at the Earth's surface and within bodies of water. Sedimentation is the collective name for processes that cause mineral and/or organic particles to settle and accumulate or minerals to precipitate from a solution....
that result from concentration and crystallization
Crystallization
Crystallization is the process of formation of solid crystals precipitating from a solution, melt or more rarely deposited directly from a gas. Crystallization is also a chemical solid–liquid separation technique, in which mass transfer of a solute from the liquid solution to a pure solid...
by evaporation
Evaporation
Evaporation is a type of vaporization of a liquid that occurs only on the surface of a liquid. The other type of vaporization is boiling, which, instead, occurs on the entire mass of the liquid....
from an aqueous solution. There are two types of evaporate deposits, marine which can also be described as ocean deposits, and non-marine which are found in standing bodies of water such as lakes. Evaporites are considered sedimentary rock
Sedimentary rock
Sedimentary rock are types of rock that are formed by the deposition of material at the Earth's surface and within bodies of water. Sedimentation is the collective name for processes that cause mineral and/or organic particles to settle and accumulate or minerals to precipitate from a solution....
s.
Formation of evaporite rocks
Although all water bodies on the surface and in aquifers contain dissolved salts, the water must evaporate into the atmosphere for the minerals to precipitate. For this to happen the water body must enter a restricted environment where water input into this environment remains below the net rate of evaporation. This is usually an aridArid
A region is said to be arid when it is characterized by a severe lack of available water, to the extent of hindering or even preventing the growth and development of plant and animal life...
environment with a small basin fed by a limited input of water. When evaporation occurs, the remaining water is enriched in salts, and they precipitate when the water becomes oversaturated.
Marine evaporites
Marine evaporites tend to have thicker deposits and are usually the focus of more extensive research. They also have a system of evaporation. When scientists evaporate ocean water in a laboratory, the minerals are deposited in a defined order that was first demonstrated by Usiglio in 1884. The first phase of the experiment begins when about 50% of the original water depth remains, at this point minor carbonates begin to form. The next phase in the sequence came when the experiment was left with about 20% of its original level, at this point the mineral gypsumGypsum
Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...
begins to form, which is then followed by halite
Halite
Halite , commonly known as rock salt, is the mineral form of sodium chloride . Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on the amount and type of impurities...
at 10%. Excluding carbonate minerals which tend not to be evaporates. The most common minerals that are generally considered to be the most representative of marine evaporates are, calcite
Calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate . The other polymorphs are the minerals aragonite and vaterite. Aragonite will change to calcite at 380-470°C, and vaterite is even less stable.-Properties:...
, gypsum
Gypsum
Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...
and anhydrite
Anhydrite
Anhydrite is a mineral – anhydrous calcium sulfate, CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium and strontium sulfates, as might be expected from the...
, halite
Halite
Halite , commonly known as rock salt, is the mineral form of sodium chloride . Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on the amount and type of impurities...
, sylvite
Sylvite
Sylvite is potassium chloride in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite . The two are, in fact, isomorphous. Sylvite is colorless to white with shades of yellow and red due to inclusions. It has a Mohs hardness of 2.5 and a specific...
, carnellite, langbeinite
Langbeinite
Langbeinite is a potassium magnesium sulfate mineral with formula: K2Mg23. Langbeinite crystallizes in the isometric - tetartoidal system as transparent colorless or white with pale tints of yellow to green and violet crystalline masses. It has a vitreous luster. The Mohs hardness is 3.5 to 4 and...
, polyhalite
Polyhalite
Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: K2Ca2Mg4·2. Polyhalite crystallizes in the triclinic system although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it...
, and kanite. Kieserite
Kieserite
Kieserite is a highly unstable magnesium sulfate mineral . It has a vitreous luster and it is colorless, grayish-white or yellowish. Its hardness is 3.5 and it has a monoclinic crystal system...
(MgSO4) may also be included, which often will make up less than four percent of the overall content. However there are approximately 80 different minerals that have been reported found in evaporite deposits (Stewart,1963;Warren,1999) though only about a dozen are common enough to be considered important rock formers.
Non-Marine Evaporites
Non-marine evaporites are usually composed of minerals that are not common in marine environments, because the water from which non-marine evaporites precipitate generally have proportions of chemical elements different from those found in the marine environments. Common minerals that are found in these deposits include bleodite, boraxBorax
Borax, also known as sodium borate, sodium tetraborate, or disodium tetraborate, is an important boron compound, a mineral, and a salt of boric acid. It is usually a white powder consisting of soft colorless crystals that dissolve easily in water.Borax has a wide variety of uses...
, epsomite
Epsomite
Epsomite is a hydrous magnesium sulfate mineral with formula MgSO4·7H2O or simply MgSO4. Epsomite forms as encrustations or efflorescences on limestone cavern walls and mine timbers and walls, as a volcanic fumaroles, and as rare beds in evaporate layers...
, gaylussite
Gaylussite
Gaylussite is a carbonate mineral, a hydrated sodium calcium carbonate, formula Na2Ca2·5H2O. It occurs as translucent, vitreous white to grey to yellow monoclinic prismatic crystals. It is an unstable mineral which dehydrates in dry air and decomposes in water.It is formed as an evaporite from...
, glauberite
Glauberite
Glauberite is a sodium calcium sulfate mineral with the formula Na2Ca2, which forms as an evaporite. It is named for the closely related Glauber's salts. Because of its solubility, glauberite is often dissolved away from the crystal matrix leaving a mould into which other minerals are deposited...
, mangadile, mirabilite
Mirabilite
Mirabilite, also known as Glauber's salt, is a hydrous sodium sulfate mineral with the chemical formula Na2SO4·10H2O. It is a vitreous, colorless to white monoclinic mineral which forms as an evaporite from sodium sulfate bearing brines. It is found around saline springs and along saline playa lakes...
, thenardite
Thenardite
Thenardite is an anhydrous sodium sulfate mineral, Na2SO4 which occurs in arid evaporite environments. It also occurs in dry caves and old mine workings as an efflorescence and as a crusty deposit around fumaroles. It occurs in volcanic caves on Mt...
and trona
Trona
Trona ; Na3•2H2O is an evaporite mineral. It is mined as the primary source of sodium carbonate in the United States, where it has replaced the Solvay process used in most of the rest of the world for sodium carbonate production.- Etymology :The word "trona" comes to English by way of either...
. Non-marine deposites may also contain halite, gypsum, and anhydrite, and may in some cases even be dominated by these minerals, although they did not come from ocean deposits. This however does not make non-marine deposits any less important, these deposits often help to paint a picture into past earth climates. Some particular deposits even show important tectonic and climatic changes. These deposits also may contain important minerals that help in today's economy. Thick non-marine deposits that accumulate tend to form where evaporation rates will exceed the inflow rate, and where there is sufficient soluble supplies. The inflow also has to occur in a closed basin, or one with restricted outflow, so that the sediment has time to pool and form a lake or other standing body of water. Primary Examples of this are called "saline lake deposits". Saline lakes includes things such as perennial lakes which are lakes that are there year round, playa lakes which are lakes that only appear at during certain seasons, or any other terms that are used to define places that hold standing bodies of water intermittently or year round. Some examples of modern non-marine depositional environments is the Great Salt Lake
Great Salt Lake
The Great Salt Lake, located in the northern part of the U.S. state of Utah, is the largest salt water lake in the western hemisphere, the fourth-largest terminal lake in the world. In an average year the lake covers an area of around , but the lake's size fluctuates substantially due to its...
in Utah, and the Dead Sea
Dead Sea
The Dead Sea , also called the Salt Sea, is a salt lake bordering Jordan to the east and Israel and the West Bank to the west. Its surface and shores are below sea level, the lowest elevation on the Earth's surface. The Dead Sea is deep, the deepest hypersaline lake in the world...
which lies between Jordan and Israel.
Evaporite depositional environments
Sedimentary depositional environment
In geology, sedimentary depositional environment describes the combination of physical, chemical and biological processes associated with the deposition of a particular type of sediment and, therefore, the rock types that will be formed after lithification, if the sediment is preserved in the rock...
which meet the above conditions include;
- GrabenGrabenIn geology, a graben is a depressed block of land bordered by parallel faults. Graben is German for ditch. Graben is used for both the singular and plural....
areas and half-grabens within continental rift environments fed by limited riverine drainage, usually in subtropical or tropical environments- Example environments at the present which match this is the Denakil Depression, Ethiopia; Death ValleyDeath ValleyDeath Valley is a desert valley located in Eastern California. Situated within the Mojave Desert, it features the lowest, driest, and hottest locations in North America. Badwater, a basin located in Death Valley, is the specific location of the lowest elevation in North America at 282 feet below...
, CaliforniaCaliforniaCalifornia is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...
- Example environments at the present which match this is the Denakil Depression, Ethiopia; Death Valley
- Graben environments in oceanic rift environments fed by limited oceanic input, leading to eventual isolation and evaporation
- Examples include the Red Sea, and the Dead SeaDead SeaThe Dead Sea , also called the Salt Sea, is a salt lake bordering Jordan to the east and Israel and the West Bank to the west. Its surface and shores are below sea level, the lowest elevation on the Earth's surface. The Dead Sea is deep, the deepest hypersaline lake in the world...
in Jordan and Israel
- Examples include the Red Sea, and the Dead Sea
- Internal drainage basins in arid to semi-arid temperate to tropical environments fed by ephemeral drainage
- Example environments at the present include the Simpson DesertSimpson DesertThe Simpson Desert is a large area of dry, red sandy plain and dunes in Northern Territory, South Australia and Queensland in central Australia. It is the fourth largest Australian desert, with an area of 176,500 km² ....
, Western AustraliaWestern AustraliaWestern Australia is a state of Australia, occupying the entire western third of the Australian continent. It is bounded by the Indian Ocean to the north and west, the Great Australian Bight and Indian Ocean to the south, the Northern Territory to the north-east and South Australia to the south-east...
, the Great Salt LakeGreat Salt LakeThe Great Salt Lake, located in the northern part of the U.S. state of Utah, is the largest salt water lake in the western hemisphere, the fourth-largest terminal lake in the world. In an average year the lake covers an area of around , but the lake's size fluctuates substantially due to its...
in UtahUtahUtah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
- Example environments at the present include the Simpson Desert
- Non-basin areas fed exclusively by groundwater seepage from artesian waters
- Example environments include the seep-mounds of the Victoria Desert, fed by the Great Artesian BasinGreat Artesian BasinThe Great Artesian Basin provides the only reliable source of freshwater through much of inland Australia. The basin is the largest and deepest artesian basin in the world, stretching over a total of , with temperatures measured ranging from 30°C to 100°C...
, Australia
- Example environments include the seep-mounds of the Victoria Desert, fed by the Great Artesian Basin
- Restricted coastal plains in regressive sea environments
- Examples include the sabkhaSabkhaSabkha is a transliteration of the Arabic word for a salt flat. Sabkhas are supratidal, forming along arid coastlines and are characterized by evaporite-carbonate deposits with some siliciclastics. Sabkhas form subaerial, prograding and shoaling-upward sequences that have an average thickness of a...
deposits of Iran, Saudi Arabia and the Red Sea; the GarabogazkölGarabogazkölThe Garabogazköl Aylagy, alternatively the Kara-Bogaz-Gol is a shallow inundated depression in the northwestern corner of Turkmenistan. It forms a lagoon of the Caspian Sea with a surface area of about...
of the Caspian SeaCaspian SeaThe Caspian Sea is the largest enclosed body of water on Earth by area, variously classed as the world's largest lake or a full-fledged sea. The sea has a surface area of and a volume of...
- Examples include the sabkha
- Drainage basins feeding into extremely arid environments
- Examples include the Chilean deserts, certain parts of the SaharaSaharaThe Sahara is the world's second largest desert, after Antarctica. At over , it covers most of Northern Africa, making it almost as large as Europe or the United States. The Sahara stretches from the Red Sea, including parts of the Mediterranean coasts, to the outskirts of the Atlantic Ocean...
and the Namib
- Examples include the Chilean deserts, certain parts of the Sahara
The most significant known evaporite depositions happened during the Messinian salinity crisis
Messinian salinity crisis
The Messinian Salinity Crisis, also referred to as the Messinian Event, and in its latest stage as the Lago Mare event, was a geological event during which the Mediterranean Sea went into a cycle of partly or nearly complete desiccation throughout the latter part of the Messinian age of the Miocene...
in the basin of the Mediterranean.
Evaporitic formations
Evaporite formations need not be composed entirely of haliteHalite
Halite , commonly known as rock salt, is the mineral form of sodium chloride . Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on the amount and type of impurities...
salt. In fact, most evaporite formations do not contain more than a few percent of evaporite minerals, the remainder being composed of the more typical detrital
Detrital
Detritus is a geological term used to describe particles of rock derived from pre-existing rock through processes of weathering and erosion. Detrital particles can consist of lithic fragments , or of monomineralic fragments...
clastic rocks and carbonates. Examples of evaporate formations include occurrences of evaporite sulfur in Eastern Europe and West Asia.
For a formation to be recognised as evaporitic it may simply require recognition of halite pseudomorph
Pseudomorph
In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form , resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by another...
s, sequences composed of some proportion of evaporite minerals, and recognition of mud crack textures or other textures
Rock microstructure
Rock microstructure includes the texture of a rock and the small scale rock structures. The words "texture" and "microstructure" are interchangeable, with the latter preferred in modern geological literature...
.
Economic importance of evaporites
Evaporites are important economically because of their mineralogy, their physical properties in-situ and their behaviour within the subsurface.Evaporite minerals, especially nitrate minerals, are economically important in Peru and Chile. Nitrate minerals are often mined for use in the production on fertilizer
Fertilizer
Fertilizer is any organic or inorganic material of natural or synthetic origin that is added to a soil to supply one or more plant nutrients essential to the growth of plants. A recent assessment found that about 40 to 60% of crop yields are attributable to commercial fertilizer use...
and explosives.
Thick halite deposits are expected to become an important location for the disposal of nuclear waste because of their geologic stability, predictable engineering and physical behaviour and imperviousness to groundwater.
Halite formations are famous for their ability to form diapirs which produce ideal locations for trapping petroleum
Petroleum
Petroleum or crude oil is a naturally occurring, flammable liquid consisting of a complex mixture of hydrocarbons of various molecular weights and other liquid organic compounds, that are found in geologic formations beneath the Earth's surface. Petroleum is recovered mostly through oil drilling...
deposits.
Major groups of evaporite minerals
This is a chart that shows minerals that form the marine evaporite rocks, they are usually the most common minerals that appear in this kind of deposit.Mineral class | Mineral name | Chemical Composition |
---|---|---|
Chlorides | Halite Sylvite Carnallite Langbeinite Polyhalite Kainite |
NaCl KCl KMgCl3 * 6H2O K2Mg2(SO4)3 K2Ca2Mg(SO4)6 * H2O KMg(SO4)Cl * 3H2O |
Sulfates | Anhydrate Gypsum Kieserite |
CaSO4 CaSO4 * 2H2O MgSO4 * H2O |
Carbonates | Dolomite Calcite Magnesite |
CaMg(CO3)2 CaCO3 MgCO3 |
- HalidesHalide mineralThe halide mineral class include those minerals with a dominant halide anion . Complex halide minerals may also have polyatomic anions in addition to or that include halides.Examples include the following:*Halite NaCl*Sylvite KCl...
: haliteHaliteHalite , commonly known as rock salt, is the mineral form of sodium chloride . Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on the amount and type of impurities...
, sylviteSylviteSylvite is potassium chloride in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite . The two are, in fact, isomorphous. Sylvite is colorless to white with shades of yellow and red due to inclusions. It has a Mohs hardness of 2.5 and a specific...
(KCl), and fluoriteFluoriteFluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon... - SulfatesSulfate mineralThe sulfate minerals are a class of minerals which include the sulfate ion within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits...
: such as gypsumGypsumGypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...
, bariteBariteBaryte, or barite, is a mineral consisting of barium sulfate. The baryte group consists of baryte, celestine, anglesite and anhydrite. Baryte itself is generally white or colorless, and is the main source of barium...
, and anhydriteAnhydriteAnhydrite is a mineral – anhydrous calcium sulfate, CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium and strontium sulfates, as might be expected from the... - Nitrates: nitratineNitratineNitratine or nitratite, also known as cubic niter , soda niter or Chile saltpeter , is a mineral, the naturally occurring form of sodium nitrate, NaNO3. Nitratine crystallizes in the trigonal system, but rarely occurs as well formed crystals. It is isostructural with calcite...
(soda niter) and niterNiterNiter or nitre is the mineral form of potassium nitrate, KNO3, also known as saltpeter or saltpetre . Historically, the term "niter" – cognate with "natrium", a Latin word for sodium – has been very vaguely defined, and it has been applied to a variety of other minerals and chemical compounds,... - BoratesBorate mineralThe borate minerals are minerals which contain a borate anion group. The borate units may be polymerised similar to the SiO4 unit of the silicate mineral class. This results in B2O5, B3O6, B2O4 anions as well as more complex structures which include hydroxide or halogen anions...
: typically found in arid-salt-lake deposits plentiful in the southwestern USUnited StatesThe United States of America is a federal constitutional republic comprising fifty states and a federal district...
. A common borate is boraxBoraxBorax, also known as sodium borate, sodium tetraborate, or disodium tetraborate, is an important boron compound, a mineral, and a salt of boric acid. It is usually a white powder consisting of soft colorless crystals that dissolve easily in water.Borax has a wide variety of uses...
, which has been used in soapSoapIn chemistry, soap is a salt of a fatty acid.IUPAC. "" Compendium of Chemical Terminology, 2nd ed. . Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford . XML on-line corrected version: created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN...
s as a surfactantSurfactantSurfactants are compounds that lower the surface tension of a liquid, the interfacial tension between two liquids, or that between a liquid and a solid...
. - Carbonates: such as tronaTronaTrona ; Na3•2H2O is an evaporite mineral. It is mined as the primary source of sodium carbonate in the United States, where it has replaced the Solvay process used in most of the rest of the world for sodium carbonate production.- Etymology :The word "trona" comes to English by way of either...
, formed in inland brine lakes.- Some evaporite minerals, such as HanksiteHanksiteHanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ion groups. It has the chemical formula: Na22K92Cl.-Occurrence:...
, are from multiple groups.
- Some evaporite minerals, such as Hanksite
Evaporite minerals start to precipitate
Precipitation (chemistry)
Precipitation is the formation of a solid in a solution or inside anothersolid during a chemical reaction or by diffusion in a solid. When the reaction occurs in a liquid, the solid formed is called the precipitate, or when compacted by a centrifuge, a pellet. The liquid remaining above the solid...
when their concentration in water reaches such a level that they can no longer exist as solutes
Solution
In chemistry, a solution is a homogeneous mixture composed of only one phase. In such a mixture, a solute is dissolved in another substance, known as a solvent. The solvent does the dissolving.- Types of solutions :...
.
The minerals precipitate out of solution in the reverse order of their solubilities, such that the order of precipitation from sea water is
- CalciteCalciteCalcite is a carbonate mineral and the most stable polymorph of calcium carbonate . The other polymorphs are the minerals aragonite and vaterite. Aragonite will change to calcite at 380-470°C, and vaterite is even less stable.-Properties:...
(CaCO3) and dolomiteDolomiteDolomite is a carbonate mineral composed of calcium magnesium carbonate CaMg2. The term is also used to describe the sedimentary carbonate rock dolostone....
(CaMg(CO3)2) - Gypsum (CaSO4-2H2O) and anhydrite (CaSO4).
- Halite (i.e. common salt, NaCl)
- PotassiumPotassiumPotassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...
and magnesiumMagnesiumMagnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...
salts
The abundance of rocks formed by seawater precipitation is in the same order as the precipitation given above. Thus, limestone
Limestone
Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....
(calcite
Calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate . The other polymorphs are the minerals aragonite and vaterite. Aragonite will change to calcite at 380-470°C, and vaterite is even less stable.-Properties:...
) and dolomite
Dolomite
Dolomite is a carbonate mineral composed of calcium magnesium carbonate CaMg2. The term is also used to describe the sedimentary carbonate rock dolostone....
are more common than gypsum
Gypsum
Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...
, which is more common than halite
Halite
Halite , commonly known as rock salt, is the mineral form of sodium chloride . Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on the amount and type of impurities...
, which is more common than potassium
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...
and magnesium
Magnesium
Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...
salts.
Evaporites can also be easily recrystallized
Recrystallization (chemistry)
-Chemistry:In chemistry, recrystallization is a procedure for purifying compounds. The most typical situation is that a desired "compound A" is contaminated by a small amount of "impurity B". There are various methods of purification that may be attempted , which includes recrystallization...
in laboratories in order to investigate the conditions and characteristics of their formation.
See also
- List of minerals
- List of rock types
- Salt domeSalt domeA salt dome is a type of structural dome formed when a thick bed of evaporite minerals found at depth intrudes vertically into surrounding rock strata, forming a diapir....
- DiapirDiapirA diapir is a type of intrusion in which a more mobile and ductily-deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh-Taylor instability-type structures in regions with low tectonic stress...
- Tectonic rifts
- GrabenGrabenIn geology, a graben is a depressed block of land bordered by parallel faults. Graben is German for ditch. Graben is used for both the singular and plural....