Feroxyhyte
Encyclopedia
Feroxyhyte is an oxide/hydroxide of iron
, δ-Fe3+O(OH). Feroxyhyte crystallizes in the hexagonal
system. It forms as brown rounded to concretionary masses. Feroxyhyte is opaque, magnetic, has a yellow streak, and has a relative density of 4.2.
It occurs in manganese
-iron
nodules
on the Atlantic
and Pacific Ocean
floors. It is also found in the Baltic
, White
, and Kara Sea
s. Forms under high pressure conditions and reverts to goethite
on exposure to surface conditions. It also occurs as cement and coatings on clasts in poorly drained soils and sediments, formed by the rapid oxidation
of iron(II) oxide
compounds.
It was first described in 1976 for an occurrence in soils at its type locality
: Kolomyya, Ivano-Frankivsk Oblast
, Ukraine
.
Iron(III) oxide-hydroxide
A number of species are dubbed iron oxide-hydroxide. These chemicals are oxide-hydroxides of iron, and may occur in anhydrous or hydrated forms...
, δ-Fe3+O(OH). Feroxyhyte crystallizes in the hexagonal
Hexagonal crystal system
In crystallography, the hexagonal crystal system is one of the 7 crystal systems, the hexagonal lattice system is one of the 7 lattice systems, and the hexagonal crystal family is one of the 6 crystal families...
system. It forms as brown rounded to concretionary masses. Feroxyhyte is opaque, magnetic, has a yellow streak, and has a relative density of 4.2.
It occurs in manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
-iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
nodules
Manganese nodule
Polymetallic nodules, also called manganese nodules, are rock concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. The core may be microscopically small and is sometimes completely transformed into manganese minerals by crystallization...
on the Atlantic
Atlantic Ocean
The Atlantic Ocean is the second-largest of the world's oceanic divisions. With a total area of about , it covers approximately 20% of the Earth's surface and about 26% of its water surface area...
and Pacific Ocean
Pacific Ocean
The Pacific Ocean is the largest of the Earth's oceanic divisions. It extends from the Arctic in the north to the Southern Ocean in the south, bounded by Asia and Australia in the west, and the Americas in the east.At 165.2 million square kilometres in area, this largest division of the World...
floors. It is also found in the Baltic
Baltic Sea
The Baltic Sea is a brackish mediterranean sea located in Northern Europe, from 53°N to 66°N latitude and from 20°E to 26°E longitude. It is bounded by the Scandinavian Peninsula, the mainland of Europe, and the Danish islands. It drains into the Kattegat by way of the Øresund, the Great Belt and...
, White
White Sea
The White Sea is a southern inlet of the Barents Sea located on the northwest coast of Russia. It is surrounded by Karelia to the west, the Kola Peninsula to the north, and the Kanin Peninsula to the northeast. The whole of the White Sea is under Russian sovereignty and considered to be part of...
, and Kara Sea
Kara Sea
The Kara Sea is part of the Arctic Ocean north of Siberia. It is separated from the Barents Sea to the west by the Kara Strait and Novaya Zemlya, and the Laptev Sea to the east by the Severnaya Zemlya....
s. Forms under high pressure conditions and reverts to goethite
Goethite
Goethite , named after the German polymath Johann Wolfgang von Goethe, is an iron bearing oxide mineral found in soil and other low-temperature environments. Goethite has been well known since prehistoric times for its use as a pigment. Evidence has been found of its use in paint pigment samples...
on exposure to surface conditions. It also occurs as cement and coatings on clasts in poorly drained soils and sediments, formed by the rapid oxidation
Redox
Redox reactions describe all chemical reactions in which atoms have their oxidation state changed....
of iron(II) oxide
Iron(II) oxide
Iron oxide, also known as ferrous oxide, is one of the iron oxides. It is a black-colored powder with the chemical formula . It consists of the chemical element iron in the oxidation state of 2 bonded to oxygen. Its mineral form is known as wüstite. Iron oxide should not be confused with rust,...
compounds.
It was first described in 1976 for an occurrence in soils at its type locality
Type locality (geology)
Type locality , also called type area or type locale, is the where a particular rock type, stratigraphic unit, fossil or mineral species is first identified....
: Kolomyya, Ivano-Frankivsk Oblast
Ivano-Frankivsk Oblast
Ivano-Frankivsk Oblast is an oblast in western Ukraine. Its administrative center is the city of Ivano-Frankivsk. As is the case with most other oblasts of Ukraine this region has the same name as its administrative center – which was renamed by the Soviets after the Ukrainian writer, nationalist...
, Ukraine
Ukraine
Ukraine is a country in Eastern Europe. It has an area of 603,628 km², making it the second largest contiguous country on the European continent, after Russia...
.