Fertile material
Encyclopedia
Fertile material is a term used to describe nuclides which generally themselves do not undergo induced fission
(fissionable by thermal neutrons) but from which fissile
material is generated by neutron absorption and subsequent nuclei conversions. Fertile materials that occur naturally which can be converted into a fissile material by irradiation in a reactor include:
Artificial isotopes formed in the reactor which can be converted into fissile material by one neutron capture include:
Some other actinides need more than one neutron capture before arriving at an isotope which is both fissile and long-lived enough to probably be able to capture another neutron and fission instead of decaying.
Since these require a total of 3 or 4 thermal neutrons to eventually fission, and a thermal neutron fission generates only about 2 to 3 neutrons, these nuclides represent a net loss of neutrons. In a fast reactor, they may require fewer neutrons to achieve fission, as well as producing more neutrons when they do fission.
A fast-neutron reactor, meaning one with little or no neutron moderator
and hence utilising fast neutrons, can be configured as a breeder reactor
, producing more fissile material than it consumes, using fertile material in a blanket around the core, or contained in special fuel rods. Since plutonium-238
, plutonium-240
and plutonium-242
are fertile, accumulation of these and other nonfissile isotopes is less of a problem than in thermal reactor
s, which cannot burn them efficiently. Breeder reactors using thermal-spectrum neutrons are only practical if the thorium fuel cycle
is used, as uranium-233
fissions far more reliably with thermal neutrons than plutonium-239.
Nuclear fission
In nuclear physics and nuclear chemistry, nuclear fission is a nuclear reaction in which the nucleus of an atom splits into smaller parts , often producing free neutrons and photons , and releasing a tremendous amount of energy...
(fissionable by thermal neutrons) but from which fissile
Fissile
In nuclear engineering, a fissile material is one that is capable of sustaining a chain reaction of nuclear fission. By definition, fissile materials can sustain a chain reaction with neutrons of any energy. The predominant neutron energy may be typified by either slow neutrons or fast neutrons...
material is generated by neutron absorption and subsequent nuclei conversions. Fertile materials that occur naturally which can be converted into a fissile material by irradiation in a reactor include:
- thorium-232 which converts into uranium-233Uranium-233Uranium-233 is a fissile isotope of uranium, bred from Thorium as part of the thorium fuel cycle. It has been used in a few nuclear reactors and has been proposed for much wider use as a nuclear fuel. It has a half-life of 160,000 years....
- uranium-234 which converts into uranium-235Uranium-235- References :* .* DOE Fundamentals handbook: Nuclear Physics and Reactor theory , .* A piece of U-235 the size of a grain of rice can produce energy equal to that contained in three tons of coal or fourteen barrels of oil. -External links:* * * one of the earliest articles on U-235 for the...
- uranium-238Uranium-238Uranium-238 is the most common isotope of uranium found in nature. It is not fissile, but is a fertile material: it can capture a slow neutron and after two beta decays become fissile plutonium-239...
which converts into plutonium-239Plutonium-239Plutonium-239 is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 has also been used and is currently the secondary isotope. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in...
Artificial isotopes formed in the reactor which can be converted into fissile material by one neutron capture include:
- plutonium-238Plutonium-238-External links:**...
which converts into plutonium-239Plutonium-239Plutonium-239 is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 has also been used and is currently the secondary isotope. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in... - plutonium-240Plutonium-240Plutonium-240 is an isotope of the metal plutonium formed when plutonium-239 captures a neutron. About 62% to 73% of the time when Pu-239 captures a neutron it undergoes fission; the rest of the time it forms Pu-240. The longer a nuclear fuel element remains in a nuclear reactor the greater the...
which converts into plutonium-241Plutonium-241Plutonium-241 is an isotope of plutonium formed when plutonium-240 captures a neutron. Like Pu-239 but unlike 240Pu, 241Pu is fissile, with a neutron absorption cross section about 1/3 greater than 239Pu, and a similar probability of fissioning on neutron absorption, around 73%. In the non-fission...
Some other actinides need more than one neutron capture before arriving at an isotope which is both fissile and long-lived enough to probably be able to capture another neutron and fission instead of decaying.
- plutonium-242Plutonium-242Pu-242 is one of the isotopes of plutonium, the second longest-lived, with a half-life of 373,300 years.242Pu's halflife is about 15 times as long as Pu-239's halflife; therefore it is 1/15 as radioactive and not one of the larger contributors to nuclear waste radioactivity.242Pu's gamma ray...
to americiumAmericiumAmericium is a synthetic element that has the symbol Am and atomic number 95. This transuranic element of the actinide series is located in the periodic table below the lanthanide element europium, and thus by analogy was named after another continent, America.Americium was first produced in 1944...
-243 to curiumCuriumCurium is a synthetic chemical element with the symbol Cm and atomic number 96. This radioactive transuranic element of the actinide series was named after Marie Skłodowska-Curie and her husband Pierre Curie. Curium was first intentionally produced and identified in summer 1944 by the group of...
-244 to curiumCuriumCurium is a synthetic chemical element with the symbol Cm and atomic number 96. This radioactive transuranic element of the actinide series was named after Marie Skłodowska-Curie and her husband Pierre Curie. Curium was first intentionally produced and identified in summer 1944 by the group of...
-245 - uranium-236Uranium-236- See also :* Depleted uranium* Uranium market* Nuclear reprocessing* United States Enrichment Corporation* Nuclear fuel cycle* Nuclear power-External links:* *...
to neptuniumNeptuniumNeptunium is a chemical element with the symbol Np and atomic number 93. A radioactive metal, neptunium is the first transuranic element and belongs to the actinide series. Its most stable isotope, 237Np, is a by-product of nuclear reactors and plutonium production and it can be used as a...
-237 to plutonium-238Plutonium-238-External links:**...
to plutonium-239Plutonium-239Plutonium-239 is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 has also been used and is currently the secondary isotope. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in... - americiumAmericiumAmericium is a synthetic element that has the symbol Am and atomic number 95. This transuranic element of the actinide series is located in the periodic table below the lanthanide element europium, and thus by analogy was named after another continent, America.Americium was first produced in 1944...
-241 to curiumCuriumCurium is a synthetic chemical element with the symbol Cm and atomic number 96. This radioactive transuranic element of the actinide series was named after Marie Skłodowska-Curie and her husband Pierre Curie. Curium was first intentionally produced and identified in summer 1944 by the group of...
-242 to curiumCuriumCurium is a synthetic chemical element with the symbol Cm and atomic number 96. This radioactive transuranic element of the actinide series was named after Marie Skłodowska-Curie and her husband Pierre Curie. Curium was first intentionally produced and identified in summer 1944 by the group of...
-243 (or, more likely, curium-242 decays to plutonium-238, which also requires one additional neutron to reach a fissile nuclide)
Since these require a total of 3 or 4 thermal neutrons to eventually fission, and a thermal neutron fission generates only about 2 to 3 neutrons, these nuclides represent a net loss of neutrons. In a fast reactor, they may require fewer neutrons to achieve fission, as well as producing more neutrons when they do fission.
A fast-neutron reactor, meaning one with little or no neutron moderator
Neutron moderator
In nuclear engineering, a neutron moderator is a medium that reduces the speed of fast neutrons, thereby turning them into thermal neutrons capable of sustaining a nuclear chain reaction involving uranium-235....
and hence utilising fast neutrons, can be configured as a breeder reactor
Breeder reactor
A breeder reactor is a nuclear reactor capable of generating more fissile material than it consumes because its neutron economy is high enough to breed fissile from fertile material like uranium-238 or thorium-232. Breeders were at first considered superior because of their superior fuel economy...
, producing more fissile material than it consumes, using fertile material in a blanket around the core, or contained in special fuel rods. Since plutonium-238
Plutonium-238
-External links:**...
, plutonium-240
Plutonium-240
Plutonium-240 is an isotope of the metal plutonium formed when plutonium-239 captures a neutron. About 62% to 73% of the time when Pu-239 captures a neutron it undergoes fission; the rest of the time it forms Pu-240. The longer a nuclear fuel element remains in a nuclear reactor the greater the...
and plutonium-242
Plutonium-242
Pu-242 is one of the isotopes of plutonium, the second longest-lived, with a half-life of 373,300 years.242Pu's halflife is about 15 times as long as Pu-239's halflife; therefore it is 1/15 as radioactive and not one of the larger contributors to nuclear waste radioactivity.242Pu's gamma ray...
are fertile, accumulation of these and other nonfissile isotopes is less of a problem than in thermal reactor
Thermal reactor
A thermal reactor is a nuclear reactor that uses slow or thermal neutrons. Most power reactors are of this type. These type of reactors use a neutron moderator to slow neutrons until they approach the average kinetic energy of the surrounding particles, that is, to reduce the speed of the neutrons...
s, which cannot burn them efficiently. Breeder reactors using thermal-spectrum neutrons are only practical if the thorium fuel cycle
Thorium fuel cycle
The thorium fuel cycle is a nuclear fuel cycle that uses the naturally abundant isotope of thorium, , as the fertile material. In the reactor, is transmuted into the fissile artificial uranium isotope which is the nuclear fuel. Unlike natural uranium, natural thorium contains only trace amounts...
is used, as uranium-233
Uranium-233
Uranium-233 is a fissile isotope of uranium, bred from Thorium as part of the thorium fuel cycle. It has been used in a few nuclear reactors and has been proposed for much wider use as a nuclear fuel. It has a half-life of 160,000 years....
fissions far more reliably with thermal neutrons than plutonium-239.