Galactoglucomannan
Encyclopedia
Galactoglucomannan is a water-soluble hemicellulose
, consisting of galactose
, glucose
and mannose
. Many softwood species, e.g. Norway spruce
are rich of galactoglucomannans and can contain it up to 10-20%
groups in locations C2 and C3 in mannose are partially substituted by acetyl
groups.
Hemicellulose
A hemicellulose is any of several heteropolymers , such as arabinoxylans, present along with cellulose in almost all plant cell walls. While cellulose is crystalline, strong, and resistant to hydrolysis, hemicellulose has a random, amorphous structure with little strength...
, consisting of galactose
Galactose
Galactose , sometimes abbreviated Gal, is a type of sugar that is less sweet than glucose. It is a C-4 epimer of glucose....
, glucose
Glucose
Glucose is a simple sugar and an important carbohydrate in biology. Cells use it as the primary source of energy and a metabolic intermediate...
and mannose
Mannose
Mannose is a sugar monomer of the aldohexose series of carbohydrates. Mannose is a C-2 epimer of glucose. It is not part of human metabolism, but is a component of microbial cell walls, and is therefore a target of the immune system and also of antibiotics....
. Many softwood species, e.g. Norway spruce
Norway Spruce
Norway Spruce is a species of spruce native to Europe. It is also commonly referred to as the European Spruce.- Description :...
are rich of galactoglucomannans and can contain it up to 10-20%
Structure
Galactoglucomannan consists of a backbone of randomly distributed (1→4)-linked mannose and glucose units with (1→6)-linked galactose units attached to mannose units. The hydroxylHydroxyl
A hydroxyl is a chemical group containing an oxygen atom covalently bonded with a hydrogen atom. In inorganic chemistry, the hydroxyl group is known as the hydroxide ion, and scientists and reference works generally use these different terms though they refer to the same chemical structure in...
groups in locations C2 and C3 in mannose are partially substituted by acetyl
Acetyl
In organic chemistry, acetyl is a functional group, the acyl with chemical formula COCH3. It is sometimes represented by the symbol Ac . The acetyl group contains a methyl group single-bonded to a carbonyl...
groups.