Gas composition
Encyclopedia
Gas composition: any gas
can be characterised by listing the pure substances it contains, and stating for each substance its proportion of the gas mixture's molecule
count.
To give a familiar example, air has a composition available here, from CRC Handbook of Chemistry and Physics, 1997 Edition of:
The molar
fractions of a complete gas composition must add up to 1.0000.
Note: a gas composition is sometimes also represented in mole percentages. These are simply a factor of 100 larger than molar fractions.
.
It is extremely unlikely that the actual composition of any specific sample of air will completely agree with any definition for standard dry air. While the various definitions for standard dry air all attempt to provide realistic information about the constituents of air, the definitions are important in and of themselves because they establish a standard which can be cited in legal contracts and publications documenting measurement calculation methodologies or equations of state.
The standards below are two examples of commonly used and cited publications that provide a composition for standard dry air.
ISO 6976:1995 provides a definition for standard dry air which specifies an air molar mass of 28.9626 g/mol.
GPA 2145:2009 is published by the Gas Processors Association. It provides a molar mass for air of 28.9625 g/mol, and provides a composition for standard dry air as a footnote.
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...
can be characterised by listing the pure substances it contains, and stating for each substance its proportion of the gas mixture's molecule
Molecule
A molecule is an electrically neutral group of at least two atoms held together by covalent chemical bonds. Molecules are distinguished from ions by their electrical charge...
count.
To give a familiar example, air has a composition available here, from CRC Handbook of Chemistry and Physics, 1997 Edition of:
Pure Gas Name | Symbol | Mole fraction |
---|---|---|
Nitrogen Nitrogen Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere... |
N2 | 0.78084 |
Oxygen Oxygen Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition... |
O2 | 0.209476 |
Argon Argon Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide... |
Ar | 0.00934 |
Carbon Dioxide Carbon dioxide Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom... |
CO2 | 0.0314 |
Neon Neon Neon is the chemical element that has the symbol Ne and an atomic number of 10. Although a very common element in the universe, it is rare on Earth. A colorless, inert noble gas under standard conditions, neon gives a distinct reddish-orange glow when used in either low-voltage neon glow lamps or... |
Ne | 0.00001818 |
Methane Methane Methane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel... |
CH4 | 0.000002 |
Helium Helium Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas that heads the noble gas group in the periodic table... |
He | 0.00000524 |
Krypton Krypton Krypton is a chemical element with the symbol Kr and atomic number 36. It is a member of Group 18 and Period 4 elements. A colorless, odorless, tasteless noble gas, krypton occurs in trace amounts in the atmosphere, is isolated by fractionally distilling liquified air, and is often used with other... |
Kr | 0.00000114 |
Hydrogen Hydrogen Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly... |
H2 | 0.0000005 |
Xenon Xenon Xenon is a chemical element with the symbol Xe and atomic number 54. The element name is pronounced or . A colorless, heavy, odorless noble gas, xenon occurs in the Earth's atmosphere in trace amounts... |
Xe | 0.000000087 |
The molar
Mole (unit)
The mole is a unit of measurement used in chemistry to express amounts of a chemical substance, defined as an amount of a substance that contains as many elementary entities as there are atoms in 12 grams of pure carbon-12 , the isotope of carbon with atomic weight 12. This corresponds to a value...
fractions of a complete gas composition must add up to 1.0000.
Note: a gas composition is sometimes also represented in mole percentages. These are simply a factor of 100 larger than molar fractions.
See also
Standard Dry Air -- an agreed-upon gas composition for air from which all water vapour has been removed. There are various standards bodies which publish documents that define a dry air gas composition. Each standard provides a list of constituent concentrations, a gas density at standard conditions and a molar massMolar mass
Molar mass, symbol M, is a physical property of a given substance , namely its mass per amount of substance. The base SI unit for mass is the kilogram and that for amount of substance is the mole. Thus, the derived unit for molar mass is kg/mol...
.
It is extremely unlikely that the actual composition of any specific sample of air will completely agree with any definition for standard dry air. While the various definitions for standard dry air all attempt to provide realistic information about the constituents of air, the definitions are important in and of themselves because they establish a standard which can be cited in legal contracts and publications documenting measurement calculation methodologies or equations of state.
The standards below are two examples of commonly used and cited publications that provide a composition for standard dry air.
ISO 6976:1995 provides a definition for standard dry air which specifies an air molar mass of 28.9626 g/mol.
GPA 2145:2009 is published by the Gas Processors Association. It provides a molar mass for air of 28.9625 g/mol, and provides a composition for standard dry air as a footnote.