Heavy mineral sands ore deposits
Encyclopedia
Heavy mineral sand
Sand
Sand is a naturally occurring granular material composed of finely divided rock and mineral particles.The composition of sand is highly variable, depending on the local rock sources and conditions, but the most common constituent of sand in inland continental settings and non-tropical coastal...

s
are a class of ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....

 deposit which is an important source of zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...

, titanium
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

, thorium
Thorium
Thorium is a natural radioactive chemical element with the symbol Th and atomic number 90. It was discovered in 1828 and named after Thor, the Norse god of thunder....

, tungsten
Tungsten
Tungsten , also known as wolfram , is a chemical element with the chemical symbol W and atomic number 74.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as...

, rare earth element
Rare earth element
As defined by IUPAC, rare earth elements or rare earth metals are a set of seventeen chemical elements in the periodic table, specifically the fifteen lanthanides plus scandium and yttrium...

s, the industrial minerals diamond
Diamond
In mineralogy, diamond is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions...

, sapphire
Sapphire
Sapphire is a gemstone variety of the mineral corundum, an aluminium oxide , when it is a color other than red or dark pink; in which case the gem would instead be called a ruby, considered to be a different gemstone. Trace amounts of other elements such as iron, titanium, or chromium can give...

, garnet
Garnet
The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...

, and occasionally precious metals or gemstone
Gemstone
A gemstone or gem is a piece of mineral, which, in cut and polished form, is used to make jewelry or other adornments...

s.

Heavy mineral sands are placer deposit
Placer deposit
In geology, a placer deposit or placer is an accumulation of valuable minerals formed by gravity separation during sedimentary processes. The name is from the Spanish word placer, meaning "alluvial sand". Placer mining is an important source of gold, and was the main technique used in the early...

s formed most usually in beach
Beach
A beach is a geological landform along the shoreline of an ocean, sea, lake or river. It usually consists of loose particles which are often composed of rock, such as sand, gravel, shingle, pebbles or cobblestones...

 environments by concentration due to the specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 of the mineral grains. It is equally likely that some concentrations of heavy minerals (aside from the usual gold
Gold
Gold is a chemical element with the symbol Au and an atomic number of 79. Gold is a dense, soft, shiny, malleable and ductile metal. Pure gold has a bright yellow color and luster traditionally considered attractive, which it maintains without oxidizing in air or water. Chemically, gold is a...

 placers) exist within streambeds, but most are of a low grade and are relatively small.

Grade and tonnage distribution

Estimated ilmenite production
in thousands of tons for 2006

according to U.S. Geological Survey

Country Production
Australia
Australia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...

 
1,140
South Africa
South Africa
The Republic of South Africa is a country in southern Africa. Located at the southern tip of Africa, it is divided into nine provinces, with of coastline on the Atlantic and Indian oceans...

 
952
Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...

809
China
China
Chinese civilization may refer to:* China for more general discussion of the country.* Chinese culture* Greater China, the transnational community of ethnic Chinese.* History of China* Sinosphere, the area historically affected by Chinese culture...

 
400
Norway
Norway
Norway , officially the Kingdom of Norway, is a Nordic unitary constitutional monarchy whose territory comprises the western portion of the Scandinavian Peninsula, Jan Mayen, and the Arctic archipelago of Svalbard and Bouvet Island. Norway has a total area of and a population of about 4.9 million...

 
380
United States
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...

 
300
Ukraine
Ukraine
Ukraine is a country in Eastern Europe. It has an area of 603,628 km², making it the second largest contiguous country on the European continent, after Russia...

 
220
India
India
India , officially the Republic of India , is a country in South Asia. It is the seventh-largest country by geographical area, the second-most populous country with over 1.2 billion people, and the most populous democracy in the world...

 
200
Brazil
Brazil
Brazil , officially the Federative Republic of Brazil , is the largest country in South America. It is the world's fifth largest country, both by geographical area and by population with over 192 million people...

 
130
Vietnam
Vietnam
Vietnam – sometimes spelled Viet Nam , officially the Socialist Republic of Vietnam – is the easternmost country on the Indochina Peninsula in Southeast Asia. It is bordered by China to the north, Laos to the northwest, Cambodia to the southwest, and the South China Sea –...

 
100
Mozambique
Mozambique
Mozambique, officially the Republic of Mozambique , is a country in southeastern Africa bordered by the Indian Ocean to the east, Tanzania to the north, Malawi and Zambia to the northwest, Zimbabwe to the west and Swaziland and South Africa to the southwest...

 
(750)
Madagascar
Madagascar
The Republic of Madagascar is an island country located in the Indian Ocean off the southeastern coast of Africa...

 
(700)
Senegal
Senegal
Senegal , officially the Republic of Senegal , is a country in western Africa. It owes its name to the Sénégal River that borders it to the east and north...

 
(150)
Other countries 120
Total world 4,800

|}
The grade of a typical heavy mineral sand ore deposit is usually low. Within the 21st century, the lowest cut-off grades of heavy minerals, as a total heavy mineral (THM) concentrate from the bulk sand, in most ore deposits of this type is around 1% heavy minerals, although several are higher grade.

Of this total heavy mineral concentrate (THM), the components are typically
  • Zircon
    Zircon
    Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is 1–x4x–y...

    , from 1% of THM to upwards of 50% of THM,
  • Ilmenite
    Ilmenite
    Ilmenite is a weakly magnetic titanium-iron oxide mineral which is iron-black or steel-gray. It is a crystalline iron titanium oxide . It crystallizes in the trigonal system, and it has the same crystal structure as corundum and hematite....

    , generally of 10% to 60% of THM
  • Rutile
    Rutile
    Rutile is a mineral composed primarily of titanium dioxide, TiO2.Rutile is the most common natural form of TiO2. Two rarer polymorphs of TiO2 are known:...

    , from 5% to 25% of THM
  • Leucoxene
    Leucoxene
    Leucoxene is a fine granular alteration product of titanium minerals. It varies in color from yellow to brown.It consists mainly of rutile or anatase...

    , from 1% to 10% of THM
  • Trash minerals, typically quartz
    Quartz
    Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

    , magnetite
    Magnetite
    Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

    , garnet
    Garnet
    The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...

    , chromite
    Chromite
    Chromite is an iron chromium oxide: FeCr2O4. It is an oxide mineral belonging to the spinel group. Magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite ; substitution of aluminium occurs leading to hercynite .-Occurrence:Chromite is found in...

     and kyanite
    Kyanite
    Kyanite, whose name derives from the Greek word kuanos sometimes referred to as "kyanos", meaning deep blue, is a typically blue silicate mineral, commonly found in aluminium-rich metamorphic pegmatites and/or sedimentary rock. Kyanite in metamorphic rocks generally indicates pressures higher than...

    , which usually account for the remaining bulk of the THM content
  • Slimes, typically minerals as above and heavy clay minerals, too fine to be economically extracted.


Generally, as zircon is the most valuable component and a critical ore component, high-zircon sands are the most valuable. Thereafter, rutile, leucoxene and then ilmenite in terms of value given to the ore. As a generality, typically the valuable components of the THM concentrate rarely exceed 30%.

Being ancient stranded dune systems, the tonnage of most deposits in excess of several tens of millions of tonnes to several hundred million tonnes. For example, the medium-sized Coburn
Coburn
Coburn may refer to:* Coburn , an electronic music band from the United Kingdom* Coburn, California, an unincorporated community in Monterey County, California, USA* Coburn, Pennsylvania, a census-designated place in Centre County, Pennsylvania, USA...

 mineral sands deposit, Western Australia
Western Australia
Western Australia is a state of Australia, occupying the entire western third of the Australian continent. It is bounded by the Indian Ocean to the north and west, the Great Australian Bight and Indian Ocean to the south, the Northern Territory to the north-east and South Australia to the south-east...

, is 230 million tonnes at 1.1% heavy minerals, and is 13km long.

Source

The source of heavy mineral sands is in a hardrock source within the erosion
Erosion
Erosion is when materials are removed from the surface and changed into something else. It only works by hydraulic actions and transport of solids in the natural environment, and leads to the deposition of these materials elsewhere...

al areas of a river which carries its load of sediment
Sediment
Sediment is naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of fluids such as wind, water, or ice, and/or by the force of gravity acting on the particle itself....

 into the ocean, where the sediments are caught up in littoral drift or longshore drift
Longshore drift
Longshore drift consists of the transportation of sediments along a coast at an angle to the shoreline, which is dependent on prevailing wind direction, swash and backwash. This process occurs in the littoral zone, and in or within close proximity to the surf zone...

. Rocks are occasionally eroded directly by wave action shed detritus
Detritus
Detritus is a biological term used to describe dead or waste organic material.Detritus may also refer to:* Detritus , a geological term used to describe the particles of rock produced by weathering...

, which is caught up in longshore drift and washed up onto beaches where the lighter minerals are winnowed.

The source rocks which provide the heavy mineral sands determine the composition of the economic minerals. The source of zircon
Zircon
Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is 1–x4x–y...

, monazite
Monazite
Monazite is a reddish-brown phosphate mineral containing rare earth metals. It occurs usually in small isolated crystals. There are actually at least four different kinds of monazite, depending on relative elemental composition of the mineral:...

, rutile
Rutile
Rutile is a mineral composed primarily of titanium dioxide, TiO2.Rutile is the most common natural form of TiO2. Two rarer polymorphs of TiO2 are known:...

, sometimes tungsten
Tungsten
Tungsten , also known as wolfram , is a chemical element with the chemical symbol W and atomic number 74.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as...

, and some ilmenite
Ilmenite
Ilmenite is a weakly magnetic titanium-iron oxide mineral which is iron-black or steel-gray. It is a crystalline iron titanium oxide . It crystallizes in the trigonal system, and it has the same crystal structure as corundum and hematite....

 is usually granite
Granite
Granite is a common and widely occurring type of intrusive, felsic, igneous rock. Granite usually has a medium- to coarse-grained texture. Occasionally some individual crystals are larger than the groundmass, in which case the texture is known as porphyritic. A granitic rock with a porphyritic...

. The source of ilmenite, garnet, sapphire and diamond is ultramafic and mafic
Mafic
Mafic is an adjective describing a silicate mineral or rock that is rich in magnesium and iron; the term is a portmanteau of the words "magnesium" and "ferric". Most mafic minerals are dark in color and the relative density is greater than 3. Common rock-forming mafic minerals include olivine,...

 rocks, such as kimberlite
Kimberlite
Kimberlite is a type of potassic volcanic rock best known for sometimes containing diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond in 1871 spawned a diamond rush, eventually creating the Big Hole....

 or basalt
Basalt
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey...

. Garnet is also sourced commonly from metamorphic rocks, such as amphibolite
Amphibolite
Amphibolite is the name given to a rock consisting mainly of hornblende amphibole, the use of the term being restricted, however, to metamorphic rocks. The modern terminology for a holocrystalline plutonic igneous rocks composed primarily of hornblende amphibole is a hornblendite, which are...

 schist
Schist
The schists constitute a group of medium-grade metamorphic rocks, chiefly notable for the preponderance of lamellar minerals such as micas, chlorite, talc, hornblende, graphite, and others. Quartz often occurs in drawn-out grains to such an extent that a particular form called quartz schist is...

s. Precious metals are sourced from ore deposits hosted within metamorphic rock
Metamorphic rock
Metamorphic rock is the transformation of an existing rock type, the protolith, in a process called metamorphism, which means "change in form". The protolith is subjected to heat and pressure causing profound physical and/or chemical change...

s.

Transport

The accumulation of a heavy mineral deposit requires a source of sediment containing heavy minerals onto a beach system in a volume which exceeds the rate of removal from the trap site. For this reason not all beaches which are supplied by sands containing heavy minerals will form economic concentrations of the minerals. This factor can be qualitatively or quantitatively measured through the ZTR index
ZTR index
The ZTR index is a method of determining how weathered, both chemically and mechanically, a sediment is. The letters in ZTR stand for 3 common minerals found in ultra-weathered sediments: zircon, tourmaline, and rutile...

.

Trap

The heavy minerals within the source sediments attain an economic concentration by accumulation within low-energy environments within streams and most usually on beaches. In beach placer deposits the lowest energy zone on the beach is the swash zone, where turbulent surf washes up on the beach face and loses energy. In this zone, heavier grains accumulate because they are denser than the quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

 grains they occur with and become stranded. It is for this reason that beach placer deposits are often referred to as "strand-line deposits".

The size and position of a heavy mineral deposit is a function of the wave energy reaching the beach, the mean grainsize of the beach sediments, and the current height of the ocean.

Anecdotal reports of certain beach placers which are forming in modern times suggest that the greatest enrichment of the sands tends to occur in storm events which are energetic enough to remove most of the beaches sediment load—a process favoring the lighter minerals. The resultant 'clinker' sands which were left behind were mined during low tide following major storm events, suggesting that most beach placer deposits are formed during such cycles.

In most cases, fossil
Fossil
Fossils are the preserved remains or traces of animals , plants, and other organisms from the remote past...

ised dune
Dune
In physical geography, a dune is a hill of sand built by wind. Dunes occur in different forms and sizes, formed by interaction with the wind. Most kinds of dunes are longer on the windward side where the sand is pushed up the dune and have a shorter "slip face" in the lee of the wind...

 systems are exploited for heavy mineral sands because they are from the ocean and because they are often remnants of previous intraglacial highstands.

Tectonic activity, which results in coastlines rising from the ocean, may also cause a beach system to become stranded above the high water mark and lock in the heavy mineral sands. Similarly, a beach system which is drowned by the subsidence of a coastline may be preserved, often for millions of years, until it is either covered by sedimentation or rises from the ocean.

Specific trap sites for heavy mineral sand placer deposits are in beaches on the leeward side of headland
Headlands and bays
Headlands and bays are two related features of the coastal environment.- Geology and geography :Headlands and bays are often found on the same coastline. A bay is surrounded by land on three sides, whereas a headland is surrounded by water on three sides. Headlands are characterized by high,...

s, as this forms a low-energy zone which traps sediments carried along by the longshore drift
Longshore drift
Longshore drift consists of the transportation of sediments along a coast at an angle to the shoreline, which is dependent on prevailing wind direction, swash and backwash. This process occurs in the littoral zone, and in or within close proximity to the surf zone...

. Also, sand bars developed at the mouths of rivers which feed the placer deposits are rich trap sites where the winnowing action of the waves are most efficient, because heavy minerals, if they are going to be too heavy to be moved, will deposit at an isthmus
Isthmus
An isthmus is a narrow strip of land connecting two larger land areas usually with waterforms on either side.Canals are often built through isthmuses where they may be particularly advantageous to create a shortcut for marine transportation...

 in preference to drifting too far down the beach.

Diamond sands

The coast of Namibia
Namibia
Namibia, officially the Republic of Namibia , is a country in southern Africa whose western border is the Atlantic Ocean. It shares land borders with Angola and Zambia to the north, Botswana to the east and South Africa to the south and east. It gained independence from South Africa on 21 March...

 is host to economic diamantiferous beach sands, which are exploited by building sea walls and isolating stretches of coastline. The beaches are so isolated that they are sometimes processed in their entirety, down to the bedrock
Bedrock
In stratigraphy, bedrock is the native consolidated rock underlying the surface of a terrestrial planet, usually the Earth. Above the bedrock is usually an area of broken and weathered unconsolidated rock in the basal subsoil...

, in search of diamonds. Such deposits have been sought around the world, with sporadic reports of high-value stones but no instances of economic quantities of sediment.

Environmental concerns

The mining of beach sands and of fossilized beach placers is often controversial because the operation requires the strip mining of large areas. Often this land is in ecologically sensitive surroundings and contains fragile ecosystem
Ecosystem
An ecosystem is a biological environment consisting of all the organisms living in a particular area, as well as all the nonliving , physical components of the environment with which the organisms interact, such as air, soil, water and sunlight....

s built up on poor sandy soils.

The mining process is ideally modelled on the extraction operations underway in Australia
Australia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...

, where the strip mining is followed by rehabilitation of the mined areas including intensive re-vegetation with ecologically similar species, re-contouring of the land to its original shape, including dunes, and management of groundwater
Groundwater
Groundwater is water located beneath the ground surface in soil pore spaces and in the fractures of rock formations. A unit of rock or an unconsolidated deposit is called an aquifer when it can yield a usable quantity of water. The depth at which soil pore spaces or fractures and voids in rock...

 resources. Modern mining practices tend to favor dry mining rather than dredging operations, due to the advent of electrostatic mineral separation processes.

In practice, not all mining of sub-Saharan Africa
Sub-Saharan Africa
Sub-Saharan Africa as a geographical term refers to the area of the African continent which lies south of the Sahara. A political definition of Sub-Saharan Africa, instead, covers all African countries which are fully or partially located south of the Sahara...

n deposits is carried out in such an environmentally responsible manner, although some South Africa
South Africa
The Republic of South Africa is a country in southern Africa. Located at the southern tip of Africa, it is divided into nine provinces, with of coastline on the Atlantic and Indian oceans...

n mines do practice dune rehabilitation http://www.rbm.co.za. The mining of the coast of South America
South America
South America is a continent situated in the Western Hemisphere, mostly in the Southern Hemisphere, with a relatively small portion in the Northern Hemisphere. The continent is also considered a subcontinent of the Americas. It is bordered on the west by the Pacific Ocean and on the north and east...

, in particular Chile
Chile
Chile ,officially the Republic of Chile , is a country in South America occupying a long, narrow coastal strip between the Andes mountains to the east and the Pacific Ocean to the west. It borders Peru to the north, Bolivia to the northeast, Argentina to the east, and the Drake Passage in the far...

 and Ecuador
Ecuador
Ecuador , officially the Republic of Ecuador is a representative democratic republic in South America, bordered by Colombia on the north, Peru on the east and south, and by the Pacific Ocean to the west. It is one of only two countries in South America, along with Chile, that do not have a border...

, is carried out in an environmentally responsible manner.

Examples of environmentally sensitive and politically sensitive mineral sands mining operations which have gained public attention and galvanised environmental activism responses to mining proposals include the Tuart-Ludlow mineral sands mine, Western Australia, and the culmination of conservationist efforts to preserve Rainbow Beach and Fraser Island, Queensland, Australia. These latter campaigns successfully lobbied government and saw Fraser Island and Rainbow Beach protected by the High Court of Australia, however the Tuart-Ludlow campaign failed to protect the Tuart forest
Tuart Forest National Park
Tuart Forest National Park is a national park in the South West region of Western Australia , south of Perth. It contains the largest remaining section of pure tuart forest in the world. Traditionally the state forest associated with this stand of trees has been known as the Ludlow State...

s in coastal Western Australia.

Similar mineral sand mining operations were carried out for 35 years in and adjacent to National Parks at Hawks Nest, New South Wales
Hawks Nest, New South Wales
Hawks Nest is a suburb of the Great Lakes Council Local Government Area in the Hunter and Mid North Coast regions of New South Wales, Australia, located north of Port Stephens between the Tasman Sea and the Myall River...

, and continue to be carried out on Stradbroke Island, Queensland.
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