Isotopes of hafnium
Encyclopedia
Natural hafnium
(Hf) consists of five stable isotope
s (176Hf, 177Hf, 178Hf, 179Hf, and 180Hf) and one very long-lived radioisotope, 174Hf, with a half-life
of 2×1015 years. In addition, there are 30 other known radionuclide
s, the most stable of which is 182Hf with a half-life of 8.9×106 years. No other radioisotope has a half-life over 1.87 days. Most isotopes have half-lives under 1 minute. There are also 27 known nuclear isomer
s, the most stable of which is 178m3Hf with a half-life of 31 years.
Standard atomic mass: 178.49(2) u
Hafnium
Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869. Hafnium was the penultimate stable...
(Hf) consists of five stable isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...
s (176Hf, 177Hf, 178Hf, 179Hf, and 180Hf) and one very long-lived radioisotope, 174Hf, with a half-life
Half-life
Half-life, abbreviated t½, is the period of time it takes for the amount of a substance undergoing decay to decrease by half. The name was originally used to describe a characteristic of unstable atoms , but it may apply to any quantity which follows a set-rate decay.The original term, dating to...
of 2×1015 years. In addition, there are 30 other known radionuclide
Radionuclide
A radionuclide is an atom with an unstable nucleus, which is a nucleus characterized by excess energy available to be imparted either to a newly created radiation particle within the nucleus or to an atomic electron. The radionuclide, in this process, undergoes radioactive decay, and emits gamma...
s, the most stable of which is 182Hf with a half-life of 8.9×106 years. No other radioisotope has a half-life over 1.87 days. Most isotopes have half-lives under 1 minute. There are also 27 known nuclear isomer
Nuclear isomer
A nuclear isomer is a metastable state of an atomic nucleus caused by the excitation of one or more of its nucleons . "Metastable" refers to the fact that these excited states have half-lives more than 100 to 1000 times the half-lives of the other possible excited nuclear states...
s, the most stable of which is 178m3Hf with a half-life of 31 years.
Standard atomic mass: 178.49(2) u
Table
nuclide symbol |
Z(p Proton The proton is a subatomic particle with the symbol or and a positive electric charge of 1 elementary charge. One or more protons are present in the nucleus of each atom, along with neutrons. The number of protons in each atom is its atomic number.... ) |
N(n Neutron The neutron is a subatomic hadron particle which has the symbol or , no net electric charge and a mass slightly larger than that of a proton. With the exception of hydrogen, nuclei of atoms consist of protons and neutrons, which are therefore collectively referred to as nucleons. The number of... ) |
isotopic mass (u) |
half-lifeBold for isotopes with half-lives longer than the age of the universe (nearly stable) | decay mode(s)Abbreviations: EC: Electron capture Electron capture Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino... IT: Isomeric transition Isomeric transition An isomeric transition is a radioactive decay process that involves emission of a gamma ray from an atom where the nucleus is in an excited metastable state, referred to in its excited state, as a nuclear isomer.... |
daughter isotope(s)Bold for stable isotopes |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
153Hf | 72 | 81 | 152.97069(54)# | 400# ms [>200 ns] | 1/2+# | ||||
153mHf | 750(100)# keV | 500# ms | 11/2-# | ||||||
154Hf | 72 | 82 | 153.96486(54)# | 2(1) sec | β+ Beta decay In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a... |
154Lu | 0+ | ||
α Alpha decay Alpha decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle and thereby transforms into an atom with a mass number 4 less and atomic number 2 less... (rare) |
150Yb | ||||||||
155Hf | 72 | 83 | 154.96339(43)# | 890(120) ms | β+ | 155Lu | 7/2-# | ||
α (rare) | 151Yb | ||||||||
156Hf | 72 | 84 | 155.95936(22) | 23(1) ms | α (97%) | 152Yb | 0+ | ||
β+ (3%) | 156Lu | ||||||||
156mHf | 1959.0(10) keV | 480(40) µs | 8+ | ||||||
157Hf | 72 | 85 | 156.95840(21)# | 115(1) ms | α (86%) | 153Yb | 7/2- | ||
β+ (14%) | 157Lu | ||||||||
158Hf | 72 | 86 | 157.954799(19) | 2.84(7) sec | β+ (55%) | 158Lu | 0+ | ||
α (45%) | 154Yb | ||||||||
159Hf | 72 | 87 | 158.953995(18) | 5.20(10) sec | β+ (59%) | 159Lu | 7/2-# | ||
α (41%) | 155Yb | ||||||||
160Hf | 72 | 88 | 159.950684(12) | 13.6(2) sec | β+ (99.3%) | 160Lu | 0+ | ||
α (.7%) | 156Yb | ||||||||
161Hf | 72 | 89 | 160.950275(24) | 18.2(5) sec | β+ (99.7%) | 161Lu | 3/2-# | ||
α (.3%) | 157Yb | ||||||||
162Hf | 72 | 90 | 161.94721(1) | 39.4(9) sec | β+ (99.99%) | 162Lu | 0+ | ||
α (.008%) | 158Yb | ||||||||
163Hf | 72 | 91 | 162.94709(3) | 40.0(6) sec | β+ | 163Lu | 3/2-# | ||
α (10−4%) | 159Yb | ||||||||
164Hf | 72 | 92 | 163.944367(22) | 111(8) sec | β+ | 164Lu | 0+ | ||
165Hf | 72 | 93 | 164.94457(3) | 76(4) sec | β+ | 165Lu | (5/2-) | ||
166Hf | 72 | 94 | 165.94218(3) | 6.77(30) min | β+ | 166Lu | 0+ | ||
167Hf | 72 | 95 | 166.94260(3) | 2.05(5) min | β+ | 167Lu | (5/2)- | ||
168Hf | 72 | 96 | 167.94057(3) | 25.95(20) min | β+ | 168Lu | 0+ | ||
169Hf | 72 | 97 | 168.94126(3) | 3.24(4) min | β+ | 169Lu | (5/2)- | ||
170Hf | 72 | 98 | 169.93961(3) | 16.01(13) hr | EC Electron capture Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino... |
170Lu | 0+ | ||
171Hf | 72 | 99 | 170.94049(3) | 12.1(4) hr | β+ | 171Lu | 7/2(+) | ||
171mHf | 21.93(9) keV | 29.5(9) sec | IT Isomeric transition An isomeric transition is a radioactive decay process that involves emission of a gamma ray from an atom where the nucleus is in an excited metastable state, referred to in its excited state, as a nuclear isomer.... |
171Hf | 1/2(-) | ||||
172Hf | 72 | 100 | 171.939448(26) | 1.87(3) yr | EC | 172Lu | 0+ | ||
172mHf | 2005.58(11) keV | 163(3) ns | (8-) | ||||||
173Hf | 72 | 101 | 172.94051(3) | 23.6(1) hr | β+ | 173Lu | 1/2- | ||
174Hfprimordial Primordial nuclide In geochemistry and geonuclear physics, primordial nuclides or primordial isotopes are nuclides found on the earth that have existed in their current form since before Earth was formed. Only 288 such nuclides are known... radionuclide Radionuclide A radionuclide is an atom with an unstable nucleus, which is a nucleus characterized by excess energy available to be imparted either to a newly created radiation particle within the nucleus or to an atomic electron. The radionuclide, in this process, undergoes radioactive decay, and emits gamma... |
72 | 102 | 173.940046(3) | 2.0(4)×1015 yr | α | 170Yb | 0+ | 0.0016(1) | 0.001619-0.001621 |
174m1Hf | 1549.3 keV | 138(4) ns | (6+) | ||||||
174m2Hf | 1797.5(20) keV | 2.39(4) µs | (8-) | ||||||
174m3Hf | 1797.5 keV | 2.39(4) µs | (8-) | ||||||
174m4Hf | 3311.7 keV | 3.7(2) µs | (14+) | ||||||
175Hf | 72 | 103 | 174.941509(3) | 70(2) days | β+ | 175Lu | 5/2- | ||
176HfUsed in Lutetium-Hafnium dating Radiometric dating Radiometric dating is a technique used to date materials such as rocks, usually based on a comparison between the observed abundance of a naturally occurring radioactive isotope and its decay products, using known decay rates... |
72 | 104 | 175.9414086(24) | Observationally StableBelieved to undergo α decay to 172Yb | 0+ | 0.0526(7) | 0.05206-0.05271 | ||
177Hf | 72 | 105 | 176.9432207(23) | Observationally StableBelieved to undergo α decay to 173Yb | 7/2- | 0.1860(9) | 0.18593-0.18606 | ||
177m1Hf | 1315.4504(8) keV | 1.09(5) sec | 23/2+ | ||||||
177m2Hf | 1342.38(20) keV | 55.9(12) µs | (19/2-) | ||||||
177m3Hf | 2740.02(15) keV | 51.4(5) min | 37/2- | ||||||
178Hf | 72 | 106 | 177.9436988(23) | Observationally StableBelieved to undergo α decay to 174Yb | 0+ | 0.2728(7) | 0.27278-0.27297 | ||
178m1Hf | 1147.423(5) keV | 4.0(2) sec | 8- | ||||||
178m2Hf | 2573.5(5) keV | 68(2) µs | (14-) | ||||||
178m3Hf | 2445.69(11) keV | 31(1) yr | 16+ | ||||||
179Hf | 72 | 107 | 178.9458161(23) | Observationally StableBelieved to undergo α decay to 175Yb | 9/2+ | 0.1362(2) | 0.13619-0.1363 | ||
179m1Hf | 375.0367(25) keV | 18.67(4) sec | 1/2- | ||||||
179m2Hf | 1105.84(19) keV | 25.05(25) days | 25/2- | ||||||
180Hf | 72 | 108 | 179.9465500(23) | Observationally StableBelieved to undergo α decay to 176Yb | 0+ | 0.3508(16) | 0.35076-0.351 | ||
180m1Hf | 1141.48(4) keV | 5.47(4) hr | 8- | ||||||
180m2Hf | 1374.15(4) keV | 0.57(2) µs | (4-) | ||||||
180m3Hf | 2425.8(10) keV | 15(5) µs | (10+) | ||||||
180m4Hf | 2486.3(9) keV | 10(1) µs | 12+ | ||||||
180m5Hf | 2538.3(12) keV | >10 µs | (14+) | ||||||
180m6Hf | 3599.3(18) keV | 90(10) µs | (18-) | ||||||
181Hf | 72 | 109 | 180.9491012(23) | 42.39(6) days | β- | 181Ta | 1/2- | ||
181m1Hf | 595(3) keV | 80(5) µs | (9/2+) | ||||||
181m2Hf | 1040(10) keV | ~100 µs | (17/2+) | ||||||
181m3Hf | 1738(10) keV | 1.5(5) ms | (27/2-) | ||||||
182Hf | 72 | 110 | 181.950554(7) | 8.90(9)×106 yr | β- | 182Ta | 0+ | ||
182mHf | 1172.88(18) keV | 61.5(15) min | β- (58%) | 182Ta | 8- | ||||
IT (42%) | 182Hf | ||||||||
183Hf | 72 | 111 | 182.95353(3) | 1.067(17) hr | β- | 183Ta | (3/2-) | ||
184Hf | 72 | 112 | 183.95545(4) | 4.12(5) hr | β- | 184Ta | 0+ | ||
184mHf | 1272.4(4) keV | 48(10) sec | β- | 184Ta | 8- | ||||
185Hf | 72 | 113 | 184.95882(21)# | 3.5(6) min | β- | 185Ta | 3/2-# | ||
186Hf | 72 | 114 | 185.96089(32)# | 2.6(12) min | β- | 186Ta | 0+ | ||
187Hf | 72 | 115 | 186.96459(43)# | 30# s [>300 ns] | |||||
188Hf | 72 | 116 | 187.96685(54)# | 20# s [>300 ns] | 0+ |