Lustre (mineralogy)
Encyclopedia
Lustre is a description of the way light interacts with the surface of a crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

, rock
Rock (geology)
In geology, rock or stone is a naturally occurring solid aggregate of minerals and/or mineraloids.The Earth's outer solid layer, the lithosphere, is made of rock. In general rocks are of three types, namely, igneous, sedimentary, and metamorphic...

, or mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

. The word lustre traces its origins back to the Latin
Latin
Latin is an Italic language originally spoken in Latium and Ancient Rome. It, along with most European languages, is a descendant of the ancient Proto-Indo-European language. Although it is considered a dead language, a number of scholars and members of the Christian clergy speak it fluently, and...

 word lux, meaning "light", and generally implies radiance, gloss, or brilliance.

A range of terms are used to describe lustre. Many terms refer to materials having similar lustres, such as earthy, metallic, greasy, and silky. Similarly, the term vitreous (derived from the Latin for glass
Glass
Glass is an amorphous solid material. Glasses are typically brittle and optically transparent.The most familiar type of glass, used for centuries in windows and drinking vessels, is soda-lime glass, composed of about 75% silica plus Na2O, CaO, and several minor additives...

, vitrum) refers to a glassy lustre. A list of these terms is given below.

Lustre varies over a wide continuum, and so there are no rigid boundaries between the different terms. (For this reason, different sources can often describe the same mineral differently. This ambiguity is further complicated by the fact that lustre can vary widely within a particular mineral species.) The terms are frequently combined to describe intermediate types of lustre (for example, a "vitreous greasy" lustre).

Some minerals exhibit unusual optical phenomena, such as asterism
Asterism (gemmology)
Asteria, or star stone is a name applied to ornamental stones that exhibit a luminous star when cut en cabochon. The typical asteria is the star-sapphire, generally a bluish-grey corundum, milky or opalescent, with a star of six rays...

 (the display of a star-shaped luminous area) or chatoyancy
Chatoyancy
In gemology, chatoyancy , or chatoyance, is an optical reflectance effect seen in certain gemstones. Coined from the French "œil de chat," meaning "cat's eye," chatoyancy arises either from the fibrous structure of a material, as in tiger eye quartz, or from fibrous inclusions or cavities within...

 (the display of luminous bands, which appear to move as the specimen is rotated). A list of such phenomena is given below.

Adamantine lustre

Adamantine
Adamantine
Adamantine is a mineral, often referred to as adamantine spar. It is a silky brown form of corundum. It has a Mohs rating of 9.Adamantine is also used as an adjective to refer to non-metallic, brilliant light reflecting and transmitting properties, known as adamantine luster...

minerals possess a superlative lustre, which is most notably seen in diamond
Diamond
In mineralogy, diamond is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions...

. Such minerals are transparent or translucent, and have a high refractive index
Refractive index
In optics the refractive index or index of refraction of a substance or medium is a measure of the speed of light in that medium. It is expressed as a ratio of the speed of light in vacuum relative to that in the considered medium....

 (of 1.9 or more). Minerals with a true adamantine lustre are uncommon, with examples being cerussite
Cerussite
Cerussite is a mineral consisting of lead carbonate , and an important ore of lead. The name is from the Latin cerussa, white lead. Cerussa nativa was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name cruse to the mineral, whilst the present form, cerussite, is due to...

 and zircon
Zircon
Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is 1–x4x–y...

.

Minerals with a lesser (but still relatively high) degree of lustre are referred to as subadamantine, with some examples being garnet
Garnet
The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...

 and corundum
Corundum
Corundum is a crystalline form of aluminium oxide with traces of iron, titanium and chromium. It is a rock-forming mineral. It is one of the naturally clear transparent materials, but can have different colors when impurities are present. Transparent specimens are used as gems, called ruby if red...

.


Dull lustre

Dull (or earthy) minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, approximating a Lambertian reflector
Lambertian reflectance
If a surface exhibits Lambertian reflectance, light falling on it is scattered such that the apparent brightness of the surface to an observer is the same regardless of the observer's angle of view. More technically, the surface luminance is isotropic...

. An example is kaolinite
Kaolinite
Kaolinite is a clay mineral, part of the group of industrial minerals, with the chemical composition Al2Si2O54. It is a layered silicate mineral, with one tetrahedral sheet linked through oxygen atoms to one octahedral sheet of alumina octahedra...

. A distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre.


Greasy lustre

Greasy minerals resemble fat or grease. A greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal
Opal
Opal is an amorphous form of silica related to quartz, a mineraloid form, not a mineral. 3% to 21% of the total weight is water, but the content is usually between 6% to 10%. It is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most...

 and cordierite
Cordierite
Cordierite or iolite is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: 2 to 2...

. Many minerals with a greasy lustre are also greasy to the touch.


Metallic luster

Metallic (or splendent) minerals have the lustre of polished metal (and with ideal surfaces will act like a mirror
Mirror
A mirror is an object that reflects light or sound in a way that preserves much of its original quality prior to its contact with the mirror. Some mirrors also filter out some wavelengths, while preserving other wavelengths in the reflection...

). Examples include galena
Galena
Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...

, pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...

 and magnetite
Magnetite
Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

.


Pearly luster

Pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearl
Pearl
A pearl is a hard object produced within the soft tissue of a living shelled mollusk. Just like the shell of a mollusk, a pearl is made up of calcium carbonate in minute crystalline form, which has been deposited in concentric layers. The ideal pearl is perfectly round and smooth, but many other...

s. Such minerals possess perfect cleavage
Cleavage (crystal)
Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness are a result of the regular locations of atoms and ions in the crystal, which create smooth repeating surfaces that are visible both in the...

, with examples including muscovite
Muscovite
Muscovite is a phyllosilicate mineral of aluminium and potassium with formula KAl22, or 236. It has a highly-perfect basal cleavage yielding remarkably-thin laminæ which are often highly elastic...

 and stilbite
Stilbite
Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:*...

.


Resinous lustre

Resinous minerals have the appearance of resin
Resin
Resin in the most specific use of the term is a hydrocarbon secretion of many plants, particularly coniferous trees. Resins are valued for their chemical properties and associated uses, such as the production of varnishes, adhesives, and food glazing agents; as an important source of raw materials...

, chewing gum
Chewing gum
Chewing gum is a type of gum traditionally made of chicle, a natural latex product, or synthetic rubber known as polyisobutylene. For economical and quality reasons, many modern chewing gums use rubber instead of chicle...

 or (smooth surfaced) plastic. A principal example is amber
Amber
Amber is fossilized tree resin , which has been appreciated for its color and natural beauty since Neolithic times. Amber is used as an ingredient in perfumes, as a healing agent in folk medicine, and as jewelry. There are five classes of amber, defined on the basis of their chemical constituents...

, which is a form of fossilized resin.


Silky lustre

Silky minerals have a parallel arrangement of extremely fine fibres, giving them a lustre reminiscent of silk
Silk
Silk is a natural protein fiber, some forms of which can be woven into textiles. The best-known type of silk is obtained from the cocoons of the larvae of the mulberry silkworm Bombyx mori reared in captivity...

. Examples include asbestos
Asbestos
Asbestos is a set of six naturally occurring silicate minerals used commercially for their desirable physical properties. They all have in common their eponymous, asbestiform habit: long, thin fibrous crystals...

, ulexite
Ulexite
Ulexite , sometimes known as TV rock, is a mineral occurring in silky white rounded crystalline masses or in parallel fibers. The natural fibers of ulexite conduct light along their long axes, by internal reflection...

 and the satin spar variety of gypsum
Gypsum
Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...

. A fibrous lustre is similar, but has a coarser texture.


Submetallic lustre

Submetallic minerals have similar lustre to metal, but are duller and less reflective. A submetallic lustre often occurs in near-opaque minerals with very high refractive indices, such as sphalerite
Sphalerite
Sphalerite is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides...

, cinnabar
Cinnabar
Cinnabar or cinnabarite , is the common ore of mercury.-Word origin:The name comes from κινναβαρι , a Greek word most likely applied by Theophrastus to several distinct substances...

 and cuprite
Cuprite
Cuprite is an oxide mineral composed of copper oxide Cu2O, and is a minor ore of copper.Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, or in combinations. Penetration twins frequently occur...

.


Vitreous lustre

Vitreous minerals have the lustre of glass
Glass
Glass is an amorphous solid material. Glasses are typically brittle and optically transparent.The most familiar type of glass, used for centuries in windows and drinking vessels, is soda-lime glass, composed of about 75% silica plus Na2O, CaO, and several minor additives...

. (The term is derived from the Latin for glass, vitrum.) This type of lustre is one of the most commonly seen, and occurs in transparent or translucent minerals with relatively low refractive indices. Common examples include calcite
Calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate . The other polymorphs are the minerals aragonite and vaterite. Aragonite will change to calcite at 380-470°C, and vaterite is even less stable.-Properties:...

, quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

, topaz
Topaz
Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al2SiO42. Topaz crystallizes in the orthorhombic system and its crystals are mostly prismatic terminated by pyramidal and other faces.-Color and varieties:...

, beryl
Beryl
The mineral beryl is a beryllium aluminium cyclosilicate with the chemical formula Be3Al26. The hexagonal crystals of beryl may be very small or range to several meters in size. Terminated crystals are relatively rare...

, tourmaline
Tourmaline
Tourmaline is a crystal boron silicate mineral compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is classified as a semi-precious stone and the gem comes in a wide variety of colors...

 and fluorite
Fluorite
Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...

, among others.


Waxy lustre

Waxy minerals have a lustre resembling wax
Wax
thumb|right|[[Cetyl palmitate]], a typical wax ester.Wax refers to a class of chemical compounds that are plastic near ambient temperatures. Characteristically, they melt above 45 °C to give a low viscosity liquid. Waxes are insoluble in water but soluble in organic, nonpolar solvents...

. Examples include jade
Jade
Jade is an ornamental stone.The term jade is applied to two different metamorphic rocks that are made up of different silicate minerals:...

 and chalcedony
Chalcedony
Chalcedony is a cryptocrystalline form of silica, composed of very fine intergrowths of the minerals quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monoclinic...

.


Asterism

Asterism
Asterism (gemmology)
Asteria, or star stone is a name applied to ornamental stones that exhibit a luminous star when cut en cabochon. The typical asteria is the star-sapphire, generally a bluish-grey corundum, milky or opalescent, with a star of six rays...

is the display of a star-shaped luminous area. It is seen in some sapphire
Sapphire
Sapphire is a gemstone variety of the mineral corundum, an aluminium oxide , when it is a color other than red or dark pink; in which case the gem would instead be called a ruby, considered to be a different gemstone. Trace amounts of other elements such as iron, titanium, or chromium can give...

s and rubies
Ruby
A ruby is a pink to blood-red colored gemstone, a variety of the mineral corundum . The red color is caused mainly by the presence of the element chromium. Its name comes from ruber, Latin for red. Other varieties of gem-quality corundum are called sapphires...

, where it is caused by impurities of rutile
Rutile
Rutile is a mineral composed primarily of titanium dioxide, TiO2.Rutile is the most common natural form of TiO2. Two rarer polymorphs of TiO2 are known:...

. It can also occur in garnet
Garnet
The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...

, diopside
Diopside
Diopside is a monoclinic pyroxene mineral with composition MgCaSi2O6. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class...

 and spinel
Spinel
Spinel is the magnesium aluminium member of the larger spinel group of minerals. It has the formula MgAl2O4. Balas ruby is an old name for a rose-tinted variety.-Spinel group:...

.


Aventurescence

Aventurescence
Aventurescence
In gemology, aventurescence is an optical reflectance effect seen in certain gems. The effect amounts to a metallic glitter, arising from minute, preferentially oriented mineral platelets within the material. These platelets are so numerous that they also influence the material's body colour...

(or aventurization) is a reflectance effect like that of glitter
Glitter
Glitter describes an assortment of very small pieces of copolymer plastics, aluminum foil, titanium dioxide, iron oxides, bismuth oxychloride or other materials painted in metallic, neon and iridescent colors to reflect light in a sparkling spectrum...

. It arises from minute, preferentially oriented mineral platelets within the material. These platelets are so numerous that they also influence the material's body colour. In aventurine quartz
Aventurine
Aventurine is a form of quartz, characterised by its translucency and the presence of platy mineral inclusions that give a shimmering or glistening effect termed aventurescence....

 chrome-bearing fuchsite makes for a green stone, and various iron oxide
Iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides.Iron oxides and oxide-hydroxides are widespread in nature, play an important role in many geological and biological processes, and are widely utilized by humans, e.g.,...

s make for a red stone.


Chatoyancy

Chatoyant
Chatoyancy
In gemology, chatoyancy , or chatoyance, is an optical reflectance effect seen in certain gemstones. Coined from the French "œil de chat," meaning "cat's eye," chatoyancy arises either from the fibrous structure of a material, as in tiger eye quartz, or from fibrous inclusions or cavities within...

minerals display luminous bands, which appear to move as the specimen is rotated. Such minerals are composed of parallel fibers (or contain fibrous voids or inclusions), which reflect light into a direction perpendicular to their orientation, thus forming narrow bands of light. The most famous examples are tiger's eye
Tiger's eye
Tiger's eye is a chatoyant gemstone that is usually a metamorphic rock that is a golden to red-brown color, with a silky luster. A member of the quartz group, it is a classic example of pseudomorphous replacement by silica of fibrous crocidolite...

 and cymophane, but the effect may also occur in other minerals such as aquamarine, moonstone
Moonstone (gemstone)
Moonstone is a sodium potassium aluminium silicate, with the chemical formula AlSi3O8.-Etymology:Its name is derived from a visual effect, or sheen, caused by light reflecting internally in the moonstone from layer inclusion of different feldspars....

 and tourmaline
Tourmaline
Tourmaline is a crystal boron silicate mineral compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is classified as a semi-precious stone and the gem comes in a wide variety of colors...

.


Colour change

Color change is most commonly found in Alexandrite, a variety of chrysoberyl
Chrysoberyl
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely...

 gemstones. Other gems also occur in color-change varieties, including (but not limited to) sapphire
Sapphire
Sapphire is a gemstone variety of the mineral corundum, an aluminium oxide , when it is a color other than red or dark pink; in which case the gem would instead be called a ruby, considered to be a different gemstone. Trace amounts of other elements such as iron, titanium, or chromium can give...

, garnet
Garnet
The garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...

, spinel
Spinel
Spinel is the magnesium aluminium member of the larger spinel group of minerals. It has the formula MgAl2O4. Balas ruby is an old name for a rose-tinted variety.-Spinel group:...

. Alexandrite displays a color change dependent upon light, along with strong pleochroism
Pleochroism
Pleochroism is an optical phenomenon in which a substance appears to be different colors when observed at different angles with polarized light.- Background :Anisotropic crystals will have optical properties that vary with the direction of light...

. The gem results from small scale replacement of aluminium by chromium oxide, which is responsible for alexandrite's characteristic green to red color change. Alexandrite from the Ural Mountains in Russia is green by daylight and red by incandescent light. Other varieties of alexandrite may be yellowish or pink in daylight and a columbine or raspberry red by incandescent light. The optimum or "ideal" color change would be fine emerald green to fine purplish red, but this is exceedingly rare.


Schiller

Schiller, from German for "twinkle", is a term used to describe the metallic iridescence originating from below the surface of a stone, that occurs when light is reflected between layers of minerals. It is seen in moonstone
Moonstone (gemstone)
Moonstone is a sodium potassium aluminium silicate, with the chemical formula AlSi3O8.-Etymology:Its name is derived from a visual effect, or sheen, caused by light reflecting internally in the moonstone from layer inclusion of different feldspars....

 and labradorite
Labradorite
Labradorite , a feldspar mineral, is an intermediate to calcic member of the plagioclase series. It is usually defined as having "%An" between 50 and 70. The specific gravity ranges from 2.68 to 2.72. The streak is white, like most silicates. The refractive index ranges from 1.559 to 1.573....

 and is very similar to adularescence
Adularescence
Adularescence is an optical phenomenon, similar to labradorescence and aventurescence, produced most notably by moonstones. Adularescence is also commonly referred to as schiller or shiller. The effect is best described as a milky, bluish luster or glow originating from below the surface of the...

 and aventurescence
Aventurescence
In gemology, aventurescence is an optical reflectance effect seen in certain gems. The effect amounts to a metallic glitter, arising from minute, preferentially oriented mineral platelets within the material. These platelets are so numerous that they also influence the material's body colour...

.

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