Galena
Encyclopedia
Galena is the natural mineral form of lead(II) sulfide
. It is the most important lead
ore
mineral.
Galena is one of the most abundant and widely distributed sulfide mineral
s. It crystallizes in the cubic crystal system
often showing octahedral forms. It is often associated with the minerals sphalerite
, calcite
and fluorite
.
as included silver sulfide mineral phases or as limited solid solution within the galena structure. These argentiferous galenas have long been the most important ore of silver in mining
. In addition zinc, cadmium, antimony, arsenic and bismuth also occur in variable amounts in lead ores. Selenium substitutes for sulfur in the structure constituting a solid solution series. The lead telluride
mineral altaite
has the same crystal structure as galena. Within the weathering
or oxidation zone galena alters to anglesite
(lead sulfate) or cerussite
(lead carbonate). Galena exposed to acid mine drainage can be oxidized to anglesite by naturally occurring bacteria
and archaea
, in a process similar to bioleaching
.
Galena deposits are found worldwide in various environments. Noted deposits include those at Freiberg, Saxony
; Cornwall
, The Mendip
s, Somerset
, Derbyshire
, and Cumberland
, England
; the Madan, Smolyan Province, Rhodope Mountains
, Bulgaria; the Sullivan Mine
of British Columbia
; and Broken Hill, Australia
. Galena also occurs at Mount Hermon
in Northern Israel
. In the United States
, it occurs most notably in the Mississippi Valley type deposits
of the Lead Belt
in southeastern Missouri
, and in the Driftless Area of Illinois
, Iowa
and Wisconsin
. The economic importance of galena to the early history of the Driftless Area was so great that one of the towns in the region was named Galena, Illinois
.
Galena also was a major mineral of the zinc
-lead mines of the tri-state district
around Joplin
in southwestern Missouri and the adjoining areas of Kansas
and Oklahoma
. Galena is also an important ore mineral in the silver mining regions of Colorado
, Idaho
, Utah
and Montana
. Of the latter, the Coeur d'Alene
district of northern Idaho was most prominent.
Galena is the official state mineral of the U.S. states of Missouri
and Wisconsin
.
The largest documented crystal of galena is composite cubo-octahedra from Great Laxcy Mine, Isle of Man, U.K. measuring 25 cm × 25 cm × 25 cm.
, which, in Ancient Egypt
, was applied around the eyes to reduce the glare of the desert sun and to repel flies, which were a potential source of disease.
Galena is the primary ore of lead
which is mainly used in making lead-acid batteries; however, significant amounts are also used to make lead sheets and shot. Galena is often mined for its silver content (e.g. the Galena Mine in northern Idaho).
Galena is a semiconductor
with a small bandgap of about 0.4 eV which found use in early wireless
communication systems. For example, it was used as the crystal in crystal radio sets, in which it was used as a point-contact diode
to detect the radio signals. The galena crystal was used with a safety pin or similar sharp wire, which was known as a "cat's whisker". Making such wireless sets was a popular home hobby in Britain and other European countries during the 1930s. Derbyshire was one of the main areas where galena was mined.
Scientists that were linked to this application are Karl Ferdinand Braun
and Sir Jagdish Bose. In modern wireless communication systems, galena detectors have been replaced by more reliable semiconductor devices, though silicon
point-contact microwave detectors still exist in the market.
Lead(II) sulfide
Lead sulfide is an inorganic compound with the formula Pb. It finds limited use in electronic devices. PbS, also known as galena, is the principal ore and most important compound of lead....
. It is the most important lead
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
mineral.
Galena is one of the most abundant and widely distributed sulfide mineral
Sulfide mineral
The sulfide minerals are a class of minerals containing sulfide as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts...
s. It crystallizes in the cubic crystal system
Crystal system
In crystallography, the terms crystal system, crystal family, and lattice system each refer to one of several classes of space groups, lattices, point groups, or crystals...
often showing octahedral forms. It is often associated with the minerals sphalerite
Sphalerite
Sphalerite is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides...
, calcite
Calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate . The other polymorphs are the minerals aragonite and vaterite. Aragonite will change to calcite at 380-470°C, and vaterite is even less stable.-Properties:...
and fluorite
Fluorite
Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...
.
Lead ore deposit
Galena deposits often contain significant amounts of silverSilver
Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...
as included silver sulfide mineral phases or as limited solid solution within the galena structure. These argentiferous galenas have long been the most important ore of silver in mining
Mining
Mining is the extraction of valuable minerals or other geological materials from the earth, from an ore body, vein or seam. The term also includes the removal of soil. Materials recovered by mining include base metals, precious metals, iron, uranium, coal, diamonds, limestone, oil shale, rock...
. In addition zinc, cadmium, antimony, arsenic and bismuth also occur in variable amounts in lead ores. Selenium substitutes for sulfur in the structure constituting a solid solution series. The lead telluride
Telluride (chemistry)
The telluride ion is Te2−. It is the final stable member of the series of dianions O2−, S2−, and Se2− ....
mineral altaite
Altaite
Altaite, or lead telluride, is a yellowish white mineral with an isometric crystal structure. Altaite is in the galena group of minerals as it shares many of properties of galena. Altaite has an unusually high density for a light-colored mineral...
has the same crystal structure as galena. Within the weathering
Weathering
Weathering is the breaking down of rocks, soils and minerals as well as artificial materials through contact with the Earth's atmosphere, biota and waters...
or oxidation zone galena alters to anglesite
Anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and...
(lead sulfate) or cerussite
Cerussite
Cerussite is a mineral consisting of lead carbonate , and an important ore of lead. The name is from the Latin cerussa, white lead. Cerussa nativa was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name cruse to the mineral, whilst the present form, cerussite, is due to...
(lead carbonate). Galena exposed to acid mine drainage can be oxidized to anglesite by naturally occurring bacteria
Bacteria
Bacteria are a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria have a wide range of shapes, ranging from spheres to rods and spirals...
and archaea
Archaea
The Archaea are a group of single-celled microorganisms. A single individual or species from this domain is called an archaeon...
, in a process similar to bioleaching
Bioleaching
Bioleaching is the extraction of specific metals from their ores through the use of living organisms. This is much cleaner than the traditional heap leaching using cyanide...
.
Galena deposits are found worldwide in various environments. Noted deposits include those at Freiberg, Saxony
Freiberg, Saxony
Freiberg is a city in the Free State of Saxony, Germany, administrative center of the Mittelsachsen district.-History:The city was founded in 1186, and has been a center of the mining industry in the Ore Mountains for centuries...
; Cornwall
Cornwall
Cornwall is a unitary authority and ceremonial county of England, within the United Kingdom. It is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar. Cornwall has a population of , and covers an area of...
, The Mendip
Mendip
Mendip is a local government district of Somerset in England. The Mendip district covers a largely rural area of ranging from the Mendip Hills through on to the Somerset Levels. It has a population of approximately 110,000...
s, Somerset
Somerset
The ceremonial and non-metropolitan county of Somerset in South West England borders Bristol and Gloucestershire to the north, Wiltshire to the east, Dorset to the south-east, and Devon to the south-west. It is partly bounded to the north and west by the Bristol Channel and the estuary of the...
, Derbyshire
Derbyshire
Derbyshire is a county in the East Midlands of England. A substantial portion of the Peak District National Park lies within Derbyshire. The northern part of Derbyshire overlaps with the Pennines, a famous chain of hills and mountains. The county contains within its boundary of approx...
, and Cumberland
Cumberland
Cumberland is a historic county of North West England, on the border with Scotland, from the 12th century until 1974. It formed an administrative county from 1889 to 1974 and now forms part of Cumbria....
, England
England
England is a country that is part of the United Kingdom. It shares land borders with Scotland to the north and Wales to the west; the Irish Sea is to the north west, the Celtic Sea to the south west, with the North Sea to the east and the English Channel to the south separating it from continental...
; the Madan, Smolyan Province, Rhodope Mountains
Rhodope Mountains
The Rhodopes are a mountain range in Southeastern Europe, with over 83% of its area in southern Bulgaria and the remainder in Greece. Its highest peak, Golyam Perelik , is the seventh highest Bulgarian mountain...
, Bulgaria; the Sullivan Mine
Sullivan mine
Sullivan Mine was an underground conventional–mechanized mine located in Kimberley, British Columbia, Canada; it has a complex, diatreme-hosted orebody, made up primarily of zinc sulfide, lead sulfide, and iron sulfides....
of British Columbia
British Columbia
British Columbia is the westernmost of Canada's provinces and is known for its natural beauty, as reflected in its Latin motto, Splendor sine occasu . Its name was chosen by Queen Victoria in 1858...
; and Broken Hill, Australia
Australia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...
. Galena also occurs at Mount Hermon
Mount Hermon
Mount Hermon is a mountain cluster in the Anti-Lebanon mountain range. Its summit straddles the border between Syria and Lebanon and, at 2,814 m above sea level, is the highest point in Syria. On the top there is “Hermon Hotel”, in the buffer zone between Syria and Israeli-occupied...
in Northern Israel
Israel
The State of Israel is a parliamentary republic located in the Middle East, along the eastern shore of the Mediterranean Sea...
. In the United States
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...
, it occurs most notably in the Mississippi Valley type deposits
Carbonate hosted lead zinc ore deposits
Carbonate-hosted lead-zinc ore deposits are important and highly valuable concentrations of lead and zinc sulfide ores hosted within carbonate formations and which share a common genetic origin....
of the Lead Belt
Lead Belt
The Southeast Missouri Lead District, commonly called the Lead Belt, is a lead mining district in the southeastern part of Missouri. Counties in the Lead Belt include Saint Francois; Crawford; Dent; Iron; Madison: Reynolds; and Washington...
in southeastern Missouri
Missouri
Missouri is a US state located in the Midwestern United States, bordered by Iowa, Illinois, Kentucky, Tennessee, Arkansas, Oklahoma, Kansas and Nebraska. With a 2010 population of 5,988,927, Missouri is the 18th most populous state in the nation and the fifth most populous in the Midwest. It...
, and in the Driftless Area of Illinois
Illinois
Illinois is the fifth-most populous state of the United States of America, and is often noted for being a microcosm of the entire country. With Chicago in the northeast, small industrial cities and great agricultural productivity in central and northern Illinois, and natural resources like coal,...
, Iowa
Iowa
Iowa is a state located in the Midwestern United States, an area often referred to as the "American Heartland". It derives its name from the Ioway people, one of the many American Indian tribes that occupied the state at the time of European exploration. Iowa was a part of the French colony of New...
and Wisconsin
Wisconsin
Wisconsin is a U.S. state located in the north-central United States and is part of the Midwest. It is bordered by Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake Michigan to the east, Michigan to the northeast, and Lake Superior to the north. Wisconsin's capital is...
. The economic importance of galena to the early history of the Driftless Area was so great that one of the towns in the region was named Galena, Illinois
Galena, Illinois
Galena is the county seat of, and largest city in, Jo Daviess County, Illinois in the United States, with a population of 3,429 in 2010. The city is a popular tourist destination known for its history, historical architecture, and ski and golf resorts. Galena was the residence of Ulysses S...
.
Galena also was a major mineral of the zinc
Zinc
Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...
-lead mines of the tri-state district
Tri-State district
The Tri-State district was an historic lead-zinc mining district located in southwest Missouri, southeast Kansas and northeast Oklahoma. The district produced lead and zinc for over 100 years. Production began in the 1850s and 60s in the Joplin - Granby area of Jasper and Newton counties of...
around Joplin
Joplin, Missouri
Joplin is a city in southern Jasper County and northern Newton County in the southwestern corner of the US state of Missouri. Joplin is the largest city in Jasper County, though it is not the county seat. As of the 2010 census, the city population was 50,150...
in southwestern Missouri and the adjoining areas of Kansas
Kansas
Kansas is a US state located in the Midwestern United States. It is named after the Kansas River which flows through it, which in turn was named after the Kansa Native American tribe, which inhabited the area. The tribe's name is often said to mean "people of the wind" or "people of the south...
and Oklahoma
Oklahoma
Oklahoma is a state located in the South Central region of the United States of America. With an estimated 3,751,351 residents as of the 2010 census and a land area of 68,667 square miles , Oklahoma is the 28th most populous and 20th-largest state...
. Galena is also an important ore mineral in the silver mining regions of Colorado
Colorado
Colorado is a U.S. state that encompasses much of the Rocky Mountains as well as the northeastern portion of the Colorado Plateau and the western edge of the Great Plains...
, Idaho
Idaho
Idaho is a state in the Rocky Mountain area of the United States. The state's largest city and capital is Boise. Residents are called "Idahoans". Idaho was admitted to the Union on July 3, 1890, as the 43rd state....
, Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
and Montana
Montana
Montana is a state in the Western United States. The western third of Montana contains numerous mountain ranges. Smaller, "island ranges" are found in the central third of the state, for a total of 77 named ranges of the Rocky Mountains. This geographical fact is reflected in the state's name,...
. Of the latter, the Coeur d'Alene
Coeur d'Alene, Idaho
Coeur d'Alene is the largest city and county seat of Kootenai County, Idaho, United States. It is the principal city of the Coeur d'Alene Metropolitan Statistical Area. Coeur d'Alene has the second largest metropolitan area in the state of Idaho. As of the 2010 census the population of Coeur...
district of northern Idaho was most prominent.
Galena is the official state mineral of the U.S. states of Missouri
Missouri
Missouri is a US state located in the Midwestern United States, bordered by Iowa, Illinois, Kentucky, Tennessee, Arkansas, Oklahoma, Kansas and Nebraska. With a 2010 population of 5,988,927, Missouri is the 18th most populous state in the nation and the fifth most populous in the Midwest. It...
and Wisconsin
Wisconsin
Wisconsin is a U.S. state located in the north-central United States and is part of the Midwest. It is bordered by Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake Michigan to the east, Michigan to the northeast, and Lake Superior to the north. Wisconsin's capital is...
.
The largest documented crystal of galena is composite cubo-octahedra from Great Laxcy Mine, Isle of Man, U.K. measuring 25 cm × 25 cm × 25 cm.
Galena uses
One of the oldest uses of galena was as kohlKohl (cosmetics)
Kohl is an ancient eye cosmetic. It was made by grinding galena and other ingredients. It is widely used in South Asia, the Middle East, North Africa, the Horn of Africa, and parts of West Africa to darken the eyelids and as mascara for the eyelashes...
, which, in Ancient Egypt
Ancient Egypt
Ancient Egypt was an ancient civilization of Northeastern Africa, concentrated along the lower reaches of the Nile River in what is now the modern country of Egypt. Egyptian civilization coalesced around 3150 BC with the political unification of Upper and Lower Egypt under the first pharaoh...
, was applied around the eyes to reduce the glare of the desert sun and to repel flies, which were a potential source of disease.
Galena is the primary ore of lead
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
which is mainly used in making lead-acid batteries; however, significant amounts are also used to make lead sheets and shot. Galena is often mined for its silver content (e.g. the Galena Mine in northern Idaho).
Galena is a semiconductor
Semiconductor
A semiconductor is a material with electrical conductivity due to electron flow intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 103 to 10−8 siemens per centimeter...
with a small bandgap of about 0.4 eV which found use in early wireless
Wireless
Wireless telecommunications is the transfer of information between two or more points that are not physically connected. Distances can be short, such as a few meters for television remote control, or as far as thousands or even millions of kilometers for deep-space radio communications...
communication systems. For example, it was used as the crystal in crystal radio sets, in which it was used as a point-contact diode
Diode
In electronics, a diode is a type of two-terminal electronic component with a nonlinear current–voltage characteristic. A semiconductor diode, the most common type today, is a crystalline piece of semiconductor material connected to two electrical terminals...
to detect the radio signals. The galena crystal was used with a safety pin or similar sharp wire, which was known as a "cat's whisker". Making such wireless sets was a popular home hobby in Britain and other European countries during the 1930s. Derbyshire was one of the main areas where galena was mined.
Scientists that were linked to this application are Karl Ferdinand Braun
Karl Ferdinand Braun
Karl Ferdinand Braun was a German inventor, physicist and Nobel laureate in physics. Braun contributed significantly to the development of the radio and television technology: he shared with Guglielmo Marconi the 1909 Nobel Prize in Physics.-Biography:Braun was born in Fulda, Germany, and...
and Sir Jagdish Bose. In modern wireless communication systems, galena detectors have been replaced by more reliable semiconductor devices, though silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...
point-contact microwave detectors still exist in the market.