Metallate
Encyclopedia
Metallate is the name given to any complex anion containing a metal
ligated to several atom
s or small groups. The spelling metalate is almost as common.
Typically, the metal will be one of the transition elements and the ligand
will be oxygen
or another chalcogenide
or a cyanide
group (though others are known). The chalcogenide metallates are known as oxometallates, thiometallates, selenometallates and tellurometallates; the cyanide metallates are known as cyanometallates.
Oxometallates include permanganate
, chromate
and vanadate
.
Thiometallates include tetrathiomolybdate and similar ions.
Cyanometallates include ferricyanide
and ferrocyanide
.
Metallate is also used as a verb by bioinorganic chemistry to describe the act of adding metal atoms or ions to a site (synthetic ligand or protein.)
Metal
A metal , is an element, compound, or alloy that is a good conductor of both electricity and heat. Metals are usually malleable and shiny, that is they reflect most of incident light...
ligated to several atom
Atom
The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons...
s or small groups. The spelling metalate is almost as common.
Typically, the metal will be one of the transition elements and the ligand
Ligand
In coordination chemistry, a ligand is an ion or molecule that binds to a central metal atom to form a coordination complex. The bonding between metal and ligand generally involves formal donation of one or more of the ligand's electron pairs. The nature of metal-ligand bonding can range from...
will be oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
or another chalcogenide
Chalcogenide
A chalcogenide is a chemical compound consisting of at least one chalcogen ion and at least one more electropositive element. Although all group 16 elements of the periodic table are defined as chalcogens, the term is more commonly reserved for sulfides, selenides, and tellurides, rather than...
or a cyanide
Cyanide
A cyanide is a chemical compound that contains the cyano group, -C≡N, which consists of a carbon atom triple-bonded to a nitrogen atom. Cyanides most commonly refer to salts of the anion CN−. Most cyanides are highly toxic....
group (though others are known). The chalcogenide metallates are known as oxometallates, thiometallates, selenometallates and tellurometallates; the cyanide metallates are known as cyanometallates.
Oxometallates include permanganate
Permanganate
A permanganate is the general name for a chemical compound containing the manganate ion, . Because manganese is in the +7 oxidation state, the permanganate ion is a strong oxidizing agent. The ion has tetrahedral geometry...
, chromate
Chromate
Chromate salts contain the chromate anion, CrO42−. Dichromate salts contain the dichromate anion, Cr2O72−. They are oxyanions of chromium in the oxidation state +6. They are moderately strong oxidizing agents.- Chemical properties :...
and vanadate
Vanadate
In chemistry, a vanadate is a compound containing an oxoanion of vanadium generally in its highest oxidation state of +5. The simplest vanadate ion is the tetrahedral, orthovanadate, VO43− anion, which is present in e.g. sodium orthovanadate and in solutions of V2O5 in strong base...
.
Thiometallates include tetrathiomolybdate and similar ions.
Cyanometallates include ferricyanide
Ferricyanide
Ferricyanide is the anion [Fe6]3−. It is also called hexacyanoferrate and in rare, but systematic nomenclature, hexacyanidoferrate...
and ferrocyanide
Ferrocyanide
Ferrocyanide is the name of the anion Fe64−. In aqueous solutions, this coordination complex is relatively unreactive. It is usually available as the salt potassium ferrocyanide, which has the formula K4Fe6....
.
Metallate is also used as a verb by bioinorganic chemistry to describe the act of adding metal atoms or ions to a site (synthetic ligand or protein.)