Metamorphism
Encyclopedia
Metamorphism is the solid-state recrystallization
of pre-existing rocks
due to changes in physical and chemical conditions, primarily heat, pressure, and the introduction of chemically active fluids. Mineralogical
, chemical and crystallographic
changes can occur during this process. Changes at or just beneath Earth's surface due to weathering
and/or diagenesis
are not classified as metamorphism.
Three types of metamorphism exist: contact, dynamic and regional. Metamorphism produced with increasing pressure and temperature conditions is known as prograde metamorphism. Conversely, decreasing temperatures and pressure characterize retrograde metamorphism.
changes, due to compaction, which result in sedimentary rock
s. There is no agreement on a pressure lower limit. Some workers argue that changes in atmospheric pressures are not metamorphic, but some types of metamorphism can occur at extremely low pressures (see below).
The upper boundary of metamorphic conditions is related to the onset of melting processes in the rock. The maximum temperature for metamorphism is typically 700 - 900°C, depending on the pressure and on the composition of the rock. Migmatite
s are rocks formed at this upper limit, which contain pods and veins of material that has started to melt but has not fully segregated from the refractory residue. Since the 1980s it has been recognized that, rarely, rocks are dry enough and of a refractory enough composition to record without melting "ultra-high" metamorphic temperatures of 900 - 1100°C.
typically associated with mountain ranges, particularly subduction zones or the roots of previously eroded
mountains. Conditions producing widespread regionally metamorphosed rocks occur during an orogenic event
. The collision of two continental plates or island arc
s with continental plates produce the extreme compressional forces required for the metamorphic changes typical of regional metamorphism. These orogenic mountains are later eroded, exposing the intensely deformed rocks typical of their cores. The conditions within the subducting slab as it plunges toward the mantle
in a subduction zone also produce regional metamorphic effects. The techniques of structural geology
are used to unravel the collisional history and determine the forces involved. Regional metamorphism can be described and classified into metamorphic facies
or metamorphic zone
s of temperature/pressure conditions throughout the orogenic terrane
.
s as a result of the temperature increase caused by the intrusion of magma
into cooler country rock
. The area surrounding the intrusion where the contact metamorphism effects are present is called the metamorphic aureole. Contact metamorphic rocks are usually known as hornfels
. Rocks formed by contact metamorphism may not present signs of strong deformation and are often fine-grained.
Contact metamorphism is greater adjacent to the intrusion and dissipates with distance from the contact. The size of the aureole depends on the heat of the intrusion, its size, and the temperature difference with the wall rocks. Dikes
generally have small aureoles with minimal metamorphism whereas large ultramafic intrusions can have significantly thick and well-developed contact metamorphism.
The metamorphic grade of an aureole is measured by the peak metamorphic mineral which forms in the aureole. This is usually related to the metamorphic temperatures of pelitic
or alumonisilicate rocks and the minerals they form.The metamorphic grades of aureoles are andalusite hornfels, sillimanite hornfels, pyroxene hornfels.
Magmatic fluids coming from the intrusive rock may also take part in the metamorphic reaction
s. Extensive addition of magmatic fluids can significantly modify the chemistry of the affected rocks. In this case the metamorphism grades into metasomatism
. If the intruded rock is rich in carbonate
the result is a skarn
. Fluorine
-rich magmatic waters which leave a cooling granite may often form greisen
s within and adjacent to the contact of the granite. Metasomatic altered aureoles can localize the deposition of metallic ore
minerals and thus are of economic interest.
reactions. The hydrothermal fluid may be magmatic (originate in an intruding magma), circulating groundwater
, or ocean water. Convective circulation of hydrothermal fluids in the ocean floor basalt
s produces extensive hydrothermal metamorphism adjacent to spreading centers and other submarine volcanic areas. The fluids eventually escape through vents in the ocean floor known as black smokers. The patterns of this hydrothermal alteration is used as a guide in the search for deposits of valuable metal ores.
for instance) collides with the Earth's surface or during an extremely violent volcanic eruption
. Impact metamorphism is, therefore, characterized by ultrahigh pressure conditions and low temperature. The resulting minerals (such as SiO2 polymorphs
coesite
and stishovite
) and textures are characteristic of these conditions.
The textures of dynamic metamorphic zones are dependent on the depth at which they were formed, as the temperature and confining pressure determine the deformation mechanism
s which predominate. Within depths less than 5 km, dynamic metamorphism is not often produced because the confining pressure is too low to produce frictional heat. Instead, a zone of breccia
or cataclasite
is formed, with the rock milled and broken into random fragments. This generally forms a mélange
. At depth, the angular breccias transit into a ductile shear texture and into mylonite zones.
Within the depth range of 5–10 km pseudotachylite
is formed, as the confining pressure is enough to prevent brecciation and milling and thus energy is focused into discrete fault planes. Frictional heating in this case may melt the rock to form pseudotachylite glass.
Within the depth range of 10–20 km, deformation is governed by ductile deformation conditions and hence frictional heating is dispersed throughout shear zones, resulting in a weaker thermal imprint and distributed deformation. Here, deformation forms mylonite
, with dynamothermal metamorphism observed rarely as the growth of porphyroblast
s in mylonite zones.
Overthrust
ing may juxtapose hot lower crustal rocks against cooler mid and upper crust blocks, resulting in conductive heat transfer and localised contact metamorphism of the cooler blocks adjacent to the hotter blocks, and often retrograde metamorphism in the hotter blocks. The metamorphic assemblages in this case are diagnostic of the depth and temperature and the throw of the fault and can also be dated
to give an age of the thrusting.
, and the context (pressure, temperature, hydrological features, etc.) of its formation.
are recognizable terranes or zones with an assemblage of key minerals that were in equilibrium under specific range of temperature and pressure during a metamorphic event. The facies are named after the metamorphic rock formed under those facies conditions from basalt
. Facies relationships were first described by Pentti Eskola in 1921.
Facies:
See diagram for more detail.
in zones of progressive metamorphism in Scotland), metamorphic grades are also classified by mineral assemblage based on the appearance of key minerals in rocks of pelitic (shaly, aluminous) origin:
Low grade ------------------- Intermediate --------------------- High grade
scale.
) with increasing temperature and (usually) pressure conditions. These are solid state dehydration reactions, and involve the loss of volatiles such as water or carbon dioxide. Prograde metamorphism results in rock characteristic of the maximum pressure and temperature experienced. Metamorphic rocks usually do not undergo further change when they are brought back to the surface.
Retrograde metamorphism involves the reconstitution of a rock via revolatisation under decreasing temperatures (and usually pressures), allowing the mineral assemblages formed in prograde metamorphism to revert to those more stable at less extreme conditions. This is a relatively uncommon process, because volatiles must be present.
Recrystallization (geology)
In geology, solid-state recrystallization is a metamorphic process that occurs under situations of intense temperature and pressure where grains, atoms or molecules of a rock or mineral are packed closer together, creating a new crystal structure. The basic composition remains the same...
of pre-existing rocks
Rock (geology)
In geology, rock or stone is a naturally occurring solid aggregate of minerals and/or mineraloids.The Earth's outer solid layer, the lithosphere, is made of rock. In general rocks are of three types, namely, igneous, sedimentary, and metamorphic...
due to changes in physical and chemical conditions, primarily heat, pressure, and the introduction of chemically active fluids. Mineralogical
Mineralogy
Mineralogy is the study of chemistry, crystal structure, and physical properties of minerals. Specific studies within mineralogy include the processes of mineral origin and formation, classification of minerals, their geographical distribution, as well as their utilization.-History:Early writing...
, chemical and crystallographic
Crystallography
Crystallography is the experimental science of the arrangement of atoms in solids. The word "crystallography" derives from the Greek words crystallon = cold drop / frozen drop, with its meaning extending to all solids with some degree of transparency, and grapho = write.Before the development of...
changes can occur during this process. Changes at or just beneath Earth's surface due to weathering
Weathering
Weathering is the breaking down of rocks, soils and minerals as well as artificial materials through contact with the Earth's atmosphere, biota and waters...
and/or diagenesis
Diagenesis
In geology and oceanography, diagenesis is any chemical, physical, or biological change undergone by a sediment after its initial deposition and during and after its lithification, exclusive of surface alteration and metamorphism. These changes happen at relatively low temperatures and pressures...
are not classified as metamorphism.
Three types of metamorphism exist: contact, dynamic and regional. Metamorphism produced with increasing pressure and temperature conditions is known as prograde metamorphism. Conversely, decreasing temperatures and pressure characterize retrograde metamorphism.
Limits of metamorphism
The temperature lower limit of metamorphism is considered to be 100 - 200°C, to exclude diageneticDiagenesis
In geology and oceanography, diagenesis is any chemical, physical, or biological change undergone by a sediment after its initial deposition and during and after its lithification, exclusive of surface alteration and metamorphism. These changes happen at relatively low temperatures and pressures...
changes, due to compaction, which result in sedimentary rock
Sedimentary rock
Sedimentary rock are types of rock that are formed by the deposition of material at the Earth's surface and within bodies of water. Sedimentation is the collective name for processes that cause mineral and/or organic particles to settle and accumulate or minerals to precipitate from a solution....
s. There is no agreement on a pressure lower limit. Some workers argue that changes in atmospheric pressures are not metamorphic, but some types of metamorphism can occur at extremely low pressures (see below).
The upper boundary of metamorphic conditions is related to the onset of melting processes in the rock. The maximum temperature for metamorphism is typically 700 - 900°C, depending on the pressure and on the composition of the rock. Migmatite
Migmatite
Migmatite is a rock at the frontier between igneous and metamorphic rocks. They can also be known as diatexite.Migmatites form under extreme temperature conditions during prograde metamorphism, where partial melting occurs in pre-existing rocks. Migmatites are not crystallized from a totally...
s are rocks formed at this upper limit, which contain pods and veins of material that has started to melt but has not fully segregated from the refractory residue. Since the 1980s it has been recognized that, rarely, rocks are dry enough and of a refractory enough composition to record without melting "ultra-high" metamorphic temperatures of 900 - 1100°C.
Regional metamorphism
Regional or Barrovian metamorphism covers large areas of continental crustContinental crust
The continental crust is the layer of igneous, sedimentary, and metamorphic rocks which form the continents and the areas of shallow seabed close to their shores, known as continental shelves. This layer is sometimes called sial due to more felsic, or granitic, bulk composition, which lies in...
typically associated with mountain ranges, particularly subduction zones or the roots of previously eroded
Erosion
Erosion is when materials are removed from the surface and changed into something else. It only works by hydraulic actions and transport of solids in the natural environment, and leads to the deposition of these materials elsewhere...
mountains. Conditions producing widespread regionally metamorphosed rocks occur during an orogenic event
Orogeny
Orogeny refers to forces and events leading to a severe structural deformation of the Earth's crust due to the engagement of tectonic plates. Response to such engagement results in the formation of long tracts of highly deformed rock called orogens or orogenic belts...
. The collision of two continental plates or island arc
Island arc
An island arc is a type of archipelago composed of a chain of volcanoes which alignment is arc-shaped, and which are situated parallel and close to a boundary between two converging tectonic plates....
s with continental plates produce the extreme compressional forces required for the metamorphic changes typical of regional metamorphism. These orogenic mountains are later eroded, exposing the intensely deformed rocks typical of their cores. The conditions within the subducting slab as it plunges toward the mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....
in a subduction zone also produce regional metamorphic effects. The techniques of structural geology
Structural geology
Structural geology is the study of the three-dimensional distribution of rock units with respect to their deformational histories. The primary goal of structural geology is to use measurements of present-day rock geometries to uncover information about the history of deformation in the rocks, and...
are used to unravel the collisional history and determine the forces involved. Regional metamorphism can be described and classified into metamorphic facies
Metamorphic facies
The metamorphic facies are groups of mineral compositions in metamorphic rocks, that are typical for a certain field in pressure-temperature space...
or metamorphic zone
Metamorphic zone
In geology, a metamorphic zone is an area where, as a result of metamorphism, the same combination of minerals occurs in the bed rocks. These zones occur because most metamorphic minerals are only stable in certain intervals of temperature and pressure....
s of temperature/pressure conditions throughout the orogenic terrane
Terrane
A terrane in geology is short-hand term for a tectonostratigraphic terrane, which is a fragment of crustal material formed on, or broken off from, one tectonic plate and accreted or "sutured" to crust lying on another plate...
.
Contact (thermal) metamorphism
Contact metamorphism occurs typically around intrusive igneous rockIgneous rock
Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava...
s as a result of the temperature increase caused by the intrusion of magma
Magma
Magma is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and is expected to exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and dissolved gas and sometimes also gas bubbles. Magma often collects in...
into cooler country rock
Country rock (geology)
Country rock is a geological term meaning the rock native to an area. It is similar and in many cases interchangeable with the terms basement and wall rocks....
. The area surrounding the intrusion where the contact metamorphism effects are present is called the metamorphic aureole. Contact metamorphic rocks are usually known as hornfels
Hornfels
Hornfels is the group designation for a series of contact metamorphic rocks that have been baked and indurated by the heat of intrusive igneous masses and have been rendered...
. Rocks formed by contact metamorphism may not present signs of strong deformation and are often fine-grained.
Contact metamorphism is greater adjacent to the intrusion and dissipates with distance from the contact. The size of the aureole depends on the heat of the intrusion, its size, and the temperature difference with the wall rocks. Dikes
Dike (geology)
A dike or dyke in geology is a type of sheet intrusion referring to any geologic body that cuts discordantly across* planar wall rock structures, such as bedding or foliation...
generally have small aureoles with minimal metamorphism whereas large ultramafic intrusions can have significantly thick and well-developed contact metamorphism.
The metamorphic grade of an aureole is measured by the peak metamorphic mineral which forms in the aureole. This is usually related to the metamorphic temperatures of pelitic
Pelite
Pelite is old and currently not widely used field terminology for a clayey fine-grained clastic sediment or sedimentary rock, i.e. mud or mudstone. It is equivalent to the Latin-derived term lutite. More commonly, metamorphic geologists currently use pelite for a metamorphosed fine-grained...
or alumonisilicate rocks and the minerals they form.The metamorphic grades of aureoles are andalusite hornfels, sillimanite hornfels, pyroxene hornfels.
Magmatic fluids coming from the intrusive rock may also take part in the metamorphic reaction
Metamorphic reaction
A metamorphic reaction is a chemical reaction that takes place during the geological process of metamorphism wherein one assemblage of minerals is transformed into a second assemblage which is stable under the new temperature/pressure conditions resulting in the final stable state of the observed...
s. Extensive addition of magmatic fluids can significantly modify the chemistry of the affected rocks. In this case the metamorphism grades into metasomatism
Metasomatism
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids.Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact...
. If the intruded rock is rich in carbonate
Carbonate
In chemistry, a carbonate is a salt of carbonic acid, characterized by the presence of the carbonate ion, . The name may also mean an ester of carbonic acid, an organic compound containing the carbonate group C2....
the result is a skarn
Skarn
Skarn is an old Swedish mining term originally used to describe a type of silicate gangue, or waste rock, associated with iron-ore bearing sulfide deposits apparently replacing Archean age limestones in Sweden's Persberg mining district. In modern usage the term "skarn" has been expanded to refer...
. Fluorine
Fluorine
Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...
-rich magmatic waters which leave a cooling granite may often form greisen
Greisen
Greisen is a highly altered granitic rock or pegmatite. Greisen is formed by autogenic alteration of a granite and is a class of endoskarn.Greisens appear as highly altered rocks, partly coarse, crystalline granite, partly vuggy with miarolitic cavities, disseminated halide minerals such as...
s within and adjacent to the contact of the granite. Metasomatic altered aureoles can localize the deposition of metallic ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
minerals and thus are of economic interest.
Hydrothermal metamorphism
Hydrothermal metamorphism is the result of the interaction of a rock with a high-temperature fluid of variable composition. The difference in composition between existing rock and the invading fluid triggers a set of metamorphic and metasomaticMetasomatism
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids.Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact...
reactions. The hydrothermal fluid may be magmatic (originate in an intruding magma), circulating groundwater
Groundwater
Groundwater is water located beneath the ground surface in soil pore spaces and in the fractures of rock formations. A unit of rock or an unconsolidated deposit is called an aquifer when it can yield a usable quantity of water. The depth at which soil pore spaces or fractures and voids in rock...
, or ocean water. Convective circulation of hydrothermal fluids in the ocean floor basalt
Basalt
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey...
s produces extensive hydrothermal metamorphism adjacent to spreading centers and other submarine volcanic areas. The fluids eventually escape through vents in the ocean floor known as black smokers. The patterns of this hydrothermal alteration is used as a guide in the search for deposits of valuable metal ores.
Shock metamorphism
This kind of metamorphism occurs when either an extraterrestrial object (a meteoriteMeteorite
A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...
for instance) collides with the Earth's surface or during an extremely violent volcanic eruption
Volcano
2. Bedrock3. Conduit 4. Base5. Sill6. Dike7. Layers of ash emitted by the volcano8. Flank| 9. Layers of lava emitted by the volcano10. Throat11. Parasitic cone12. Lava flow13. Vent14. Crater15...
. Impact metamorphism is, therefore, characterized by ultrahigh pressure conditions and low temperature. The resulting minerals (such as SiO2 polymorphs
Polymorphism (materials science)
Polymorphism in materials science is the ability of a solid material to exist in more than one form or crystal structure. Polymorphism can potentially be found in any crystalline material including polymers, minerals, and metals, and is related to allotropy, which refers to chemical elements...
coesite
Coesite
Coesite[p] is a form of silicon dioxide SiO2 that is formed when very high pressure , and moderately high temperature , are applied to quartz. Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company, in 1953. In 1960, coesite was found by Edward C. T...
and stishovite
Stishovite
Stishovite is an extremely hard, dense tetragonal form of silicon dioxide. It was long considered the hardest known oxide; however, boron suboxide has recently been discovered to be much harder...
) and textures are characteristic of these conditions.
Dynamic metamorphism
Dynamic metamorphism is associated with zones of high to moderate strain such as fault zones. Cataclasis, crushing and grinding of rocks into angular fragments, occurs in dynamic metamorphic zones, giving cataclastic texture.The textures of dynamic metamorphic zones are dependent on the depth at which they were formed, as the temperature and confining pressure determine the deformation mechanism
Deformation mechanism
In structural geology, metallurgy and materials science, deformation mechanisms refer to the various mechanisms at the grain scale that are responsible for accommodating large plastic strains in rocks, metals and other materials.-Mechanisms:...
s which predominate. Within depths less than 5 km, dynamic metamorphism is not often produced because the confining pressure is too low to produce frictional heat. Instead, a zone of breccia
Breccia
Breccia is a rock composed of broken fragments of minerals or rock cemented together by a fine-grained matrix, that can be either similar to or different from the composition of the fragments....
or cataclasite
Cataclasite
Cataclasite is a type of cataclastic rock that is formed by fracturing and comminution during faulting. It is normally cohesive and non-foliated, consisting of angular clasts in a finer-grained matrix.- Types of cataclasite :...
is formed, with the rock milled and broken into random fragments. This generally forms a mélange
Mélange
In geology, a mélange is a large-scale breccia, a mappable body of rock characterized by a lack of continuous bedding and the inclusion of fragments of rock of all sizes, contained in a fine-grained deformed matrix. The mélange typically consists of a jumble of large blocks of varied lithologies...
. At depth, the angular breccias transit into a ductile shear texture and into mylonite zones.
Within the depth range of 5–10 km pseudotachylite
Pseudotachylite
Pseudotachylite is a fault rock that has the appearance of the basaltic glass, tachylyte. It is dark in color and has a glassy appearance. However, the glass has normally been completely devitrified into very fine-grained material with radial and concentric clusters of crystals...
is formed, as the confining pressure is enough to prevent brecciation and milling and thus energy is focused into discrete fault planes. Frictional heating in this case may melt the rock to form pseudotachylite glass.
Within the depth range of 10–20 km, deformation is governed by ductile deformation conditions and hence frictional heating is dispersed throughout shear zones, resulting in a weaker thermal imprint and distributed deformation. Here, deformation forms mylonite
Mylonite
Mylonite is a fine-grained, compact rock produced by dynamic recrystallization of the constituent minerals resulting in a reduction of the grain size of the rock. It is classified as a metamorphic rock...
, with dynamothermal metamorphism observed rarely as the growth of porphyroblast
Porphyroblast
A porphyroblast is a large mineral crystal in a metamorphic rock which has grown within the finer grained groundmass. Porphyroblasts are commonly euhedral crystals, but can also be partly to completely irregular in shape....
s in mylonite zones.
Overthrust
Thrust fault
A thrust fault is a type of fault, or break in the Earth's crust across which there has been relative movement, in which rocks of lower stratigraphic position are pushed up and over higher strata. They are often recognized because they place older rocks above younger...
ing may juxtapose hot lower crustal rocks against cooler mid and upper crust blocks, resulting in conductive heat transfer and localised contact metamorphism of the cooler blocks adjacent to the hotter blocks, and often retrograde metamorphism in the hotter blocks. The metamorphic assemblages in this case are diagnostic of the depth and temperature and the throw of the fault and can also be dated
Radiometric dating
Radiometric dating is a technique used to date materials such as rocks, usually based on a comparison between the observed abundance of a naturally occurring radioactive isotope and its decay products, using known decay rates...
to give an age of the thrusting.
Classification of Metamorphic Rocks
Metamorphic rocks are classified by their mineral composition, the source rock, also known as a protolithProtolith
Protolith refers to the precursor lithology of a metamorphic rock.For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other rock and thus have a wide variety of protoliths. Identifying a protolith is a major aim of metamorphic geology.Sedimentary...
, and the context (pressure, temperature, hydrological features, etc.) of its formation.
Metamorphic facies
Metamorphic faciesMetamorphic facies
The metamorphic facies are groups of mineral compositions in metamorphic rocks, that are typical for a certain field in pressure-temperature space...
are recognizable terranes or zones with an assemblage of key minerals that were in equilibrium under specific range of temperature and pressure during a metamorphic event. The facies are named after the metamorphic rock formed under those facies conditions from basalt
Basalt
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey...
. Facies relationships were first described by Pentti Eskola in 1921.
Facies:
- Low T - Low P : ZeoliteZeolite faciesZeolite facies describes the mineral assemblage resulting from the pressure and temperature conditions of low-grade metamorphism.The zeolite facies is generally considered to be transitional between diagenetic processes which turn sediments into sedimentary rocks, and prehnite-pumpellyite facies,...
- Mod - High T - Low P : Prehnite-PumpellyitePrehnite-pumpellyite faciesThe prehnite-pumpellyite facies is a metamorphic facies typical of subseafloor alteration of the oceanic crust around mid-ocean ridge spreading centres....
- Low T - High P : BlueschistBlueschistBlueschist is a rock that forms by the metamorphism of basalt and rocks with similar composition at high pressures and low temperatures, approximately corresponding to a depth of 15 to 30 kilometers and 200 to ~500 degrees Celsius....
- Mod to High T - Mod P : GreenschistGreenschistGreenschist is a general field petrologic term applied to metamorphic or altered mafic volcanic rock. The term greenstone is sometimes used to refer to greenschist but can refer to other rock types too. The green is due to abundant green chlorite, actinolite and epidote minerals that dominate the...
- AmphiboliteAmphiboliteAmphibolite is the name given to a rock consisting mainly of hornblende amphibole, the use of the term being restricted, however, to metamorphic rocks. The modern terminology for a holocrystalline plutonic igneous rocks composed primarily of hornblende amphibole is a hornblendite, which are...
- GranuliteGranuliteGranulites are medium to coarse–grained metamorphic rocks that have experienced high temperature metamorphism, composed mainly of feldspars sometimes associated with quartz and anhydrous ferromagnesian minerals, with granoblastic texture and gneissose to massive structure... - Mod - High T - High P : EclogiteEclogiteEclogite is a mafic metamorphic rock. Eclogite is of special interest for at least two reasons. First, it forms at pressures greater than those typical of the crust of the Earth...
See diagram for more detail.
Metamorphic grades
In the Barrovian sequence (described by George BarrowGeorge Barrow
George Barrow was a British geologist.Barrow matriculated at London University in 1871, holding a Turner scholarship. Admitted to King's College London, he studied science, winning prizes in mathematics and geology. He was the first to map a metamorphic gradient by determining a sequence of...
in zones of progressive metamorphism in Scotland), metamorphic grades are also classified by mineral assemblage based on the appearance of key minerals in rocks of pelitic (shaly, aluminous) origin:
Low grade ------------------- Intermediate --------------------- High grade
- Greenschist ------------- Amphibolite ----------------------- Granulite
- SlateSlateSlate is a fine-grained, foliated, homogeneous metamorphic rock derived from an original shale-type sedimentary rock composed of clay or volcanic ash through low-grade regional metamorphism. The result is a foliated rock in which the foliation may not correspond to the original sedimentary layering...
--- PhyllitePhyllitePhyllite is a type of foliated metamorphic rock primarily composed of quartz, sericite mica, and chlorite; the rock represents a gradation in the degree of metamorphism between slate and mica schist. Minute crystals of graphite, sericite, or chlorite impart a silky, sometimes golden sheen to the...
---- SchistSchistThe schists constitute a group of medium-grade metamorphic rocks, chiefly notable for the preponderance of lamellar minerals such as micas, chlorite, talc, hornblende, graphite, and others. Quartz often occurs in drawn-out grains to such an extent that a particular form called quartz schist is...
--------- GneissGneissGneiss is a common and widely distributed type of rock formed by high-grade regional metamorphic processes from pre-existing formations that were originally either igneous or sedimentary rocks.-Etymology:...
-----------------------MigmatiteMigmatiteMigmatite is a rock at the frontier between igneous and metamorphic rocks. They can also be known as diatexite.Migmatites form under extreme temperature conditions during prograde metamorphism, where partial melting occurs in pre-existing rocks. Migmatites are not crystallized from a totally...
(partial melting) >>>melt - ChloriteChlorite groupThe chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the following four elements in the silicate lattice; Mg, Fe, Ni, and Mn....
zone-
-
- BiotiteBiotiteBiotite is a common phyllosilicate mineral within the mica group, with the approximate chemical formula . More generally, it refers to the dark mica series, primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous endmembers...
zone-
-
- GarnetGarnetThe garnet group includes a group of minerals that have been used since the Bronze Age as gemstones and abrasives. The name "garnet" may come from either the Middle English word gernet meaning 'dark red', or the Latin granatus , possibly a reference to the Punica granatum , a plant with red seeds...
zone-
-
- StauroliteStauroliteStaurolite is a red brown to black, mostly opaque, nesosilicate mineral with a white streak.-Properties:It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and a rather complex chemical formula: 2Al94O204...
zone-
-
- KyaniteKyaniteKyanite, whose name derives from the Greek word kuanos sometimes referred to as "kyanos", meaning deep blue, is a typically blue silicate mineral, commonly found in aluminium-rich metamorphic pegmatites and/or sedimentary rock. Kyanite in metamorphic rocks generally indicates pressures higher than...
zone-
-
- SillimaniteSillimaniteSillimanite is an alumino-silicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman . It was first described in 1824 for an occurrence in Chester, Middlesex County, Connecticut, USA....
zone
- Sillimanite
-
-
- Kyanite
-
-
- Staurolite
-
-
- Garnet
-
-
- Biotite
-
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Recrystallization
In recrystallization the grains making up the protolith change shape and size. The identity of the mineral does not change during this process, only the texture. Recrystallization occurs due to heating of the protolith. The temperature at which this occurs can vary depending on the minerals present. Recrystallization generally begins when temperatures reach above half the melting point of the mineral on the KelvinKelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...
scale.
Phase Change
Phase change metamorphism is the creating of new minerals with the same chemical formula as the protolith. This involves a rearrangement of the atoms in the crystals.Neocrystallization
Neocrystallization involves the creation of new mineral crystals different from the protolith. Chemical reactions digest the minerals of the protolith which yields new minerals. This is a very slow process as it can also involve the diffusion of atoms through solid crystals.Pressure Solution
Pressure solution is a metamorphic process that requires a rock to be under strong pressure from one direction and in the presence of hot water. During this process mineral of the protolith partially dissolve, diffuse through the water and precipitate elsewhere.Plastic Deformation
In plastic deformation pressure is applied to the protolith, which causes it to shear or bend, but not break. In order for this to happen temperatures must be high enough that brittle fractures do not occur, but not so high that diffusion of crystals takes place.Prograde and retrograde metamorphism
Metamorphism is further divided into prograde and retrograde metamorphism. Prograde metamorphism involves the change of mineral assemblages (paragenesisParagenesis
Paragenesis is a petrologic concept meaning an equilibrium assemblage of mineral phases. It is used in studies of igneous and metamorphic rock genesis and importantly in studies of the hydrothermal deposition of ore minerals and the rock alteration associated with ore mineral deposits...
) with increasing temperature and (usually) pressure conditions. These are solid state dehydration reactions, and involve the loss of volatiles such as water or carbon dioxide. Prograde metamorphism results in rock characteristic of the maximum pressure and temperature experienced. Metamorphic rocks usually do not undergo further change when they are brought back to the surface.
Retrograde metamorphism involves the reconstitution of a rock via revolatisation under decreasing temperatures (and usually pressures), allowing the mineral assemblages formed in prograde metamorphism to revert to those more stable at less extreme conditions. This is a relatively uncommon process, because volatiles must be present.
See also
- Metamorphic rockMetamorphic rockMetamorphic rock is the transformation of an existing rock type, the protolith, in a process called metamorphism, which means "change in form". The protolith is subjected to heat and pressure causing profound physical and/or chemical change...
- MetasomatismMetasomatismMetasomatism is the chemical alteration of a rock by hydrothermal and other fluids.Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact...
- GeothermobarometryGeothermobarometryGeothermobarometry is the science of measuring the previous pressure and temperature history of a metamorphic or intrusive igneous rocks. Geothermobarometry is a combination of geobarometry, where a pressure of mineral formation is resolved, and geothermometry where a temperature of formation is...
- Ultrahigh-temperature metamorphismUltrahigh-temperature metamorphismUltra-high-temperature metamorphism represents extreme crustal metamorphism with metamorphic temperatures exceeding 900 °C. Granulite facies rocks metamorphosed at very high temperatures were identified in the early 1980s, although it took another decade for the geoscience community to recognize...
External links
- James Madison University: Metamorphism
- BARROVIAN METAMORPHISM: Brock Univ.
- Metamorphism of Carbonate Rocks: University of Wisconsin - Green Bay
- http://metpetdb.rpi.eduMetamorphic Petrology Database (MetPetDBMetPetDBMetPetDB is a relational database and repository for global geochemical data on and images collected from metamorphic rocks from the earth's crust...
)] - Department of Earth and Environmental Sciences, Rensselaer Polytechnic InstituteRensselaer Polytechnic InstituteStephen Van Rensselaer established the Rensselaer School on November 5, 1824 with a letter to the Rev. Dr. Samuel Blatchford, in which van Rensselaer asked Blatchford to serve as the first president. Within the letter he set down several orders of business. He appointed Amos Eaton as the school's...