Molybdenite
Encyclopedia
Molybdenite is a mineral of molybdenum disulfide
, Mo
S
2. Similar in appearance and feel to graphite
, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum atoms sandwiched between sheets of sulfur
atoms. The Mo-S bonds are strong, but the interaction between the sulfur atoms at the top and bottom of separate sandwich-like tri-layers is weak, resulting in easy slippage as well as cleavage planes.
Molybdenite occurs in high temperature hydrothermal ore
deposits.
Its associated minerals include pyrite
, chalcopyrite
, quartz
, anhydrite
, fluorite
, and scheelite
. Important deposits include the disseminated porphyry molybdenum deposits at Questa, New Mexico
and the Henderson
and Climax
mines in Colorado
. Molybdenite also occurs in porphyry copper deposits of Arizona
, Utah
, and Mexico
.
The element rhenium
is always present in molybdenite as a substitute for molybdenum, usually in the parts per million (ppm) range, but often up to 1–2%. High rhenium content results in a structural variety detectable by X-ray diffraction techniques. Molybdenite ores are essentially the only source for rhenium. The presence of the radioactive isotope rhenium-187 and its daughter isotope osmium
-187 provides a useful geochronologic
dating technique.
with good charge mobility and can be used to create small or low-voltage transistor
s possibly easier than graphene
.
Molybdenum disulfide
Molybdenum disulfide is the inorganic compound with the formula MoS2. This black crystalline sulfide of molybdenum occurs as the mineral molybdenite. It is the principal ore from which molybdenum metal is extracted. The natural amorphous form is known as the rarer mineral jordisite. MoS2 is less...
, Mo
Molybdenum
Molybdenum , is a Group 6 chemical element with the symbol Mo and atomic number 42. The name is from Neo-Latin Molybdaenum, from Ancient Greek , meaning lead, itself proposed as a loanword from Anatolian Luvian and Lydian languages, since its ores were confused with lead ores...
S
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...
2. Similar in appearance and feel to graphite
Graphite
The mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Ancient Greek γράφω , "to draw/write", for its use in pencils, where it is commonly called lead . Unlike diamond , graphite is an electrical conductor, a semimetal...
, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum atoms sandwiched between sheets of sulfur
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...
atoms. The Mo-S bonds are strong, but the interaction between the sulfur atoms at the top and bottom of separate sandwich-like tri-layers is weak, resulting in easy slippage as well as cleavage planes.
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
deposits.
Its associated minerals include pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...
, chalcopyrite
Chalcopyrite
Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite...
, quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...
, anhydrite
Anhydrite
Anhydrite is a mineral – anhydrous calcium sulfate, CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium and strontium sulfates, as might be expected from the...
, fluorite
Fluorite
Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...
, and scheelite
Scheelite
Scheelite is a calcium tungstate mineral with the chemical formula CaWO4. It is an important ore of tungsten. Well-formed crystals are sought by collectors and are occasionally fashioned into gemstones when suitably free of flaws...
. Important deposits include the disseminated porphyry molybdenum deposits at Questa, New Mexico
Questa, New Mexico
Questa is a village in Taos County, New Mexico, United States. The population was 1,864 at the 2000 census. Located on the Enchanted Circle scenic highway, near the confluence of the Rio Grande and the Red River, Questa is the least tourist-oriented town on the route...
and the Henderson
Henderson molybdenum mine
The Henderson molybdenum mine is a large underground molybdenum mine west of the town of Empire in Clear Creek County, Colorado, USA. The Henderson mine, which has produced molybdenum since 1976, is owned by Freeport-McMoRan....
and Climax
Climax mine
The Climax mine, located in Climax, Colorado, United States, was a major molybdenum mine in Lake and Summit counties, Colorado. In its heyday, the Climax mine was the largest molybdenum mine in the world, and for many years it supplied three-fourths of the world's supply of molbdenum...
mines in Colorado
Colorado
Colorado is a U.S. state that encompasses much of the Rocky Mountains as well as the northeastern portion of the Colorado Plateau and the western edge of the Great Plains...
. Molybdenite also occurs in porphyry copper deposits of Arizona
Arizona
Arizona ; is a state located in the southwestern region of the United States. It is also part of the western United States and the mountain west. The capital and largest city is Phoenix...
, Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
, and Mexico
Mexico
The United Mexican States , commonly known as Mexico , is a federal constitutional republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of...
.
The element rhenium
Rhenium
Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-white, heavy, third-row transition metal in group 7 of the periodic table. With an average concentration of 1 part per billion , rhenium is one of the rarest elements in the Earth's crust. The free element has...
is always present in molybdenite as a substitute for molybdenum, usually in the parts per million (ppm) range, but often up to 1–2%. High rhenium content results in a structural variety detectable by X-ray diffraction techniques. Molybdenite ores are essentially the only source for rhenium. The presence of the radioactive isotope rhenium-187 and its daughter isotope osmium
Osmium
Osmium is a chemical element with the symbol Os and atomic number 76. Osmium is a hard, brittle, blue-gray or blue-blacktransition metal in the platinum family, and is the densest natural element. Osmium is twice as dense as lead. The density of osmium is , slightly greater than that of iridium,...
-187 provides a useful geochronologic
Geochronology
Geochronology is the science of determining the age of rocks, fossils, and sediments, within a certain degree of uncertainty inherent to the method used. A variety of dating methods are used by geologists to achieve this, and schemes of classification and terminology have been proposed...
dating technique.
Semiconductor
Molybdenite flakes are a direct bandgap semiconductorSemiconductor
A semiconductor is a material with electrical conductivity due to electron flow intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 103 to 10−8 siemens per centimeter...
with good charge mobility and can be used to create small or low-voltage transistor
Transistor
A transistor is a semiconductor device used to amplify and switch electronic signals and power. It is composed of a semiconductor material with at least three terminals for connection to an external circuit. A voltage or current applied to one pair of the transistor's terminals changes the current...
s possibly easier than graphene
Graphene
Graphene is an allotrope of carbon, whose structure is one-atom-thick planar sheets of sp2-bonded carbon atoms that are densely packed in a honeycomb crystal lattice. The term graphene was coined as a combination of graphite and the suffix -ene by Hanns-Peter Boehm, who described single-layer...
.
See also
- Molybdenum disulfideMolybdenum disulfideMolybdenum disulfide is the inorganic compound with the formula MoS2. This black crystalline sulfide of molybdenum occurs as the mineral molybdenite. It is the principal ore from which molybdenum metal is extracted. The natural amorphous form is known as the rarer mineral jordisite. MoS2 is less...
- PowellitePowellitePowellite is a calcium molybdate mineral with formula CaMoO4. Powellite crystallizes with tetragonal - dipyramidal crystal structure as transparent adamantine blue, greenish brown, yellow to grey typically anhedral forms. It exhibits distinct cleavage and has a brittle to conchoidal fracture. It...
(calcium molybdate : CaMoO4) - RheniiteRheniiteRheniite is a very rare rhenium sulfide mineral . It forms metallic, silver grey platey crystals in the Triclinic - pinacoidal class. It has a specific gravity of 7.5....
- WulfeniteWulfeniteWulfenite is a lead molybdate mineral with the formula PbMoO4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore".It crystallizes...
(lead molybdate : PbMoO4)