Nitrogen group - AbsoluteAstronomy.com

Group		15
Period	2 Period 2 element A period 2 element is one of the chemical elements in the second row of the periodic table. The periodic table is laid out in rows to illustrate recurring trends in the chemical behavior of the elements as their atomic number increases; a new row is started when chemical behavior begins to...
	3 Period 3 element A period 3 element is one of the chemical elements in the third row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical...
	4 Period 4 element A period 4 element is one of the chemical elements in the fourth row of the periodic table of the elements. The periodic table is laid out in rows to illustrate recurring trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour...
	5 Period 5 element A period 5 element is one of the chemical elements in the fifth row of the periodic table of the elements. The periodic table is laid out in rows to illustrate recurring trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour...
	6 Period 6 element A period 6 element is one of the chemical elements in the sixth row of the periodic table of the elements, including the lanthanides...
	7 Period 7 element A period 7 element is one of the chemical elements in the seventh row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical...

The nitrogen group is a periodic table group consisting of nitrogen

Nitrogen

Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...

(N), phosphorus

Phosphorus

Phosphorus is the chemical element that has the symbol P and atomic number 15. A multivalent nonmetal of the nitrogen group, phosphorus as a mineral is almost always present in its maximally oxidized state, as inorganic phosphate rocks...

(P), arsenic

Arsenic

Arsenic is a chemical element with the symbol As, atomic number 33 and relative atomic mass 74.92. Arsenic occurs in many minerals, usually in conjunction with sulfur and metals, and also as a pure elemental crystal. It was first documented by Albertus Magnus in 1250.Arsenic is a metalloid...

(As), antimony

Antimony

Antimony is a toxic chemical element with the symbol Sb and an atomic number of 51. A lustrous grey metalloid, it is found in nature mainly as the sulfide mineral stibnite...

(Sb), bismuth

Bismuth

Bismuth is a chemical element with symbol Bi and atomic number 83. Bismuth, a trivalent poor metal, chemically resembles arsenic and antimony. Elemental bismuth may occur naturally uncombined, although its sulfide and oxide form important commercial ores. The free element is 86% as dense as lead...

(Bi) and ununpentium

Ununpentium

Ununpentium is the temporary name of a synthetic superheavy element in the periodic table that has the temporary symbol Uup and has the atomic number 115....

(Uup) (unconfirmed).

In modern IUPAC notation, it is called Group 15. In the old IUPAC and CAS

Chemical Abstracts Service

Chemical Abstracts is a periodical index that provides summaries and indexes of disclosures in recently published scientific documents. Approximately 8,000 journals, technical reports, dissertations, conference proceedings, and new books, in any of 50 languages, are monitored yearly, as are patent...

systems, it was called Group VB and Group VA, respectively . In the field of semiconductor physics, it is still universally called Group V. It is also collectively named the pnictogens. The "five" ("V") in the historical names comes from the fact that these elements have five valence electron

Valence electron

In chemistry, valence electrons are the electrons of an atom that can participate in the formation of chemical bonds with other atoms. Valence electrons are the "own" electrons, present in the free neutral atom, that combine with valence electrons of other atoms to form chemical bonds. In a single...

s (see below).

Like other groups, the members of this family show patterns in its electron configuration

Electron configuration

In atomic physics and quantum chemistry, electron configuration is the arrangement of electrons of an atom, a molecule, or other physical structure...

, especially the outermost shells resulting in trends in chemical behavior:

Z Atomic number In chemistry and physics, the atomic number is the number of protons found in the nucleus of an atom and therefore identical to the charge number of the nucleus. It is conventionally represented by the symbol Z. The atomic number uniquely identifies a chemical element...	Element Chemical element A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminum, iron, copper, gold, mercury, and lead.As of November 2011, 118 elements...	No. of electrons/shell Electron shell An electron shell may be thought of as an orbit followed by electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" , followed by the "2 shell" , then the "3 shell" , and so on further and further from the nucleus. The shell letters K,L,M,.....
7	nitrogen	2, 5
15	phosphorus	2, 8, 5
33	arsenic	2, 8, 18, 5
51	antimony	2, 8, 18, 18, 5
83	bismuth	2, 8, 18, 32, 18, 5
115	ununpentium	2, 8, 18, 32, 32, 18, 5

This group has the defining characteristic that all the component
elements have 5 electrons in their outermost shell

Electron shell

An electron shell may be thought of as an orbit followed by electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" , followed by the "2 shell" , then the "3 shell" , and so on further and further from the nucleus. The shell letters K,L,M,.....

, that is 2 electrons in the s subshell and 3 unpaired electrons in the p subshell. They are therefore 3 electrons short of filling their outermost electron shell in their non-ion

Ion

An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. The name was given by physicist Michael Faraday for the substances that allow a current to pass between electrodes in a...

ized state.
The most important elements of this group are nitrogen
Nitrogen
Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...

(chemical symbol

Chemical symbol

A chemical symbol is a 1- or 2-letter internationally agreed code for a chemical element, usually derived from the name of the element, often in Latin. Only the first letter is capitalised...

N), which in its diatomic form is the principal component of air, and phosphorus

Phosphorus

(P), which, like nitrogen, is essential to all known forms of life.

Binary compounds of the group can be referred to collectively as pnictides. The spelling derives from the Greek

Greek language

Greek is an independent branch of the Indo-European family of languages. Native to the southern Balkans, it has the longest documented history of any Indo-European language, spanning 34 centuries of written records. Its writing system has been the Greek alphabet for the majority of its history;...

πνίγειν (pnígein), to choke

Choking

Choking is the mechanical obstruction of the flow of air from the environment into the lungs. Choking prevents breathing, and can be partial or complete, with partial choking allowing some, although inadequate, flow of air into the lungs. Prolonged or complete choking results in asphyxia which...

or stifle, which is a property of nitrogen; it can also be used as a mnemonic

Mnemonic

A mnemonic , or mnemonic device, is any learning technique that aids memory. To improve long term memory, mnemonic systems are used to make memorization easier. Commonly encountered mnemonics are often verbal, such as a very short poem or a special word used to help a person remember something,...

for the two most common members, P and N. The name pentels (from Greek πέντε, pénte, five) was also used for this group at one time, stemming from the earlier group naming convention (Group VB).

These elements are also noted for their stability

Chemical stability

Chemical stability when used in the technical sense in chemistry, means thermodynamic stability of a chemical system.Thermodynamic stability occurs when a system is in its lowest energy state, or chemical equilibrium with its environment. This may be a dynamic equilibrium, where individual atoms...

in compounds due to their tendency for forming double and triple covalent bonds. This is the property of these elements which leads to their potential toxicity

Toxicity

Toxicity is the degree to which a substance can damage a living or non-living organisms. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a substructure of the organism, such as a cell or an organ , such as the liver...

, most evident in phosphorus, arsenic and antimony. When these substances react with various chemicals of the body, they create strong free radicals not easily processed by the liver, where they accumulate. Paradoxically it is this strong bonding which causes nitrogen and bismuth's reduced toxicity (when in molecules), as these form strong bonds with other atoms which are difficult to split, creating very unreactive molecules. For example N₂, the diatomic

Diatomic

Diatomic molecules are molecules composed only of two atoms, of either the same or different chemical elements. The prefix di- means two in Greek. Common diatomic molecules are hydrogen , nitrogen , oxygen , and carbon monoxide . Seven elements exist in the diatomic state in the liquid and solid...

form of nitrogen, is used for inert atmosphere in situations where argon

Argon

Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide...

or another noble gas

Noble gas

The noble gases are a group of chemical elements with very similar properties: under standard conditions, they are all odorless, colorless, monatomic gases, with very low chemical reactivity...

would be prohibitively expensive.

The nitrogen group consists of two non-metals, two metalloid

Metalloid

Metalloid is a term used in chemistry when classifying the chemical elements. On the basis of their general physical and chemical properties, each element can usually be classified as a metal or a nonmetal. However, some elements with intermediate or mixed properties can be harder to characterize...

s, one metal

Metal

A metal , is an element, compound, or alloy that is a good conductor of both electricity and heat. Metals are usually malleable and shiny, that is they reflect most of incident light...

, and one synthetic (presumably metallic) element. All the elements in the group are a solid

Solid

Solid is one of the three classical states of matter . It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a...

at room temperature

Room temperature

-Comfort levels:The American Society of Heating, Refrigerating and Air-Conditioning Engineers has listings for suggested temperatures and air flow rates in different types of buildings and different environmental circumstances. For example, a single office in a building has an occupancy ratio per...

except for nitrogen which is a gas at room temperature.
Nitrogen and bismuth, despite both being part of the nitrogen group, are very different in their physical properties. For example, at STP nitrogen is a transparent nonmetallic gas, while bismuth is a brittle pinkish metallic solid.

See also