Periodic poling
Encyclopedia
Periodic poling is a formation of layers with alternate orientation in a birefringent material. The domains are regularly spaced, with period in a multiple of the desired wavelength
Wavelength
In physics, the wavelength of a sinusoidal wave is the spatial period of the wave—the distance over which the wave's shape repeats.It is usually determined by considering the distance between consecutive corresponding points of the same phase, such as crests, troughs, or zero crossings, and is a...

 of operation. The structure is desired to achieve quasi-phase-matching
Quasi-phase-matching
Quasi-phase-matching is a technique in nonlinear optics which allows a positive net flow of energy from the pump frequency to the signal and idler frequencies by creating a periodic structure in the nonlinear medium. Momentum is conserved, as is necessary for phase-matching, through an additional...

 (QPM) in the material.

Periodically poled crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

s are frequently used as nonlinear optical materials. They are up to 20 times more efficient at second-harmonic generation than crystals of the same material without periodic
Periodic table (crystal structure)
The structures of metallic elements adopted at standard temperatures and pressures are color coded and shown below, the only exception is mercury, Hg, which is a liquid and the structure refers to the low temperature form. The melting points of the metals is shown above the element symbol...

 structure. The material for the crystals is usually a wide band gap
Band gap
In solid state physics, a band gap, also called an energy gap or bandgap, is an energy range in a solid where no electron states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference between the top of the valence band and the...

 inorganic crystal, or in some cases a suitable organic
Organic chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, composition, reactions, and preparation of carbon-based compounds, hydrocarbons, and their derivatives...

 polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...

. Some popular materials in current use are KTP
Potassium titanyl phosphate
Potassium titanyl phosphate or KTP is a nonlinear optical material which is commonly used for frequency doubling diode pumped solid-state lasers such as Nd:YAG and other neodymium-doped lasers. The material has a relatively high optical damage threshold , a great optical nonlinearity and excellent...

, lithium niobate
Lithium niobate
Lithium niobate is a compound of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides, mobile phones, optical modulators and various other linear and non-linear optical applications.-Properties:...

, and lithium tantalate
Lithium tantalate
Lithium tantalate , is a crystalline solid which possesses unique optical, piezoelectric and pyroelectric properties which make it valuable for nonlinear optics, passive infrared sensors such as motion detectors, terahertz generation and detection, surface acoustic wave applications, cell phones...

.

The periodic structure is created in the crystal using a range of techniques. Pulsed electric field, electron bombardment, thermal pulsing, or other methods can be used to reposition the atom
Atom
The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons...

s in the lattice
Crystal structure
In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry...

, creating oriented domains. This can be achieved either during the growth of the crystal, or subsequently. http://www.iop.org/EJ/abstract/0022-3727/28/9/001

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