Pigeonite is a mineral in the clinopyroxene group. It has a general formula of (Ca

Calcium

Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

,Mg

Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

,Fe

Iron

Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

)(Mg,Fe)Si

Silicon

Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...

₂O

Oxygen

Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

₆. The calcium

Calcium

Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

 cation fraction can vary from 5% to 25%, with iron and magnesium making up the rest of the cations.

Pigeonite crystallizes in the monoclinic system, as does augite

Augite

Augite is a single chain inosilicate mineral, 2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.-Characteristics:Augite is a solid solution in the pyroxene group...

, and a miscibility gap

Solid solution

A solid solution is a solid-state solution of one or more solutes in a solvent. Such a mixture is considered a solution rather than a compound when the crystal structure of the solvent remains unchanged by addition of the solutes, and when the mixture remains in a single homogeneous phase...

 exists between the two minerals. At lower temperatures, pigeonite is unstable relative to augite plus orthopyroxene. The low-temperature limit of pigeonite stability depends upon Fe/Mg ratio in the mineral and is hotter for more Mg-rich compositions; for a Fe/Mg ratio of about 1, the temperature is about 900 °C. The presence of pigeonite in an igneous rock

Igneous rock

Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava...

 thus provides evidence for the crystallization temperature of the magma

Magma

Magma is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and is expected to exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and dissolved gas and sometimes also gas bubbles. Magma often collects in...

, and hence indirectly for the water content of that magma.

Pigeonite is found as phenocryst

Phenocryst

thumb|right|300px|[[Granite]]s often have large [[feldspar|feldspatic]] phenocrysts. This granite, from the [[Switzerland|Swiss]] side of the [[Mont Blanc]] massif, has large white [[plagioclase]] phenocrysts, [[triclinic]] [[mineral]]s that give [[trapezium|trapezoid]] shapes when cut through)...

s in volcanic rock

Volcanic rock

Volcanic rock is a rock formed from magma erupted from a volcano. In other words, it is an igneous rock of volcanic origin...

s on Earth and as crystals in meteorite

Meteorite

A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

s from Mars

Mars

Mars is the fourth planet from the Sun in the Solar System. The planet is named after the Roman god of war, Mars. It is often described as the "Red Planet", as the iron oxide prevalent on its surface gives it a reddish appearance...

 and the Moon

Moon

The Moon is Earth's only known natural satellite,There are a number of near-Earth asteroids including 3753 Cruithne that are co-orbital with Earth: their orbits bring them close to Earth for periods of time but then alter in the long term . These are quasi-satellites and not true moons. For more...

. In slowly cooled intrusive igneous rocks, pigeonite is rarely preserved, but textural evidence of its breakdown to orthopyroxene plus augite may be present, as shown in the accompanying microscopic image.

Pigeonite is named for its type locality

Type locality (geology)

Type locality , also called type area or type locale, is the where a particular rock type, stratigraphic unit, fossil or mineral species is first identified....

 on Lake Superior

Lake Superior

Lake Superior is the largest of the five traditionally-demarcated Great Lakes of North America. It is bounded to the north by the Canadian province of Ontario and the U.S. state of Minnesota, and to the south by the U.S. states of Wisconsin and Michigan. It is the largest freshwater lake in the...

's shores at Pigeon Point, Cook County, Minnesota

Cook County, Minnesota

Northern Minnesota offers extreme winter weather. While the averages are low, the extremes provide more details. A third of the year is below freezing . Of those days, 21 are below zero degrees Fahrenheit .-External links:...

, United States. It was first described in 1900.