Spontaneous glass breakage is a phenomenon by which toughened glass

Toughened glass

Toughened or tempered glass is a type of safety glass processed by controlled thermal or chemical treatments to increase its strength compared with normal glass. Tempering creates balanced internal stresses which cause the glass, when broken, to crumble into small granular chunks instead of...

 (or tempered) may spontaneously break without any apparent reason.
The most common causes are:

• Minor damage during installation such as nicked or chipped edges which later develop into larger breaks
• Binding of the glass in the frame causing stresses to develop as the glass expands and contracts due to thermal changes or deflects due to wind
• Internal defects within the glass such as nickel sulfide inclusion
  Nickel sulfide inclusion
  A nickel sulfide inclusion, , occurs during the process of manufacturing float glass .-Occurrence:In a batch of glass, contaminants that contain nickel might be present,...
  
  .
• Thermal stresses in the glass
• Inadequate glass thickness to resist wind load

Installation damage

While glass is being moved and installed, it is easy for the glaziers to nick or chip the edges of the glass with various tools. It is also possible for fasteners such as nails or screws which are used to attach glass stops to nick the glass edges if these fasteners are installed at an improper angle. These small nicks or chips may not result in immediate breakage. However, over time, as the glass expands and contracts, stress concentrations can develop around the nick that break the entire unit. In the case of tempered glass the entire unit usually breaks.

Binding in the frame

All glass expands and contracts with changes in temperature and deflects due to wind. This means that almost all modern glass in set on resilient blocks at the bottom and with space for expansion at the sides and top. The gaskets holding the glass in the frame are also usually resilient to cushion the glass against wind buffeting. If no space is provided at the perimeter of the unit, the glass will bind against the frame causing internal stresses to develop in the glass which can exceed the strength of glass resulting in breakage.

Internal defects in the glass

Nickel sulfide inclusion

Nickel sulfide inclusion

A nickel sulfide inclusion, , occurs during the process of manufacturing float glass .-Occurrence:In a batch of glass, contaminants that contain nickel might be present,...

s ("stones") can exist in the glass. The most common cause of these inclusions is the use of stainless steel machinery in the glass making and handling process. Small shavings of stainless steel

Stainless steel

In metallurgy, stainless steel, also known as inox steel or inox from French "inoxydable", is defined as a steel alloy with a minimum of 10.5 or 11% chromium content by mass....

 containing nickel

Nickel

Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

 change structure over time and grow, creating internal stresses in the glass. When these stresses exceed the strength of the glass, breakage results. This type of breakage is almost always found in tempered glass and is indicated by a distinctive "figure eight" pattern, with each "loop" of the figure eight approx. 30mm in diameter. The other use of the word "stone" includes that of the internal furnace wall known as refractory brick. As the molten glass pool is processed, the molten glass erodes the inner brick wall causing small pieces of the brick to become suspended in the molten glass solution. After the glass product is formed, these "stones" are embedded in the final product. The problem with this situation is that these stones, when the ware is heated, creates a thermal anomaly which creates a situation for glass explosion.

Thermal stresses

This is most common in large pieces of sealed insulating glass with heavy heat-absorbing (reflective) coatings. The coating is usually applied to the "number two" surface (the inside face of the outside lite). This causes the outside lite of glass to heat up more than the inside lite as the coating converts radiant heat from the Sun into sensible heat. As the outer lite expands due to heating, the entire unit bends outward. If the spacer bar or other edge condition connects the two lites of glass in a very rigid manner, bending stresses can develop which exceed the strength of the glass causing breakage. This was the cause of extensive glass breakage at the John Hancock Tower

John Hancock Tower

The John Hancock Tower, officially named Hancock Place and colloquially known as The Hancock, is a 60-story, 790-foot skyscraper in Boston. The tower was designed by Henry N. Cobb of the firm I. M. Pei & Partners and was completed in 1976...

 in Boston.

Inadequate glass thickness

All glass is engineered to withstand expected wind loads at the site. If the pane is very large and the thickness selected is inadequate, wind loads can cause breakage.

Remedies

Any breakage problem has more severe consequences where the glass installed overhead or in public areas (such as in high-rise buildings). Protection from this hazard can be increased by the application of a safety window film

Safety and security window film

Safety and security window films are polyester films that are applied to glass and glazing in order to hold them together if the glass is shattered . The main difference between film and laminated glass is that the film can be applied to the glass or glazing after manufacture or installation, i.e.,...

to the tempered panes of glass. An old-fashioned precaution was to install metal screens below skylites.