Thomas Andrews (scientist)
Encyclopedia
Thomas Andrews FRS
(9 December 1813 – 26 November 1885) was an Irish
chemist
and physicist
who did important work on phase transitions between gas
es and liquid
s.
merchant
. He attended the Belfast Academy and the Royal Belfast Academical Institution
, where at the latter of which he studied mathematics under James Thomson
. In 1828 he went to the University of Glasgow
to study chemistry under Professor Thomas Thomson, then studied at Trinity College, Dublin
, where he gained distinction in classics
as well as in science. Finally, at University of Edinburgh
in 1835 he was awarded a doctorate in medicine.
Andrews began a successful medical practice in his native Belfast in 1835, also giving instruction in chemistry at the Academical Institution. In 1845 he was appointed vice-president of the newly established Queen's University of Belfast
, and professor of chemistry there. He held these two offices until his retirement in 1879 at age 66. He died in 1885, and was buried in the Borough Cemetery in Belfast.
awarded him a Royal Medal
in 1844. Another important investigation, undertaken in collaboration with Peter Guthrie Tait
, was devoted to ozone
.
His reputation mainly rests on his work with liquefaction
of gases. In the 1860s he carried out a very complete inquiry into the gas laws
—expressing the relations of pressure
, temperature
, and volume
in carbon dioxide
. In particular, he established the concepts of critical temperature and critical pressure, showing that a substance passes from vapor to liquid state without any breach of continuity.
In Andrews' experiments on phase transitions, he showed that carbon dioxide may be carried from any of the states we usually call liquid to any of those we usually call gas, without losing homogeneity. The mathematical physicist Willard Gibbs cited these results in support of the Gibbs free energy
equation. They also set off a race among researchers to liquify various other gases. In 1877-78 Louis Paul Cailletet
was the first to liquefy oxygen, hydrogen, and nitrogen.
- Contains a biographical memoir of Andrews by Tait and Crum Brown
Royal Society
The Royal Society of London for Improving Natural Knowledge, known simply as the Royal Society, is a learned society for science, and is possibly the oldest such society in existence. Founded in November 1660, it was granted a Royal Charter by King Charles II as the "Royal Society of London"...
(9 December 1813 – 26 November 1885) was an Irish
Irish
Irish may refer to:*Irish cuisine* Ireland, an island in north-western Europe, on which are located:** Northern Ireland, a constituent country of the United Kingdom** Republic of Ireland, a sovereign state...
chemist
Chemistry
Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties. Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds....
and physicist
Physics
Physics is a natural science that involves the study of matter and its motion through spacetime, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.Physics is one of the oldest academic...
who did important work on phase transitions between gas
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...
es and liquid
Liquid
Liquid is one of the three classical states of matter . Like a gas, a liquid is able to flow and take the shape of a container. Some liquids resist compression, while others can be compressed. Unlike a gas, a liquid does not disperse to fill every space of a container, and maintains a fairly...
s.
Life
Andrews was born in Belfast, Ireland where his father was a linenLinen
Linen is a textile made from the fibers of the flax plant, Linum usitatissimum. Linen is labor-intensive to manufacture, but when it is made into garments, it is valued for its exceptional coolness and freshness in hot weather....
merchant
Merchant
A merchant is a businessperson who trades in commodities that were produced by others, in order to earn a profit.Merchants can be one of two types:# A wholesale merchant operates in the chain between producer and retail merchant...
. He attended the Belfast Academy and the Royal Belfast Academical Institution
Royal Belfast Academical Institution
The Royal Belfast Academical Institution, is a Grammar School in Belfast, Northern Ireland. Locally referred to as Inst, the school educates boys from ages 11–18...
, where at the latter of which he studied mathematics under James Thomson
James Thomson (mathematician)
James Thomson was an Irish mathematician, notable for his role in the formation of the thermodynamics school at Glasgow University...
. In 1828 he went to the University of Glasgow
University of Glasgow
The University of Glasgow is the fourth-oldest university in the English-speaking world and one of Scotland's four ancient universities. Located in Glasgow, the university was founded in 1451 and is presently one of seventeen British higher education institutions ranked amongst the top 100 of the...
to study chemistry under Professor Thomas Thomson, then studied at Trinity College, Dublin
Trinity College, Dublin
Trinity College, Dublin , formally known as the College of the Holy and Undivided Trinity of Queen Elizabeth near Dublin, was founded in 1592 by letters patent from Queen Elizabeth I as the "mother of a university", Extracts from Letters Patent of Elizabeth I, 1592: "...we...found and...
, where he gained distinction in classics
Classics
Classics is the branch of the Humanities comprising the languages, literature, philosophy, history, art, archaeology and other culture of the ancient Mediterranean world ; especially Ancient Greece and Ancient Rome during Classical Antiquity Classics (sometimes encompassing Classical Studies or...
as well as in science. Finally, at University of Edinburgh
University of Edinburgh
The University of Edinburgh, founded in 1583, is a public research university located in Edinburgh, the capital of Scotland, and a UNESCO World Heritage Site. The university is deeply embedded in the fabric of the city, with many of the buildings in the historic Old Town belonging to the university...
in 1835 he was awarded a doctorate in medicine.
Andrews began a successful medical practice in his native Belfast in 1835, also giving instruction in chemistry at the Academical Institution. In 1845 he was appointed vice-president of the newly established Queen's University of Belfast
Queen's University of Belfast
Queen's University Belfast is a public research university in Belfast, Northern Ireland. The university's official title, per its charter, is the Queen's University of Belfast. It is often referred to simply as Queen's, or by the abbreviation QUB...
, and professor of chemistry there. He held these two offices until his retirement in 1879 at age 66. He died in 1885, and was buried in the Borough Cemetery in Belfast.
Work
Andrews first became known as a scientific investigator with his work on the heat developed in chemical actions, for which the Royal SocietyRoyal Society
The Royal Society of London for Improving Natural Knowledge, known simply as the Royal Society, is a learned society for science, and is possibly the oldest such society in existence. Founded in November 1660, it was granted a Royal Charter by King Charles II as the "Royal Society of London"...
awarded him a Royal Medal
Royal Medal
The Royal Medal, also known as The Queen's Medal, is a silver-gilt medal awarded each year by the Royal Society, two for "the most important contributions to the advancement of natural knowledge" and one for "distinguished contributions in the applied sciences" made within the Commonwealth of...
in 1844. Another important investigation, undertaken in collaboration with Peter Guthrie Tait
Peter Guthrie Tait
Peter Guthrie Tait FRSE was a Scottish mathematical physicist, best known for the seminal energy physics textbook Treatise on Natural Philosophy, which he co-wrote with Kelvin, and his early investigations into knot theory, which contributed to the eventual formation of topology as a mathematical...
, was devoted to ozone
Ozone
Ozone , or trioxygen, is a triatomic molecule, consisting of three oxygen atoms. It is an allotrope of oxygen that is much less stable than the diatomic allotrope...
.
His reputation mainly rests on his work with liquefaction
Liquefaction
Liquefaction may refer to:* Liquefaction, the general process of becoming liquid* Soil liquefaction, the process by which sediments become suspended* Liquefaction of gases in physics, chemistry, and thermal engineering* Liquefactive necrosis in pathology...
of gases. In the 1860s he carried out a very complete inquiry into the gas laws
Gas laws
The early gas laws were developed at the end of the 18th century, when scientists began to realize that relationships between the pressure, volume and temperature of a sample of gas could be obtained which would hold for all gases...
—expressing the relations of pressure
Pressure
Pressure is the force per unit area applied in a direction perpendicular to the surface of an object. Gauge pressure is the pressure relative to the local atmospheric or ambient pressure.- Definition :...
, temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...
, and volume
Volume
Volume is the quantity of three-dimensional space enclosed by some closed boundary, for example, the space that a substance or shape occupies or contains....
in carbon dioxide
Carbon dioxide
Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom...
. In particular, he established the concepts of critical temperature and critical pressure, showing that a substance passes from vapor to liquid state without any breach of continuity.
In Andrews' experiments on phase transitions, he showed that carbon dioxide may be carried from any of the states we usually call liquid to any of those we usually call gas, without losing homogeneity. The mathematical physicist Willard Gibbs cited these results in support of the Gibbs free energy
Gibbs free energy
In thermodynamics, the Gibbs free energy is a thermodynamic potential that measures the "useful" or process-initiating work obtainable from a thermodynamic system at a constant temperature and pressure...
equation. They also set off a race among researchers to liquify various other gases. In 1877-78 Louis Paul Cailletet
Louis Paul Cailletet
Louis-Paul Cailletet was a French physicist and inventor.- Life and work :Cailletet was born in Châtillon-sur-Seine, Côte-d'Or. Educated in Paris, Cailletet returned to Châtillon to manage his father's ironworks...
was the first to liquefy oxygen, hydrogen, and nitrogen.
Selected writings
- Thomas Andrews, "The Bakerian Lecture: On the Continuity of the Gaseous and Liquid States of Matter", Philosophical Transactions of the Royal Society of London, vol. 159 (1869), pp. 575–590.
- Contains a biographical memoir of Andrews by Tait and Crum Brown